File name: Pandora196s1_Sapporo_20231006_L2Fit_fout2c7d20230627p1-8.txt File generation date: 20240503T122610.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora196_OF_v4d20210122.txt Instrument calibration file used: Pandora196s1_CF_v8d20230627.txt Level 1 file used: Pandora196s1_Sapporo_20231006_L1_smca1c7d20230627p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20231006 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration after repairs + OOB session First and last pixel inside fitting window: 208 349 Nominal wavelengths inside fitting window [nm]: 305.1398 305.2812 305.4227 305.5641 305.7055 305.8469 305.9883 306.1297 306.2710 306.4124 306.5537 306.6951 306.8364 306.9777 307.1190 307.2603 307.4016 307.5428 307.6841 307.8253 307.9666 308.1078 308.2490 308.3902 308.5314 308.6726 308.8137 308.9549 309.0960 309.2372 309.3783 309.5194 309.6605 309.8016 309.9426 310.0837 310.2247 310.3658 310.5068 310.6478 310.7888 310.9298 311.0708 311.2118 311.3527 311.4937 311.6346 311.7755 311.9164 312.0573 312.1982 312.3391 312.4799 312.6208 312.7616 312.9025 313.0433 313.1841 313.3249 313.4657 313.6064 313.7472 313.8880 314.0287 314.1694 314.3101 314.4508 314.5915 314.7322 314.8729 315.0135 315.1542 315.2948 315.4354 315.5760 315.7166 315.8572 315.9978 316.1384 316.2789 316.4195 316.5600 316.7005 316.8410 316.9815 317.1220 317.2624 317.4029 317.5433 317.6838 317.8242 317.9646 318.1050 318.2454 318.3858 318.5261 318.6665 318.8068 318.9472 319.0875 319.2278 319.3681 319.5084 319.6486 319.7889 319.9291 320.0694 320.2096 320.3498 320.4900 320.6302 320.7704 320.9105 321.0507 321.1908 321.3310 321.4711 321.6112 321.7513 321.8914 322.0314 322.1715 322.3115 322.4516 322.5916 322.7316 322.8716 323.0116 323.1516 323.2915 323.4315 323.5714 323.7114 323.8513 323.9912 324.1311 324.2709 324.4108 324.5507 324.6905 324.8304 324.9702 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231006T005242.8Z 8679.036606 376 1 1.59 2 52.19 151.06 59.08 280.67 0.00 1 0.00 1 0 17 1.283e-02 8.874e-03 3.285e-03 1.596e-03 2.401436e-01 8.232348e-04 2.832697e-03 -6.000000e+00 7.487263e-03 226.74 -2.00 3.56 -2.00 316.23 0.00e+00 9.131143e-04 9.428861e-05 1.361097e-04 -6.000000e+00 3.376489e-04 283.62 -2.00 20.00 -2.00 315.52 0.00e+00 1.627 0.000 302.00 328.00 3 2.0016e+00 2.1325e-03 2.0264e-02 -6.0000e+00 1.8549e-02 3.0320e-03 2.3928e-03 1.2113e-02 -6.0000e+00 2.0165e-02 4.6805e-03 1.3794e-03 5.9358e-03 -6.0000e+00 1.2024e-02 -7.8559e-03 6.3581e-04 1.7801e-03 -6.0000e+00 5.0677e-03 1.0704e-02 2.4698e-03 4.6426e-05 1.8963e-05 -6.0000e+00 3.6272e-04 -1.4751e-03 0.0000e+00 12 9 1 12 5 1 -170.58 16.75 0.26 -0.00148 0.01708 14 117 1 5 0 105.110 20.67 15.00 16.75 19.06 1.6 918.67 -1877 -1192 -2530 -2077 -1607 -3405 -1445 -2040 -1471 -3678 -2421 -2017 -1120 45 731 740 1288 1876 1641 2003 1823 2469 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-726 -561 -1434 -657 -171 -1110 -1310 -234 -154 1684 2094 1963 856 662 655 -26 6 100 466 293 252 -133 768 586 238 490 -216 -698 303 -312 -483 -696 -1191 -316 456 609 350 1044 615 74 17 -360 -1328 -1053 SS 20231006T005734.4Z 8679.039981 379 1 47.78 2 51.77 152.50 59.93 281.37 0.00 1 0.00 1 0 17 2.498e-02 1.008e-02 1.639e-02 4.412e-03 2.413289e-01 2.246778e-03 2.849916e-03 -6.000000e+00 1.457033e-02 226.74 -2.00 3.56 -2.00 317.89 0.00e+00 1.522592e-03 3.840273e-04 3.417043e-04 -6.000000e+00 6.574100e-04 283.62 -2.00 20.00 -2.00 317.11 0.00e+00 1.612 0.000 302.00 328.00 3 5.6623e+00 6.0003e-03 2.0246e-02 -6.0000e+00 3.6096e-02 3.3843e-02 6.8179e-03 1.2258e-02 -6.0000e+00 3.9248e-02 9.7578e-03 4.1669e-03 6.1417e-03 -6.0000e+00 2.3402e-02 -1.3529e-02 2.0612e-03 2.0899e-03 -6.0000e+00 9.8573e-03 2.7371e-04 1.9634e-03 1.3419e-04 2.0180e-05 -6.0000e+00 7.0618e-04 2.0833e-03 0.0000e+00 12 9 8 11 4 0 99.99 16.75 0.35 0.00208 0.01684 96 25 1 5 0 497.460 20.67 15.01 16.75 19.56 1.6 924.26 6721 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-1533 -236 -2589 -895 -2533 -2791 -1773 -2327 -1659 -649 509 606 2018 856 2006 546 387 -1643 -534 -516 -180 655 478 536 -1126 -72 -2536 -945 -1210 -696 -1773 -356 -409 1654 2401 1877 2139 240 531 -1225 90 -845 135 -486 744 -131 705 693 196 834 -636 -913 -455 -61 -1329 -595 -1709 -51 250 1090 766 936 1498 539 471 -357 -1549 -1431 SS 20231006T022316.9Z 8679.099501 431 1 47.61 2 48.05 180.11 74.39 293.55 0.00 1 0.00 1 0 17 1.308e-02 8.282e-03 4.686e-03 1.527e-03 2.196098e-01 7.760747e-04 2.611087e-03 -6.000000e+00 7.630325e-03 226.73 -2.00 3.56 -2.00 317.46 0.00e+00 1.038280e-03 1.189398e-04 2.984712e-04 -6.000000e+00 3.442791e-04 283.61 -2.00 20.00 -2.00 316.68 0.00e+00 1.493 0.000 302.00 328.00 3 4.2832e+00 2.0533e-03 1.8623e-02 -6.0000e+00 1.8903e-02 1.5038e-02 2.3225e-03 1.1151e-02 -6.0000e+00 2.0554e-02 6.6397e-03 1.3884e-03 5.5248e-03 -6.0000e+00 1.2256e-02 -1.1505e-02 6.7484e-04 1.6945e-03 -6.0000e+00 5.1621e-03 1.2850e-03 1.9320e-03 4.6122e-05 1.6990e-05 -6.0000e+00 3.6983e-04 2.1277e-03 0.0000e+00 11 9 0 11 4 0 99.96 16.77 0.24 0.00213 0.01665 234 60 1 5 0 203.430 20.67 15.00 16.77 19.64 1.6 922.95 -2166 -2212 -2730 -3165 12 -3565 334 -1998 -1295 -4383 -1824 -1620 -55 -651 -149 231 1151 1973 1351 2610 583 2478 -9 1035 -760 -824 -1684 -593 -602 -717 -500 -914 -1699 -4309 -1980 -3572 -1158 -1325 -894 -1408 -354 135 271 358 761 313 58 293 578 922 844 1242 947 806 911 809 497 422 1196 1463 1836 1570 1834 404 266 -49 -25 682 987 -177 424 303 216 17 -1303 -1338 -2759 -2020 -2432 -2613 -2562 -2610 -1727 -434 139 806 903 790 876 522 404 -1021 -264 -519 -85 -19 449 47 -624 -475 -1350 -663 -451 -815 -1347 -229 -68 959 1224 1313 639 541 72 -245 98 132 355 79 216 -50 517 368 29 236 -341 -864 135 -9 -518 -469 -925 -247 133 558 107 683 589 357 -19 -142 -861 -566 -258 -272 -346 -358 1 -384 38 -258 -177 -619 -249 -242 -9 -123 -31 50 255 453 320 632 142 595 -2 276 -213 -233 -480 -156 -153 -189 -140 -273 -542 -1323 -573 -1129 -409 -556 -436 -756 -197 77 157 206 437 177 32 157 306 506 497 762 613 537 615 558 343 286 803 1005 1342 1237 1525 342 208 -35 -18 497 814 -160 396 283 195 15 -1012 -943 -1967 -1478 -1899 -2266 -2442 -2657 -1814 -484 165 1000 1151 1007 1077 595 422 -985 -246 -510 -91 -22 577 63 -836 -598 -1583 -739 -523 -1033 -1792 -316 -98 1429 1832 2050 1004 813 106 -333 125 169 476 115 330 -78 791 550 42 321 -447 -1073 169 -12 -739 -699 -1408 -381 212 946 180 1173 1036 630 -33 -251 -1476 -957 SS 20231006T040949.8Z 8679.173493 506 1 2.84 2 53.82 213.72 90.39 309.74 0.00 1 0.00 1 0 17 1.957e-02 1.083e-02 1.355e-02 5.951e-03 2.498632e-01 3.067221e-03 2.939955e-03 -6.000000e+00 1.141581e-02 226.72 -2.00 3.56 -2.00 316.48 0.00e+00 9.583592e-04 3.739893e-04 1.603821e-04 -6.000000e+00 5.148626e-04 283.60 -2.00 20.00 -2.00 315.76 0.00e+00 1.689 0.000 302.00 328.00 3 4.4606e+00 7.9721e-03 2.1057e-02 -6.0000e+00 2.8280e-02 1.3882e-02 8.9544e-03 1.2606e-02 -6.0000e+00 3.0746e-02 8.2270e-03 5.2053e-03 6.1859e-03 -6.0000e+00 1.8333e-02 -8.9394e-03 2.4332e-03 1.8716e-03 -6.0000e+00 7.7261e-03 8.4131e-04 2.4349e-03 1.7403e-04 1.9534e-05 -6.0000e+00 5.5311e-04 -8.1996e-04 0.0000e+00 12 9 9 12 5 1 999.00 16.80 0.29 -0.00082 0.01748 1 9 1 5 0 1413.970 20.77 15.00 16.80 23.64 1.4 952.76 3772 -3828 -2873 -2480 -3182 -1513 -7122 -448 -2596 179 -6939 3025 -5118 3797 -4396 -264 3875 4667 696 2229 4488 1914 3006 -519 1976 -1859 1074 -1693 1669 -2042 -1492 -1942 -884 -5628 -2650 -2739 -2204 737 -2579 -772 -1418 875 895 1775 774 577 1464 -2387 811 140 734 1084 1613 357 561 723 -349 378 2392 1014 1583 2586 1525 748 -1159 307 -737 1726 389 1258 510 47 -183 -281 -2125 -2868 -1324 -2463 -2665 -3099 -1715 -2828 -386 -659 -52 775 407 1119 1234 1704 579 -869 -380 -245 -684 -140 -109 -278 36 -405 -1369 -890 128 -830 -1243 34 -502 815 1509 1014 1208 440 824 -270 -52 1316 248 232 -681 591 458 250 -821 511 -857 -511 -82 809 -1098 81 -521 -638 53 987 4 630 673 -632 157 -765 -274 -224 602 -665 -484 -382 -462 -227 -1210 -79 -503 34 -1409 617 -1257 972 -1295 -79 1144 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