File name: Pandora196s1_Sapporo_20231101_L2Fit_fout2c9d20230627p1-8.txt File generation date: 20250123T073834.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v9d20230627.txt Level 1 file used: Pandora196s1_Sapporo_20231101_L1_smca1c9d20230627p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20231101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 349 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1606 305.3019 305.4432 305.5845 305.7258 305.8670 306.0083 306.1495 306.2907 306.4320 306.5732 306.7144 306.8555 306.9967 307.1379 307.2790 307.4202 307.5613 307.7024 307.8435 307.9846 308.1257 308.2668 308.4078 308.5489 308.6899 308.8310 308.9720 309.1130 309.2540 309.3950 309.5359 309.6769 309.8178 309.9588 310.0997 310.2406 310.3815 310.5224 310.6633 310.8042 310.9450 311.0859 311.2267 311.3675 311.5084 311.6492 311.7900 311.9307 312.0715 312.2123 312.3530 312.4937 312.6345 312.7752 312.9159 313.0566 313.1973 313.3379 313.4786 313.6192 313.7599 313.9005 314.0411 314.1817 314.3223 314.4629 314.6034 314.7440 314.8845 315.0251 315.1656 315.3061 315.4466 315.5871 315.7276 315.8680 316.0085 316.1489 316.2893 316.4298 316.5702 316.7106 316.8510 316.9913 317.1317 317.2720 317.4124 317.5527 317.6930 317.8333 317.9736 318.1139 318.2542 318.3944 318.5347 318.6749 318.8151 318.9554 319.0956 319.2358 319.3759 319.5161 319.6563 319.7964 319.9365 320.0767 320.2168 320.3569 320.4970 320.6370 320.7771 320.9172 321.0572 321.1972 321.3372 321.4773 321.6173 321.7572 321.8972 322.0372 322.1771 322.3171 322.4570 322.5969 322.7368 322.8767 323.0166 323.1565 323.2963 323.4362 323.5760 323.7158 323.8556 323.9954 324.1352 324.2750 324.4148 324.5545 324.6943 324.8340 324.9737 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231101T011302.2Z 8705.050720 389 1 16.13 2 59.28 161.55 92.74 311.01 0.00 1 0.00 1 0 17 2.100e-02 1.446e-02 8.853e-03 2.918e-03 2.657602e-01 1.420027e-03 3.192844e-03 -6.000000e+00 1.153538e-02 224.09 -2.00 3.56 -2.00 317.09 0.00e+00 1.056902e-03 1.968640e-04 3.892365e-04 -6.000000e+00 5.126594e-04 280.37 -2.00 20.00 -2.00 316.40 0.00e+00 1.950 0.000 302.00 328.00 3 5.1470e+00 3.7134e-03 2.3512e-02 -6.0000e+00 2.8459e-02 -4.2372e-03 4.1970e-03 1.3338e-02 -6.0000e+00 3.1072e-02 2.2403e-02 2.5236e-03 6.6389e-03 -6.0000e+00 1.8535e-02 -1.9488e-02 1.2512e-03 1.9517e-03 -6.0000e+00 7.8941e-03 3.2293e-04 3.1422e-04 7.8688e-05 1.8543e-05 -6.0000e+00 5.2990e-04 7.6276e-03 0.0000e+00 12 9 9 12 5 1 99.62 17.55 0.43 0.00763 0.00999 6 5 1 5 0 2302.420 21.38 15.01 17.55 20.76 1.6 934.04 297 -2526 -429 -4836 -6099 3689 -5490 1119 -4024 614 -6568 -4737 -3525 1181 1399 163 301 2472 2459 2888 2672 868 1899 2066 446 9 -227 -2527 -2583 -2384 -463 -910 678 -1314 -4016 -4885 -5912 -2907 -2380 594 -58 833 641 849 250 24 1300 -319 -363 -387 -56 962 1426 1210 1410 602 1645 794 -124 238 566 1669 2410 3413 1516 401 -1447 -2299 -638 846 1186 1639 1218 619 299 -1719 -3150 -5807 -4521 -3279 -1842 -2196 -2499 -1789 -349 459 1606 2330 2252 1661 741 -1016 -2858 -2460 -1829 -423 651 1913 1493 161 -950 -2153 -2528 -1116 -1103 -722 10 -291 1230 1832 2424 2082 1321 54 -955 -1305 -1467 -436 -75 1175 891 1071 765 286 344 -855 -1458 -864 -578 -725 -513 -987 -838 -72 172 213 930 901 986 500 27 -1057 -1059 31 -306 -53 -607 -683 355 -607 130 -544 85 -966 -691 -567 209 283 37 72 598 617 750 715 233 510 589 135 3 -72 -788 -756 -687 -139 -295 233 -481 -1410 -1664 -2199 -1187 -1123 313 -33 488 387 515 153 15 784 -191 -215 -231 -35 622 964 849 1013 441 1218 591 -92 175 423 1306 1991 2947 1328 335 -1163 -1822 -522 753 1119 1585 1180 591 271 -1466 -2543 -4596 -3694 -2898 -1750 -2234 -2651 -1940 -395 540 1934 2842 2757 1993 849 -1111 -2993 -2526 -1950 -479 782 2445 1984 212 -1205 -2613 -2969 -1341 -1397 -941 13 -401 1729 2673 3660 3158 1958 77 -1304 -1723 -1944 -596 -106 1723 1320 1571 1109 403 470 -1144 -1901 -1139 -796 -1043 -758 -1483 -1273 -111 278 352 1555 1524 1667 833 44 -1705 -1691 SS 20231101T013018.7Z 8705.062717 398 1 35.26 2 58.41 166.34 94.96 313.97 0.00 1 0.00 1 0 17 1.898e-02 1.316e-02 7.570e-04 2.928e-04 2.569509e-01 1.426030e-04 3.076405e-03 -6.000000e+00 1.042903e-02 224.09 -2.00 3.56 -2.00 316.83 0.00e+00 1.179694e-03 1.846416e-05 2.633933e-04 -6.000000e+00 4.634771e-04 280.36 -2.00 20.00 -2.00 316.15 0.00e+00 1.902 0.000 302.00 328.00 3 1.6611e+00 3.7110e-04 2.2852e-02 -6.0000e+00 2.5730e-02 -3.8501e-02 4.1853e-04 1.2873e-02 -6.0000e+00 2.8091e-02 1.7405e-02 2.4748e-04 6.3871e-03 -6.0000e+00 1.6757e-02 -1.5906e-02 1.2033e-04 1.9195e-03 -6.0000e+00 7.1373e-03 1.1417e-02 4.0975e-04 7.8909e-06 1.8335e-05 -6.0000e+00 4.7904e-04 7.2035e-03 0.0000e+00 12 9 9 12 5 1 99.70 17.57 0.31 0.00720 0.01028 562 196 1 5 0 62.620 21.38 15.00 17.57 22.25 1.6 945.12 92 -105 317 -2769 -5608 -5421 -4335 -2043 -1518 -2231 -5028 -4699 -2617 -862 1350 1536 1337 1516 1811 2575 2163 990 1611 1469 673 897 -37 -1204 -2630 -1996 -473 -443 987 -1302 -5025 -5769 -4837 -2990 -737 567 317 214 757 631 1133 957 464 61 -819 -624 566 832 1231 1574 1075 1224 866 440 -259 -235 504 1510 2517 3409 1509 -288 -1366 -2311 -396 754 1311 1638 1140 1100 -97 -1748 -3295 -4883 -3799 -3016 -2174 -1674 -2384 -1737 -558 301 1143 1764 2188 1567 837 -534 -1875 -2253 -1496 -838 406 1633 1246 296 -566 -1919 -2314 -947 -1044 -668 -443 -11 893 1697 2114 1696 1209 151 -1038 -1240 -1171 -526 310 859 663 1033 1079 438 285 -946 -1230 -622 -469 -334 -401 -595 -889 -211 275 305 834 1100 714 222 -246 -909 -1087 12 -14 45 -427 -778 -698 -578 -297 -248 -393 -899 -837 -467 -175 310 396 362 425 529 775 673 307 501 486 216 301 -13 -430 -878 -647 -161 -163 360 -511 -1895 -2091 -1894 -1333 -358 322 184 130 474 401 714 607 291 38 -498 -378 358 566 882 1109 786 909 660 336 -194 -174 384 1229 2077 3000 1355 -241 -1137 -1882 -337 683 1220 1585 1106 1028 -90 -1483 -2731 -3896 -3156 -2657 -2138 -1709 -2465 -1859 -636 347 1375 2177 2698 1865 974 -574 -1971 -2309 -1630 -952 481 2024 1640 383 -725 -2279 -2747 -1105 -1338 -851 -589 -16 1232 2488 3111 2522 1809 211 -1409 -1592 -1515 -711 428 1259 987 1506 1534 628 388 -1244 -1616 -831 -643 -466 -588 -895 -1363 -321 444 495 1374 1856 1211 366 -393 -1472 -1738 SS 20231101T014036.1Z 8705.069863 401 1 47.86 2 58.02 169.23 96.23 315.77 0.00 1 0.00 1 0 17 1.893e-02 1.326e-02 6.628e-04 2.535e-04 2.533161e-01 1.233987e-04 3.030411e-03 -6.000000e+00 1.040204e-02 224.09 -2.00 3.56 -2.00 316.82 0.00e+00 1.195377e-03 1.588090e-05 2.676868e-04 -6.000000e+00 4.622631e-04 280.36 -2.00 20.00 -2.00 316.14 0.00e+00 1.881 0.000 302.00 328.00 3 1.6820e+00 3.2152e-04 2.2574e-02 -6.0000e+00 2.5663e-02 -3.8827e-02 3.6239e-04 1.2684e-02 -6.0000e+00 2.8018e-02 1.7947e-02 2.1468e-04 6.3049e-03 -6.0000e+00 1.6713e-02 -1.6073e-02 1.0467e-04 1.9079e-03 -6.0000e+00 7.1192e-03 1.1476e-02 4.4883e-04 6.8438e-06 1.8258e-05 -6.0000e+00 4.7777e-04 6.7633e-03 0.0000e+00 12 9 8 11 4 0 99.99 17.57 0.33 0.00676 0.01014 899 232 1 5 0 53.050 21.38 15.00 17.57 23.10 1.5 951.80 132 69 593 -2395 -5537 -5379 -4199 -1921 -1888 -2118 -4883 -4952 -2436 -802 1372 1577 1136 1552 2076 2595 2055 1061 1660 1527 667 754 10 -1249 -2660 -1880 -475 -315 973 -1196 -5028 -5683 -4904 -2902 -722 514 171 220 756 545 1196 1059 436 76 -846 -634 579 808 1185 1495 1121 1257 786 392 -270 -237 471 1574 2601 3424 1497 -264 -1434 -2304 -406 729 1316 1688 1168 1148 -75 -1675 -3297 -4868 -3823 -2966 -2229 -1693 -2423 -1768 -559 251 1156 1746 2179 1618 828 -535 -1861 -2297 -1582 -852 408 1663 1230 318 -599 -1909 -2349 -962 -1015 -705 -449 -16 905 1687 2146 1708 1197 144 -995 -1184 -1170 -536 331 824 617 1075 1046 457 368 -968 -1251 -659 -441 -355 -413 -612 -882 -213 248 354 858 1091 725 249 -231 -922 -1077 17 10 90 -358 -745 -672 -542 -271 -300 -362 -844 -855 -461 -157 304 391 297 418 582 751 615 316 497 485 225 265 4 -428 -852 -584 -155 -111 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