File name: Pandora196s1_Sapporo_20231220_L2Fit_fout2c7d20230627p1-8.txt File generation date: 20240503T111849.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora196_OF_v4d20210122.txt Instrument calibration file used: Pandora196s1_CF_v8d20230627.txt Level 1 file used: Pandora196s1_Sapporo_20231220_L1_smca1c7d20230627p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20231220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration after repairs + OOB session First and last pixel inside fitting window: 208 349 Nominal wavelengths inside fitting window [nm]: 305.1398 305.2812 305.4227 305.5641 305.7055 305.8469 305.9883 306.1297 306.2710 306.4124 306.5537 306.6951 306.8364 306.9777 307.1190 307.2603 307.4016 307.5428 307.6841 307.8253 307.9666 308.1078 308.2490 308.3902 308.5314 308.6726 308.8137 308.9549 309.0960 309.2372 309.3783 309.5194 309.6605 309.8016 309.9426 310.0837 310.2247 310.3658 310.5068 310.6478 310.7888 310.9298 311.0708 311.2118 311.3527 311.4937 311.6346 311.7755 311.9164 312.0573 312.1982 312.3391 312.4799 312.6208 312.7616 312.9025 313.0433 313.1841 313.3249 313.4657 313.6064 313.7472 313.8880 314.0287 314.1694 314.3101 314.4508 314.5915 314.7322 314.8729 315.0135 315.1542 315.2948 315.4354 315.5760 315.7166 315.8572 315.9978 316.1384 316.2789 316.4195 316.5600 316.7005 316.8410 316.9815 317.1220 317.2624 317.4029 317.5433 317.6838 317.8242 317.9646 318.1050 318.2454 318.3858 318.5261 318.6665 318.8068 318.9472 319.0875 319.2278 319.3681 319.5084 319.6486 319.7889 319.9291 320.0694 320.2096 320.3498 320.4900 320.6302 320.7704 320.9105 321.0507 321.1908 321.3310 321.4711 321.6112 321.7513 321.8914 322.0314 322.1715 322.3115 322.4516 322.5916 322.7316 322.8716 323.0116 323.1516 323.2915 323.4315 323.5714 323.7114 323.8513 323.9912 324.1311 324.2709 324.4108 324.5507 324.6905 324.8304 324.9702 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231219T224911.4Z 8753.950826 69 1 47.51 2 83.87 130.36 131.01 42.60 0.00 1 0.00 1 0 17 6.884e-01 3.823e-02 4.461e-01 2.953e-02 1.109121e+00 1.796747e-02 1.317083e-02 -6.000000e+00 4.147084e-01 222.52 -2.00 3.56 -2.00 322.62 0.00e+00 1.648032e-02 9.397600e-03 5.517777e-03 -6.000000e+00 1.938398e-02 274.89 -2.00 20.00 -2.00 322.21 0.00e+00 8.411 0.011 302.00 328.00 3 7.2493e-01 6.8310e-02 1.0221e-01 -6.0000e+00 1.0249e+00 2.1562e+00 7.8392e-02 5.7848e-02 -6.0000e+00 1.1265e+00 -2.5059e+00 5.1511e-02 2.9565e-02 -6.0000e+00 6.6316e-01 9.0077e-01 2.8497e-02 1.5733e-02 -6.0000e+00 2.7536e-01 1.5881e-05 5.3658e-04 7.6933e-04 3.6043e-04 -6.0000e+00 2.0725e-02 3.5406e-03 0.0000e+00 12 9 8 11 4 0 99.06 16.17 0.46 0.00354 0.00757 37 10 1 5 0 1283.810 19.85 15.01 16.17 1.17 2.7 787.63 6859 148967 12722 900000 -60149 900000 18507 900000 19450 -27240 344492 45179 -23285 27747 239211 10642 900000 -8076 900000 114505 900000 -30423 185195 55476 900000 -15262 -38026 900000 -32654 119715 -67457 900000 -30619 900000 12050 286970 -22526 9650 32349 -4867 249074 -6992 187481 -23131 900000 -43961 900000 -6389 129961 25778 96428 26362 138886 38394 11975 74553 -6004 900000 -48906 143260 -31984 111600 4949 27466 -2256 13122 32008 10348 54771 1845 78554 -2064 51677 -13382 58154 -27769 -2754 -6139 934 17241 3874 23669 -17347 25352 -13132 22082 -1486 30992 -3459 9355 628 -1961 -10622 -7933 3280 -4177 6120 -8163 11308 -8601 8682 -5400 4798 -8165 1911 -8731 -3039 426 -2255 5057 -2673 1927 -4185 2926 -1307 4914 -1570 3495 -677 2461 1861 -1673 3441 -2102 1539 -5536 3471 -1355 2460 -697 2165 -1455 70 -654 -1275 488 -25 1214 -1835 2172 -1145 590 561 4278 868 900000 -5236 900000 566 900000 559 -1009 9893 1297 -1402 1259 6869 739 900000 -696 900000 3288 900000 -2155 5318 1593 900000 -695 -1996 900000 -1681 3438 -7232 900000 -2789 900000 573 8241 -1561 535 1570 -361 7153 -540 5384 -1993 900000 -4658 900000 -531 3732 1798 3659 2136 3988 2953 1179 3823 -647 900000 -6922 4114 -4100 4036 579 2817 -312 1588 3381 1475 5884 344 7102 -381 5166 -2155 4144 -4460 -369 -1006 177 3301 950 5292 -6120 6110 -4822 5865 -504 7713 -1117 2567 181 -586 -3682 -3206 1447 -2373 3691 -6337 7283 -6307 4683 -2946 2313 -4781 1056 -5758 -2095 328 -2121 5150 -3246 2330 -5413 3454 -1586 5765 -2064 4578 -933 3114 2209 -1973 3776 -2471 1725 -6613 4268 -2052 4249 -1421 4727 -3584 185 -1870 -3818 1443 -74 3516 -5109 5315 -2653 1306 SS 20231219T232444.0Z 8753.975509 81 1 47.73 2 79.18 137.10 126.31 51.70 0.00 1 0.00 1 0 17 6.814e-01 1.097e-02 1.001e-01 2.185e-03 7.972096e-01 1.211289e-03 1.013200e-02 -6.000000e+00 3.911265e-01 222.52 -2.00 3.56 -2.00 321.85 0.00e+00 1.080748e-02 6.569882e-04 6.867082e-03 -6.000000e+00 1.729634e-02 274.89 -2.00 20.00 -2.00 321.40 0.00e+00 5.134 0.003 302.00 328.00 3 6.9648e-01 4.2487e-03 6.9006e-02 -6.0000e+00 9.6261e-01 1.9987e-01 6.5704e-03 4.8793e-02 -6.0000e+00 1.0513e+00 -3.8078e-01 7.3929e-03 3.6834e-02 -6.0000e+00 6.2568e-01 1.5528e-01 3.3801e-03 1.8873e-02 -6.0000e+00 2.6381e-01 7.2530e-04 1.8943e-03 6.0092e-05 2.8387e-04 -6.0000e+00 1.9236e-02 1.2176e-03 0.0000e+00 12 9 8 11 4 0 17.94 16.25 0.28 0.00122 0.01545 349 90 1 5 0 136.740 19.96 15.00 16.25 2.53 2.7 799.42 -170394 -233718 -184858 -234184 -202063 -252375 -244084 -188509 -227025 -203154 -213934 -132304 -176335 -53967 -99113 -33544 -80777 -54745 -59355 -58765 -59508 -75358 -59161 -65323 -34109 -75846 -52580 -53820 -26149 -42641 -22116 -18119 -8703 -14102 -23895 -6256 -12569 1573 -10981 8781 -5997 14509 1119 11357 7716 10318 9446 7604 12999 6975 18514 10069 18014 7780 15653 7123 7031 2295 5363 2813 6747 9557 8093 9815 6703 6939 3847 6623 4981 5365 4042 4672 1613 -217 -1853 -3892 -4828 -5156 -859 -1723 -55 -2192 -544 -616 463 577 1184 1250 1372 599 -1207 -1920 -3269 -2060 -1784 -163 -389 21 -663 -398 -1509 -1073 -1083 -1917 -1858 -1283 12 499 1247 1033 704 -105 -87 -584 -304 -143 -151 -128 -125 698 1063 1401 519 517 -385 -391 331 138 17 30 -58 -292 2 -9 -8 332 520 -121 -70 -84 -526 -515 -891 -2581 -1289 -2450 -1448 -3031 -2884 -1388 -2639 -1968 -2611 -1043 -2699 -356 -1309 -272 -1188 -688 -822 -839 -837 -1253 -882 -1086 -429 -1487 -818 -872 -357 -854 -452 -421 -208 -346 -631 -149 -370 48 -454 337 -289 609 56 528 390 530 521 460 809 517 1393 905 1639 831 1594 811 794 264 591 330 847 1344 1330 1730 1215 1273 764 1410 1250 1462 1159 1306 435 -54 -423 -868 -1136 -1399 -271 -646 -23 -1056 -272 -330 260 339 708 742 784 323 -631 -994 -1825 -1312 -1339 -141 -387 23 -722 -405 -1381 -889 -904 -1740 -1761 -1289 13 598 1540 1432 1042 -158 -128 -827 -417 -200 -221 -198 -197 1055 1520 2122 769 741 -544 -538 493 217 30 59 -123 -660 5 -23 -21 898 1423 -328 -180 -200 -1182 -1139 SS 20231219T233028.5Z 8753.979496 84 1 47.72 2 78.48 138.23 125.50 53.06 0.00 1 0.00 1 0 17 6.259e-01 9.327e-03 8.076e-02 1.711e-03 7.621825e-01 9.447527e-04 9.448243e-03 -6.000000e+00 3.592751e-01 222.52 -2.00 3.56 -2.00 321.72 0.00e+00 9.471065e-03 5.018907e-04 6.274491e-03 -6.000000e+00 1.588842e-02 274.89 -2.00 20.00 -2.00 321.26 0.00e+00 4.845 0.002 302.00 328.00 3 6.3592e-01 3.2919e-03 6.5484e-02 -6.0000e+00 8.8422e-01 1.1534e-01 4.9621e-03 4.6889e-02 -6.0000e+00 9.6572e-01 -2.5789e-01 5.5686e-03 3.4852e-02 -6.0000e+00 5.7473e-01 1.0466e-01 2.5733e-03 1.7317e-02 -6.0000e+00 2.4232e-01 1.0555e-03 1.8820e-03 4.7642e-05 2.6127e-04 -6.0000e+00 1.7670e-02 1.5073e-03 0.0000e+00 11 9 0 11 4 0 23.89 16.26 0.22 0.00151 0.01565 436 112 1 5 0 109.430 19.96 15.00 16.26 3.21 2.6 805.06 -196240 -236019 -185537 -197888 -204683 -164641 -216292 -171003 -223382 -161166 -184792 -137850 -147355 -85906 -101355 -54052 -69931 -51565 -45956 -59859 -38982 -73116 -33770 -64056 -39028 -63130 -51672 -63040 -46944 -37948 -23723 -9424 -17115 -9438 -27787 -5232 -13906 2966 -10341 2250 -4656 4464 5036 6131 8062 4915 9812 5159 8775 6757 14075 7541 12365 6748 7127 3220 3978 2370 1038 5759 3621 8182 7032 8256 5381 6249 2111 4512 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