File name: Pandora196s1_Sapporo_20231130_L2Fit_fout2c9d20230627p1-8.txt File generation date: 20250123T075914.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v9d20230627.txt Level 1 file used: Pandora196s1_Sapporo_20231130_L1_smca1c9d20230627p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20231130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 349 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1606 305.3019 305.4432 305.5845 305.7258 305.8670 306.0083 306.1495 306.2907 306.4320 306.5732 306.7144 306.8555 306.9967 307.1379 307.2790 307.4202 307.5613 307.7024 307.8435 307.9846 308.1257 308.2668 308.4078 308.5489 308.6899 308.8310 308.9720 309.1130 309.2540 309.3950 309.5359 309.6769 309.8178 309.9588 310.0997 310.2406 310.3815 310.5224 310.6633 310.8042 310.9450 311.0859 311.2267 311.3675 311.5084 311.6492 311.7900 311.9307 312.0715 312.2123 312.3530 312.4937 312.6345 312.7752 312.9159 313.0566 313.1973 313.3379 313.4786 313.6192 313.7599 313.9005 314.0411 314.1817 314.3223 314.4629 314.6034 314.7440 314.8845 315.0251 315.1656 315.3061 315.4466 315.5871 315.7276 315.8680 316.0085 316.1489 316.2893 316.4298 316.5702 316.7106 316.8510 316.9913 317.1317 317.2720 317.4124 317.5527 317.6930 317.8333 317.9736 318.1139 318.2542 318.3944 318.5347 318.6749 318.8151 318.9554 319.0956 319.2358 319.3759 319.5161 319.6563 319.7964 319.9365 320.0767 320.2168 320.3569 320.4970 320.6370 320.7771 320.9172 321.0572 321.1972 321.3372 321.4773 321.6173 321.7572 321.8972 322.0372 322.1771 322.3171 322.4570 322.5969 322.7368 322.8767 323.0166 323.1565 323.2963 323.4362 323.5760 323.7158 323.8556 323.9954 324.1352 324.2750 324.4148 324.5545 324.6943 324.8340 324.9737 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231129T233545.3Z 8733.983164 336 1 47.69 2 75.20 140.11 81.22 299.60 0.00 1 0.00 1 0 25 3.457e-01 1.270e-02 5.283e-02 1.341e-03 6.203420e-01 6.727414e-04 7.526981e-03 -6.000000e+00 1.887101e-01 222.58 -2.00 3.56 -2.00 320.60 0.00e+00 2.517425e-03 2.692344e-04 3.749516e-03 -6.000000e+00 8.318705e-03 276.93 -2.00 20.00 -2.00 320.07 0.00e+00 3.838 0.001 302.00 328.00 3 2.4886e+00 2.0399e-03 5.1680e-02 -6.0000e+00 4.6456e-01 -1.1476e-01 2.6891e-03 3.7282e-02 -6.0000e+00 5.0812e-01 9.9150e-03 2.7860e-03 2.0493e-02 -6.0000e+00 3.0284e-01 -5.2773e-03 1.3895e-03 6.5961e-03 -6.0000e+00 1.2893e-01 5.1922e-04 4.7722e-04 3.4799e-05 9.3136e-05 -6.0000e+00 8.7206e-03 1.0896e-02 0.0000e+00 12 9 8 11 4 0 99.85 16.42 0.25 0.01090 0.01448 145 37 1 5 0 328.810 20.04 15.00 16.42 2.41 2.6 794.19 -173685 -84241 -125565 -89061 -128400 -92008 -87458 -84453 -74894 -117526 -84282 -126438 -48119 -89571 -6678 -43410 -10496 -24228 -11684 -14430 -15559 -12983 -35912 -5588 -33507 -10857 -24616 -10707 -32154 -11927 -16444 -4250 -2859 -2931 -7243 -14238 -7158 -10104 1037 -2240 3932 -84 5091 1937 3053 1645 2708 1832 -971 1789 572 3633 2773 3942 2466 4652 2065 2424 93 -160 966 2392 4467 4559 3819 424 762 -1868 870 1299 2458 1806 1707 972 -1014 -3076 -5145 -5965 -5180 -2701 -2445 -727 -2758 -1551 -427 790 1346 2418 2551 1840 1163 -1253 -2195 -2825 -1559 -1074 545 1347 1173 -190 -991 -2394 -2908 -1038 -1450 -823 -725 78 900 2154 2343 1946 1144 -4 -1090 -1271 -1049 -580 311 448 615 856 1256 335 208 -1180 -1524 -571 -372 -35 -310 -601 -936 -196 16 -35 710 1012 538 263 -166 -657 -582 -1961 -518 -1179 -641 -1242 -602 -595 -641 -597 -1598 -860 -2182 -485 -1780 -74 -857 -170 -504 -235 -319 -362 -294 -1071 -137 -1183 -328 -885 -326 -1181 -384 -667 -183 -144 -162 -399 -821 -427 -739 84 -230 432 -10 633 256 405 228 381 270 -154 295 107 743 571 880 595 1144 541 631 24 -41 252 682 1429 1659 1473 163 288 -746 375 651 1234 951 888 524 -508 -1402 -2240 -2660 -2592 -1579 -1527 -511 -2159 -1264 -341 667 1186 2167 2277 1583 1010 -1042 -1771 -2378 -1356 -1079 578 1626 1531 -247 -1205 -2634 -3169 -1147 -1627 -963 -896 102 1204 3198 3592 3127 1832 -6 -1703 -1911 -1602 -928 493 734 986 1399 1985 513 307 -1697 -2123 -844 -626 -62 -560 -1148 -1875 -392 34 -77 1599 2315 1223 568 -338 -1345 -1173 SS 20231129T234630.9Z 8733.990635 339 1 47.75 2 73.97 142.37 82.86 301.22 0.00 1 0.00 1 0 33 2.637e-01 1.234e-02 3.582e-02 1.068e-03 5.801268e-01 5.323037e-04 6.990474e-03 -6.000000e+00 1.439493e-01 222.58 -2.00 3.56 -2.00 320.38 0.00e+00 2.180821e-03 1.984294e-04 3.021750e-03 -6.000000e+00 6.345775e-03 276.93 -2.00 20.00 -2.00 319.83 0.00e+00 3.561 0.001 302.00 328.00 3 2.3144e+00 1.5809e-03 4.7512e-02 -6.0000e+00 3.5437e-01 -1.1696e-01 2.0237e-03 3.3335e-02 -6.0000e+00 3.8760e-01 3.0244e-02 2.0205e-03 1.8108e-02 -6.0000e+00 2.3101e-01 -1.5536e-02 1.0242e-03 5.8098e-03 -6.0000e+00 9.8347e-02 8.3082e-04 4.0922e-04 2.8039e-05 7.8546e-05 -6.0000e+00 6.6524e-03 1.1206e-02 0.0000e+00 12 9 8 11 4 0 98.11 16.43 0.28 0.01121 0.01428 243 63 1 5 0 196.480 20.14 15.00 16.43 3.18 2.5 800.95 -66150 -119582 -57593 -107039 -84154 -92936 -92118 -66188 -84102 -63893 -85866 -65127 -59612 -33636 -33337 -8584 -23541 -12678 -15849 -2793 -11335 -15141 -13768 -12861 -9307 -15971 -6721 -20869 -12178 -20184 -6857 -9368 -3446 -5537 -7510 -10778 -10956 -3099 -3980 3559 -273 2407 210 3904 992 2090 1784 1349 -204 412 1746 2012 3374 2458 3223 2142 2501 552 223 -343 1020 2058 3697 5117 2514 986 -645 -1468 30 1774 1713 2174 996 907 -1145 -2941 -4575 -6105 -4189 -3431 -1760 -1682 -2065 -1915 -194 394 1575 2225 2569 1871 943 -587 -2324 -2414 -1807 -793 332 1651 974 76 -1115 -2262 -2623 -1077 -1196 -1075 -553 40 1210 1947 2335 1746 1136 -52 -1120 -1270 -1062 -567 56 547 397 1077 1090 472 96 -1156 -1555 -520 -519 -242 -269 -506 -915 -456 157 63 870 1030 665 193 -106 -762 -586 -407 -1370 -432 -1316 -745 -871 -931 -593 -1043 -719 -1252 -848 -925 -519 -649 -159 -574 -308 -434 -72 -329 -456 -427 -438 -333 -655 -260 -904 -468 -891 -315 -525 -213 -384 -505 -730 -824 -256 -412 416 -38 347 33 605 160 343 300 234 -38 80 372 437 790 634 876 613 739 166 65 -99 302 666 1342 2071 1093 417 -272 -637 14 961 940 1238 566 532 -626 -1460 -2152 -2939 -2220 -1970 -1157 -1260 -1690 -1647 -163 351 1458 2103 2415 1695 797 -509 -1958 -2096 -1620 -813 359 2019 1291 100 -1374 -2523 -2903 -1216 -1368 -1288 -696 54 1632 2915 3824 2805 1808 -84 -1728 -1880 -1596 -893 93 884 633 1746 1716 719 141 -1648 -2295 -755 -855 -414 -499 -932 -1764 -930 321 135 1879 2266 1454 403 -221 -1516 -1146 SS 20231129T235637.7Z 8733.997659 342 1 47.46 2 72.88 144.54 84.38 302.76 0.00 1 0.00 1 0 33 1.905e-01 1.228e-02 6.422e-02 1.793e-03 5.469128e-01 8.894140e-04 6.569312e-03 -6.000000e+00 1.040023e-01 222.58 -2.00 3.56 -2.00 320.25 0.00e+00 1.759005e-03 3.189694e-04 2.655638e-03 -6.000000e+00 4.584423e-03 276.92 -2.00 20.00 -2.00 319.70 0.00e+00 3.346 0.001 302.00 328.00 3 3.5335e+00 2.6195e-03 4.4522e-02 -6.0000e+00 2.5603e-01 -1.2262e-01 3.3098e-03 3.1023e-02 -6.0000e+00 2.8003e-01 5.3646e-02 3.2439e-03 1.6690e-02 -6.0000e+00 1.6690e-01 -2.6671e-02 1.6581e-03 5.2578e-03 -6.0000e+00 7.1059e-02 3.1025e-04 4.8988e-04 4.7683e-05 6.7111e-05 -6.0000e+00 4.8059e-03 1.0587e-02 0.0000e+00 12 9 8 11 4 0 99.97 16.46 0.20 0.01059 0.01427 89 23 1 5 0 533.200 20.14 14.99 16.46 3.90 2.5 805.98 -47259 -105933 -31650 -66171 -78390 -43116 -61992 7985 -60884 -38960 -74036 -46839 -46634 -35304 -16723 1974 -14403 -7296 -5034 -4992 -8581 4827 -15672 -4607 -10140 -6724 -8768 -18211 -4582 -10265 -4236 -5965 1789 -5723 -7119 -9279 -8759 -4099 -3883 1932 -1414 1675 2090 3049 -1313 1392 2137 939 -1085 -686 913 938 3119 1619 3385 2047 2617 -269 -568 -1738 320 2193 3972 4459 2034 979 -222 -1258 -399 1584 1172 2139 1109 554 -934 -2668 -4144 -6252 -4015 -3558 -1819 -1391 -2273 -2077 -449 653 1445 2270 2572 1656 1075 -703 -2025 -2271 -1603 -762 456 1801 1031 -93 -1060 -2110 -2606 -1171 -1017 -915 -217 -223 1183 1747 2412 1692 1434 -86 -1263 -1419 -1166 -758 162 669 236 1054 1167 278 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