File name: Pandora196s1_Sapporo_20230921_L2Fit_fout2c9d20230627p1-8.txt File generation date: 20250123T072508.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v9d20230627.txt Level 1 file used: Pandora196s1_Sapporo_20230921_L1_smca1c9d20230627p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20230921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 349 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1606 305.3019 305.4432 305.5845 305.7258 305.8670 306.0083 306.1495 306.2907 306.4320 306.5732 306.7144 306.8555 306.9967 307.1379 307.2790 307.4202 307.5613 307.7024 307.8435 307.9846 308.1257 308.2668 308.4078 308.5489 308.6899 308.8310 308.9720 309.1130 309.2540 309.3950 309.5359 309.6769 309.8178 309.9588 310.0997 310.2406 310.3815 310.5224 310.6633 310.8042 310.9450 311.0859 311.2267 311.3675 311.5084 311.6492 311.7900 311.9307 312.0715 312.2123 312.3530 312.4937 312.6345 312.7752 312.9159 313.0566 313.1973 313.3379 313.4786 313.6192 313.7599 313.9005 314.0411 314.1817 314.3223 314.4629 314.6034 314.7440 314.8845 315.0251 315.1656 315.3061 315.4466 315.5871 315.7276 315.8680 316.0085 316.1489 316.2893 316.4298 316.5702 316.7106 316.8510 316.9913 317.1317 317.2720 317.4124 317.5527 317.6930 317.8333 317.9736 318.1139 318.2542 318.3944 318.5347 318.6749 318.8151 318.9554 319.0956 319.2358 319.3759 319.5161 319.6563 319.7964 319.9365 320.0767 320.2168 320.3569 320.4970 320.6370 320.7771 320.9172 321.0572 321.1972 321.3372 321.4773 321.6173 321.7572 321.8972 322.0372 322.1771 322.3171 322.4570 322.5969 322.7368 322.8767 323.0166 323.1565 323.2963 323.4362 323.5760 323.7158 323.8556 323.9954 324.1352 324.2750 324.4148 324.5545 324.6943 324.8340 324.9737 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230920T212458.2Z 8663.892340 67 1 3.57 2 79.01 99.15 142.20 73.91 0.00 1 0.00 1 0 25 3.554e-01 1.906e-02 2.734e-01 9.325e-03 5.662825e-01 4.807358e-03 7.386062e-03 -6.000000e+00 1.987289e-01 228.53 -2.00 3.56 -2.00 320.72 0.00e+00 1.041208e-03 2.036399e-03 5.766189e-03 -6.000000e+00 9.177910e-03 285.49 -2.00 20.00 -2.00 320.07 0.00e+00 5.054 0.002 302.00 328.00 3 2.3387e+00 1.5388e-02 6.4496e-02 -6.0000e+00 4.9545e-01 -3.0644e-02 2.0052e-02 4.7530e-02 -6.0000e+00 5.3939e-01 -8.6270e-02 1.8864e-02 1.9053e-02 -6.0000e+00 3.2059e-01 3.8765e-02 9.2707e-03 4.3655e-03 -6.0000e+00 1.3688e-01 2.0522e-04 6.2122e-04 2.5436e-04 8.3162e-05 -6.0000e+00 9.0821e-03 1.0452e-02 0.0000e+00 12 9 9 12 5 1 -30.93 16.60 0.31 0.01045 0.01512 4 17 1 5 0 712.560 20.67 15.00 16.60 22.18 1.4 941.13 900000 -191727 129225 -138103 -60936 -30976 -59255 -39044 -139247 900000 -122668 32740 -141876 900000 -9381 26159 -63384 -15707 -31164 5786 32464 -22554 -7162 -42797 76549 -39682 73457 -28845 -21214 -37248 7228 -5635 5150 -6472 9049 18602 -23209 13476 -13401 24992 -829 28646 4121 14871 -4943 7530 11033 -2514 2747 -5146 14585 -2647 20017 -175 15514 1992 15733 -3804 5849 -4707 -2661 3677 2739 9056 -508 4857 -416 3233 -2014 5817 -192 4673 868 1872 -2430 -6573 -2489 -6688 -2588 -7635 333 -4010 -1628 -2561 1066 677 2365 1991 2735 2795 -10 617 -5955 -2269 -3566 162 -1072 1082 16 -907 -2193 -2394 -2014 -1014 -407 -1762 494 -1360 1743 1010 3966 1684 1583 -728 -1476 -842 -2352 165 352 1909 802 1890 -65 1509 122 -1230 -2100 -584 -376 -491 287 -808 -759 -940 584 10 943 575 1209 380 -268 -1089 -933 900000 -5101 1175 -2376 -554 -282 -539 -355 -3048 900000 -2614 298 -4879 900000 -141 334 -2138 -368 -918 127 572 -679 -193 -1807 1116 -1890 1215 -1233 -812 -1740 259 -268 255 -389 449 826 -1693 825 -1298 2040 -97 2710 521 1747 -708 975 1412 -374 402 -861 2230 -534 3548 -41 3306 498 3620 -1046 1432 -1261 -723 1035 869 3038 -192 1692 -149 1145 -818 2534 -96 2342 448 914 -1144 -2904 -999 -2817 -1162 -4156 193 -2708 -1160 -1916 829 559 2009 1738 2389 2358 -8 470 -4627 -1749 -3065 152 -1135 1249 19 -1108 -2579 -2592 -2053 -1058 -455 -2072 597 -1745 2337 1475 6096 2702 2521 -1138 -2217 -1223 -3496 250 563 3112 1306 2994 -102 2290 182 -1796 -3002 -863 -610 -858 526 -1550 -1493 -1938 1248 23 2103 1303 2717 833 -570 -2249 -1908 SS 20230920T225323.1Z 8663.953739 118 1 47.56 2 63.66 116.02 127.11 90.79 0.00 1 0.00 1 0 17 2.009e-02 1.347e-02 2.874e-03 8.564e-04 2.724170e-01 4.234797e-04 3.238570e-03 -6.000000e+00 1.122311e-02 228.52 -2.00 3.56 -2.00 317.36 0.00e+00 1.256291e-03 6.317294e-05 4.565083e-04 -6.000000e+00 5.011915e-04 285.48 -2.00 20.00 -2.00 316.56 0.00e+00 2.241 0.000 302.00 328.00 3 3.6354e+00 1.1226e-03 2.6317e-02 -6.0000e+00 2.7924e-02 -1.9435e-02 1.2684e-03 1.4008e-02 -6.0000e+00 3.0361e-02 2.1741e-02 7.6738e-04 6.8725e-03 -6.0000e+00 1.8104e-02 -1.8314e-02 3.8147e-04 1.9951e-03 -6.0000e+00 7.6757e-03 1.1035e-03 4.6683e-04 2.3254e-05 1.8132e-05 -6.0000e+00 5.0754e-04 7.3102e-03 0.0000e+00 12 9 8 11 4 0 99.96 16.60 0.28 0.00731 0.01082 100 26 1 5 0 475.440 20.67 15.00 16.60 23.75 1.3 953.22 -1761 -242 -1424 -2619 -6613 -3214 -5435 -1047 -2739 -3033 -6024 -5980 -2404 -1088 1819 1063 1488 1210 2381 1555 2129 298 1387 1192 103 841 -752 -1789 -2999 -1840 -711 328 917 -1687 -4863 -5600 -4939 -3106 -993 493 200 133 780 660 1421 1120 463 -6 -700 -838 733 737 1148 1676 1056 1492 1073 530 -74 14 339 1832 2564 3527 1485 -197 -1447 -2354 -442 797 1347 1560 1086 1049 -44 -1971 -3624 -5107 -3998 -3146 -2391 -1721 -2493 -1524 -452 348 1110 1967 2242 1613 833 -724 -2028 -2369 -1708 -1019 418 1718 1237 187 -625 -2082 -2379 -950 -1060 -672 -351 15 884 1818 2255 1847 1231 53 -1122 -1203 -1207 -603 308 862 741 1051 1141 421 329 -1100 -1332 -771 -629 -552 -490 -727 -876 -244 316 241 991 1120 701 362 -219 -820 -1119 -168 -26 -160 -287 -659 -289 -525 -108 -326 -389 -787 -784 -344 -179 337 224 329 254 518 355 498 70 327 299 28 234 -215 -489 -845 -503 -206 93 284 -565 -1559 -1730 -1656 -1189 -450 239 107 75 451 388 828 659 270 -3 -397 -476 435 473 717 1104 724 1037 767 379 -52 10 244 1402 1979 2906 1252 -155 -1146 -1831 -360 685 1264 1525 1065 990 -39 -1714 -2892 -3930 -3213 -2659 -2261 -1674 -2606 -1646 -487 400 1338 2425 2767 1921 920 -789 -2046 -2336 -1795 -1184 501 2136 1636 243 -812 -2511 -2714 -1124 -1378 -860 -469 20 1218 2662 3478 2880 1848 75 -1547 -1568 -1589 -830 454 1273 1110 1541 1630 612 455 -1470 -1796 -1058 -881 -828 -729 -1111 -1364 -396 517 413 1723 1895 1192 629 -368 -1337 -1803 SS 20230920T225833.8Z 8663.957336 121 1 15.00 2 62.82 117.12 126.21 91.64 0.00 1 0.00 1 0 25 2.475e-02 1.412e-02 7.038e-03 2.262e-03 2.662182e-01 1.117324e-03 3.167751e-03 -6.000000e+00 1.382965e-02 228.52 -2.00 3.56 -2.00 317.20 0.00e+00 1.121589e-03 1.588840e-04 4.392503e-04 -6.000000e+00 6.175567e-04 285.48 -2.00 20.00 -2.00 316.41 0.00e+00 2.177 0.000 302.00 328.00 3 4.4129e+00 2.9520e-03 2.5600e-02 -6.0000e+00 3.4409e-02 -1.0768e-02 3.3298e-03 1.3659e-02 -6.0000e+00 3.7411e-02 1.8277e-02 1.9935e-03 6.6673e-03 -6.0000e+00 2.2308e-02 -1.6553e-02 9.8299e-04 1.8972e-03 -6.0000e+00 9.4592e-03 5.4264e-04 4.5017e-04 6.1202e-05 1.7677e-05 -6.0000e+00 6.2533e-04 6.4768e-03 0.0000e+00 12 9 9 12 5 1 99.42 16.61 0.33 0.00648 0.00986 11 10 1 5 0 1249.110 20.67 15.00 16.61 23.95 1.3 954.55 -3821 1086 -3426 -998 -11095 1181 -11634 3984 -4597 -656 -8305 -4770 -3509 -530 4091 402 4075 -692 2852 911 2484 -643 1707 1428 -20 297 -1472 -1003 -3698 -682 -1147 1502 620 -799 -6066 -3604 -5779 -3042 -449 617 507 313 1362 999 1554 135 1046 -567 -244 -939 885 467 1563 1799 767 1731 91 896 -474 408 31 2084 2328 3471 1380 -243 -1481 -2620 -369 596 1117 1633 1569 820 254 -2053 -3074 -5364 -4116 -3217 -2461 -1587 -2803 -1611 -425 765 964 2156 2049 1581 970 -966 -2012 -2678 -1606 -1039 415 1629 1520 338 -599 -2292 -2166 -1002 -964 -880 -425 -177 997 1876 2321 1970 1202 180 -1311 -1263 -1261 -435 408 1001 922 1463 891 511 297 -1179 -1239 -1158 -425 -715 -445 -919 -845 -247 245 569 743 1070 469 452 -191 -568 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