File name: Pandora196s1_Sapporo_20231017_L2Fit_fwvt1c9d20230627p1-8.txt File generation date: 20250123T073544.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v9d20230627.txt Level 1 file used: Pandora196s1_Sapporo_20231017_L1_smca1c9d20230627p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20231017 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1622 1771 Nominal wavelengths inside fitting window [nm]: 492.0256 492.1473 492.2689 492.3905 492.5121 492.6336 492.7552 492.8767 492.9982 493.1198 493.2412 493.3627 493.4842 493.6056 493.7270 493.8484 493.9698 494.0912 494.2125 494.3339 494.4552 494.5765 494.6978 494.8190 494.9403 495.0615 495.1827 495.3039 495.4251 495.5463 495.6674 495.7886 495.9097 496.0308 496.1519 496.2729 496.3940 496.5150 496.6360 496.7570 496.8780 496.9990 497.1199 497.2408 497.3618 497.4827 497.6035 497.7244 497.8452 497.9661 498.0869 498.2077 498.3285 498.4492 498.5700 498.6907 498.8114 498.9321 499.0528 499.1734 499.2941 499.4147 499.5353 499.6559 499.7765 499.8970 500.0176 500.1381 500.2586 500.3791 500.4996 500.6200 500.7405 500.8609 500.9813 501.1017 501.2221 501.3424 501.4628 501.5831 501.7034 501.8237 501.9439 502.0642 502.1844 502.3047 502.4249 502.5450 502.6652 502.7854 502.9055 503.0256 503.1457 503.2658 503.3859 503.5059 503.6259 503.7459 503.8659 503.9859 504.1059 504.2258 504.3458 504.4657 504.5856 504.7054 504.8253 504.9452 505.0650 505.1848 505.3046 505.4244 505.5441 505.6638 505.7836 505.9033 506.0230 506.1426 506.2623 506.3819 506.5016 506.6212 506.7407 506.8603 506.9799 507.0994 507.2189 507.3384 507.4579 507.5774 507.6968 507.8162 507.9357 508.0551 508.1744 508.2938 508.4131 508.5325 508.6518 508.7711 508.8904 509.0096 509.1289 509.2481 509.3673 509.4865 509.6057 509.7248 509.8439 509.9631 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231016T215636.3Z 8689.914309 70 1 47.33 2 79.21 113.41 103.72 104.60 0.00 1 0.00 1 0 15 4.329e-03 4.318e-03 1.090e-03 1.089e-03 2.959086e+03 6.917055e+01 1.950136e+02 -6.000000e+00 2.511412e+02 282.27 -2.00 20.00 -2.00 505.28 0.00e+00 1.189256e-03 3.054061e-05 6.286329e-05 -6.000000e+00 1.237296e-04 282.27 -2.00 20.00 -2.00 500.47 0.00e+00 5.419315e-01 2.187091e-02 2.693800e-02 -6.000000e+00 8.732550e-02 225.48 -2.00 3.56 -2.00 502.06 0.00e+00 5.140 0.003 489.00 513.00 1 7.6802e+00 1.6820e-03 7.8104e-03 -6.0000e+00 6.7193e-03 1.7059e-02 4.2441e-04 6.9964e-04 -6.0000e+00 1.7085e-03 4.1068e-04 -5.7994e-05 1.2204e-04 2.9876e-05 -6.0000e+00 5.0118e-04 1.3682e-02 -9.8882e-05 11 9 0 11 4 0 99.93 17.50 0.91 0.01368 0.01328 24 6 1 4 0 1971.720 21.27 15.00 17.50 12.93 1.9 872.00 -1129 -1158 -895 -261 -164 224 812 627 527 336 287 179 -262 -517 -460 -531 -448 92 175 29 405 490 619 304 630 468 533 -189 -446 -462 -479 -219 -322 -47 31 16 181 286 -154 -180 8 155 335 337 392 743 540 465 19 -176 -465 -673 -866 -320 -328 -220 -157 293 282 100 577 459 601 412 314 209 198 -153 -171 -235 -164 -471 -144 -54 -55 -288 -442 -376 -573 -412 -407 -533 -366 -153 -288 -470 -135 -29 -90 80 339 530 759 575 633 36 -113 -372 -394 -439 -920 -470 -162 76 -256 -387 -462 -290 -406 -235 -120 304 397 415 657 912 1051 556 583 247 237 174 244 290 373 115 119 90 304 -34 180 -178 -626 -710 -298 -211 -423 -145 27 465 87 478 338 137 57 -328 -187 -602 -613 -570 -1096 -1132 -883 -262 -167 231 841 654 552 350 297 183 -267 -522 -464 -534 -455 94 181 30 422 512 647 320 662 490 557 -196 -459 -469 -480 -219 -325 -48 32 17 189 296 -159 -185 8 159 345 348 409 773 561 480 19 -177 -463 -661 -847 -314 -325 -221 -160 299 288 103 590 468 613 421 320 210 198 -151 -168 -231 -160 -462 -141 -54 -54 -283 -432 -363 -554 -397 -393 -515 -354 -149 -282 -462 -133 -28 -89 79 334 528 756 574 628 36 -110 -356 -374 -411 -867 -445 -156 74 -254 -383 -457 -284 -396 -231 -118 302 398 417 660 919 1060 563 585 247 234 171 240 286 366 113 117 88 298 -33 175 -172 -603 -681 -287 -205 -413 -142 27 463 87 478 339 138 57 -327 -184 -587 -595 -553 SQ 20231016T233707.3Z 8689.984113 136 1 12.87 2 63.98 134.16 87.64 121.00 0.00 1 0.00 1 0 15 3.850e-03 3.854e-03 1.110e-03 1.108e-03 1.423736e+03 6.698737e+01 9.297185e+01 -6.000000e+00 2.233287e+02 282.26 -2.00 20.00 -2.00 505.26 0.00e+00 5.798348e-04 3.101005e-05 2.941777e-05 -6.000000e+00 1.100306e-04 282.26 -2.00 20.00 -2.00 500.43 0.00e+00 1.270327e-01 2.222675e-02 1.373279e-02 -6.000000e+00 7.766453e-02 225.47 -2.00 3.56 -2.00 502.03 0.00e+00 2.266 0.000 489.00 513.00 1 6.8703e+00 1.7101e-03 3.4925e-03 -6.0000e+00 5.9758e-03 1.9104e-02 4.3375e-04 3.3764e-04 -6.0000e+00 1.5196e-03 1.4482e-03 -3.8509e-06 1.2537e-04 1.3819e-05 -6.0000e+00 4.4568e-04 1.5045e-02 -1.1156e-04 12 9 1 12 5 1 99.91 17.55 0.80 0.01505 0.01502 8 9 1 4 0 1428.920 21.27 15.00 17.55 11.82 2.0 862.79 -1026 -904 -686 -495 -11 291 547 565 546 510 88 154 -351 -243 -368 -407 -313 170 109 146 417 347 461 593 616 381 444 -128 -551 -381 -439 -473 -236 130 67 -206 -98 193 -26 14 50 128 277 440 169 554 412 524 99 -138 -343 -689 -875 -604 -132 -216 -28 -67 18 145 595 651 431 471 144 157 18 -100 -148 -478 -112 -337 -85 132 -53 -255 -302 -358 -304 -390 -225 -354 -301 -60 -191 -416 -66 -139 -86 189 380 518 373 549 501 181 -208 -268 -568 167 -854 -459 -243 10 -410 -455 -435 -248 -286 -237 -169 -51 299 248 756 823 860 642 498 320 198 374 461 249 120 118 115 318 88 -60 28 -117 -565 -602 -203 -170 -314 -310 -1 161 178 152 319 47 119 -295 -345 -176 -463 -203 -1015 -898 -677 -502 -11 300 571 596 577 535 91 157 -356 -250 -376 -417 -315 174 114 154 431 359 478 616 641 397 459 -135 -573 -385 -448 -483 -238 134 69 -215 -102 197 -27 14 52 132 281 451 175 572 424 531 101 -139 -337 -683 -860 -596 -133 -216 -28 -69 19 150 612 670 433 473 148 159 18 -99 -144 -463 -110 -333 -82 129 -52 -249 -291 -350 -295 -378 -218 -347 -289 -58 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0.01388 0.01159 506 130 1 4 0 11.540 21.38 15.00 17.55 11.81 2.0 863.49 -976 -880 -630 -406 -124 283 506 552 544 447 289 -28 -261 -352 -410 -531 -266 -39 177 93 303 398 451 476 561 454 305 40 -203 -385 -559 -607 -175 187 -24 -61 64 126 -31 3 69 123 259 440 496 524 551 390 153 -193 -467 -704 -748 -594 -293 -145 -70 42 105 326 539 575 439 411 369 264 31 -80 -198 -247 -224 -325 -156 44 -47 -213 -447 -455 -476 -424 -398 -582 -480 -182 -266 -311 -208 -47 -83 75 274 546 535 489 492 230 -151 -313 -347 -586 -687 -451 -74 -44 -264 -360 -444 -301 -145 -172 -86 113 273 444 658 776 794 719 574 394 218 201 341 254 214 236 191 253 228 55 -49 -208 -490 -552 -269 -137 -240 -141 26 145 201 323 312 239 34 -248 -400 -555 -613 -407 -953 -864 -632 -408 -128 289 525 580 572 467 298 -28 -263 -360 -417 -541 -266 -40 185 96 314 412 467 494 584 473 316 41 -210 -389 -556 -602 -176 192 -25 -64 66 129 -32 3 72 125 264 452 513 544 568 398 158 -194 -461 -698 -735 -586 -287 -145 -72 42 106 328 542 580 445 416 370 268 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