File name: Pandora196s1_Sapporo_20230215_L2Fit_fout2c1d20220907p1-8.txt File generation date: 20250123T071617.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v4d20210122.txt Instrument calibration file used: Pandora196s1_CF_v1d20220907.txt Level 1 file used: Pandora196s1_Sapporo_20230215_L1_smca1c1d20220907p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20230215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0502 305.1915 305.3327 305.4740 305.6153 305.7565 305.8977 306.0389 306.1802 306.3214 306.4625 306.6037 306.7449 306.8860 307.0272 307.1683 307.3094 307.4506 307.5917 307.7327 307.8738 308.0149 308.1560 308.2970 308.4380 308.5791 308.7201 308.8611 309.0021 309.1431 309.2840 309.4250 309.5659 309.7069 309.8478 309.9887 310.1296 310.2705 310.4114 310.5523 310.6932 310.8340 310.9748 311.1157 311.2565 311.3973 311.5381 311.6789 311.8197 311.9604 312.1012 312.2419 312.3827 312.5234 312.6641 312.8048 312.9455 313.0861 313.2268 313.3675 313.5081 313.6487 313.7894 313.9300 314.0706 314.2112 314.3517 314.4923 314.6329 314.7734 314.9139 315.0545 315.1950 315.3355 315.4760 315.6164 315.7569 315.8974 316.0378 316.1782 316.3187 316.4591 316.5995 316.7399 316.8802 317.0206 317.1610 317.3013 317.4416 317.5820 317.7223 317.8626 318.0029 318.1431 318.2834 318.4237 318.5639 318.7041 318.8444 318.9846 319.1248 319.2649 319.4051 319.5453 319.6854 319.8256 319.9657 320.1058 320.2459 320.3860 320.5261 320.6662 320.8063 320.9463 321.0864 321.2264 321.3664 321.5064 321.6464 321.7864 321.9264 322.0663 322.2063 322.3462 322.4861 322.6261 322.7660 322.9059 323.0457 323.1856 323.3255 323.4653 323.6052 323.7450 323.8848 324.0246 324.1644 324.3042 324.4439 324.5837 324.7234 324.8632 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230215T000651.4Z 8446.004761 240 1 35.94 2 67.05 136.58 77.25 213.83 0.00 1 0.00 1 0 17 1.144e-01 6.818e-03 7.425e-02 3.700e-03 4.715627e-01 1.914024e-03 5.620100e-03 -6.000000e+00 6.568285e-02 224.72 -2.00 3.56 -2.00 319.79 0.00e+00 3.240846e-03 5.650601e-04 6.972618e-04 -6.000000e+00 2.809387e-03 273.24 -2.00 20.00 -2.00 319.30 0.00e+00 2.544 0.000 302.00 328.00 3 4.7458e+00 5.3916e-03 3.5320e-02 -6.0000e+00 1.6268e-01 6.4007e-03 6.4458e-03 2.4574e-02 -6.0000e+00 1.7662e-01 -7.7304e-03 5.7142e-03 1.3568e-02 -6.0000e+00 1.0484e-01 -5.8183e-03 3.0087e-03 5.6108e-03 -6.0000e+00 4.5087e-02 1.9773e-04 -1.5048e-04 1.0539e-04 5.4166e-05 -6.0000e+00 3.0303e-03 1.9544e-05 -4.7536e-05 12 9 1 12 1 1 91.22 16.50 0.30 0.00002 -0.00111 14 5 1 5 0 2383.850 20.25 15.00 16.50 -0.86 17.2 867.09 22894 -61895 -18598 -50167 14287 -54307 -35094 -18911 -36503 -36497 -33427 -26069 -20007 2744 -3212 3868 -8241 -1617 -4969 -1638 -3316 -5519 636 -2834 3934 -12769 -5041 -13844 -661 -4755 2692 -1823 1502 -1202 -5551 -6078 -4082 457 -3810 1200 -4321 763 -85 2368 2234 615 -2375 4025 1335 1365 1787 2033 2869 1271 2274 -308 1188 -1179 -532 386 -492 939 2692 2309 1595 610 -285 183 951 1682 -285 733 -237 1738 -408 -617 -1132 -2089 -884 -1259 -1014 -2199 -1715 -1651 -583 -518 905 725 600 949 267 96 -959 450 -490 217 -337 662 -84 -215 -817 -1359 -138 -110 -468 -1454 -370 -648 514 499 905 200 715 -119 137 93 365 83 256 -188 -342 76 293 759 268 239 -332 481 -185 -142 -5 -653 -323 -32 218 292 259 -272 262 -233 160 -527 199 -1393 -299 -1053 149 -1064 -602 -312 -804 -868 -785 -615 -546 74 -111 147 -386 -77 -262 -88 -187 -322 36 -179 247 -993 -368 -1061 -43 -336 204 -165 148 -131 -587 -662 -482 59 -623 221 -929 165 -19 541 514 147 -587 948 329 350 499 625 935 454 834 -119 465 -468 -205 147 -196 405 1265 1197 852 308 -142 91 515 1043 -189 499 -160 1120 -247 -334 -592 -1097 -493 -824 -730 -1801 -1502 -1473 -554 -522 945 773 636 957 250 86 -818 387 -473 230 -394 836 -113 -282 -1025 -1590 -150 -125 -566 -1840 -491 -888 753 780 1513 335 1184 -187 205 134 534 127 409 -312 -564 120 461 1135 396 339 -455 695 -290 -237 -9 -1183 -606 -61 447 608 546 -587 558 -486 317 -1023 SS 20230215T002019.1Z 8446.014109 243 1 47.71 2 65.40 139.68 78.63 216.47 0.00 1 0.00 1 0 17 6.712e-02 6.229e-03 4.324e-02 2.690e-03 4.421795e-01 1.387589e-03 5.322004e-03 -6.000000e+00 3.852479e-02 224.72 -2.00 3.56 -2.00 319.60 0.00e+00 2.485658e-03 3.832174e-04 6.668037e-04 -6.000000e+00 1.647840e-03 273.24 -2.00 20.00 -2.00 319.10 0.00e+00 2.386 0.000 302.00 328.00 3 4.5668e+00 3.8743e-03 3.3164e-02 -6.0000e+00 9.5417e-02 4.9801e-03 4.5671e-03 2.3067e-02 -6.0000e+00 1.0360e-01 -2.1848e-03 3.8823e-03 1.2393e-02 -6.0000e+00 6.1492e-02 -8.2166e-03 2.0591e-03 4.6254e-03 -6.0000e+00 2.6444e-02 2.8585e-04 -2.7926e-04 7.7205e-05 4.6772e-05 -6.0000e+00 1.7775e-03 2.1029e-04 -5.1891e-05 10 0 0 10 0 0 98.59 16.52 0.34 0.00021 -0.00189 25 6 1 5 0 1906.950 20.25 15.00 16.52 0.33 17.8 880.67 -22007 -1028 -37715 -25765 -33253 -2848 -20247 -10016 -13532 -17511 -5082 -26045 4484 -11126 5339 -3757 -986 -8048 3674 -1283 2924 -8321 -2925 -6180 -3073 -502 -6071 -3290 -6012 -2595 -164 1079 -1052 301 -6589 -417 -4622 -6253 -1776 -1026 -964 -1341 977 -743 1591 1099 -479 803 745 809 1507 2790 787 2851 -411 1090 -707 461 -347 954 706 2555 1953 1866 1385 -183 711 -495 1629 1575 925 32 117 -243 -298 -1007 -1135 -1881 -1498 -666 -2182 -1105 -2287 -936 -870 -145 423 631 458 436 756 221 30 -325 242 17 598 44 352 -475 -539 -1146 -161 -501 -1009 -1422 -618 -331 405 756 628 532 270 98 -209 492 463 -242 180 -395 -56 98 734 15 849 350 -60 66 -59 -158 -293 -655 -229 170 105 111 314 156 -144 -233 136 -420 -390 -17 -945 -558 -693 -43 -382 -193 -304 -441 -115 -775 119 -422 207 -186 -51 -488 211 -81 184 -575 -198 -465 -239 -42 -542 -273 -497 -213 -15 110 -123 37 -809 -48 -611 -987 -326 -220 -229 -337 251 -198 416 295 -130 218 205 230 464 932 286 1092 -169 453 -307 196 -145 391 301 1173 997 1042 792 -99 370 -261 922 976 622 22 81 -160 -190 -577 -607 -1001 -873 -449 -1602 -899 -2021 -854 -854 -150 457 695 502 456 727 199 26 -280 229 18 715 56 475 -628 -663 -1347 -177 -578 -1271 -1778 -812 -456 599 1213 1030 887 438 156 -311 696 669 -369 291 -669 -94 158 1147 23 1212 482 -83 93 -92 -265 -501 -1159 -420 327 215 225 648 329 -302 -488 271 -800 SS 20230215T002954.1Z 8446.020766 248 1 46.49 2 64.29 141.95 79.67 218.31 0.00 1 0.00 1 0 17 7.901e-02 6.914e-03 6.081e-02 4.268e-03 4.261534e-01 2.199009e-03 5.131116e-03 -6.000000e+00 4.535445e-02 224.72 -2.00 3.56 -2.00 319.55 0.00e+00 3.073043e-03 5.954735e-04 8.246017e-04 -6.000000e+00 1.939898e-03 273.24 -2.00 20.00 -2.00 319.05 0.00e+00 2.291 0.000 302.00 328.00 3 5.4283e+00 6.1153e-03 3.1858e-02 -6.0000e+00 1.1233e-01 1.8089e-02 7.1768e-03 2.2119e-02 -6.0000e+00 1.2196e-01 -5.0501e-03 5.9694e-03 1.2169e-02 -6.0000e+00 7.2392e-02 -9.4067e-03 3.1676e-03 4.9174e-03 -6.0000e+00 3.1133e-02 1.3405e-04 -1.5780e-04 1.2333e-04 4.9200e-05 -6.0000e+00 2.0925e-03 5.5258e-05 -4.5378e-05 11 8 0 10 0 0 98.22 16.55 0.25 0.00006 -0.00113 14 4 1 5 0 3319.980 20.25 15.00 16.55 1.05 17.5 884.04 -36547 -23080 -37846 3634 -39728 -2256 -30973 14652 -24346 -27079 -9722 6777 -17531 2158 2773 -10751 -137 -3730 -16 2272 -3033 1652 -7196 -6150 1197 -2027 -5420 -2569 -6682 -2819 -5216 4576 -2499 4813 -5638 -166 -2403 -1553 203 -678 -2759 -10 -716 -1255 1727 1347 -598 -1483 1078 1831 864 1754 2999 2373 1056 1139 -423 510 -681 1134 -1595 2779 2673 2613 1133 1586 1446 -1297 1181 950 514 228 171 -390 -140 -795 -298 -3050 -968 -1640 -1794 -1807 -2379 -1593 -755 -258 701 1088 669 441 193 834 -1002 191 103 43 303 404 260 -582 -949 -1059 -723 -268 -716 -1236 -382 -211 184 713 777 597 240 108 -103 48 986 52 342 -106 -170 417 506 16 480 -92 175 -126 -134 -614 -127 -662 -322 286 240 47 262 -48 -231 114 136 -398 -851 -531 -1075 67 -1010 -39 -738 256 -692 -850 -259 166 -653 80 123 -637 -8 -240 -1 153 -223 115 -566 -512 98 -179 -508 -224 -588 -244 -526 479 -309 591 -723 -20 -327 -245 38 -149 -683 -3 -192 -345 469 375 -169 -426 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