File name: Pandora196s1_Sapporo_20240101_L2Fit_fout2c7d20230627p1-8.txt File generation date: 20240503T151921.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora196_OF_v4d20210122.txt Instrument calibration file used: Pandora196s1_CF_v8d20230627.txt Level 1 file used: Pandora196s1_Sapporo_20240101_L1_smca1c7d20230627p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20240101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration after repairs + OOB session First and last pixel inside fitting window: 208 349 Nominal wavelengths inside fitting window [nm]: 305.1398 305.2812 305.4227 305.5641 305.7055 305.8469 305.9883 306.1297 306.2710 306.4124 306.5537 306.6951 306.8364 306.9777 307.1190 307.2603 307.4016 307.5428 307.6841 307.8253 307.9666 308.1078 308.2490 308.3902 308.5314 308.6726 308.8137 308.9549 309.0960 309.2372 309.3783 309.5194 309.6605 309.8016 309.9426 310.0837 310.2247 310.3658 310.5068 310.6478 310.7888 310.9298 311.0708 311.2118 311.3527 311.4937 311.6346 311.7755 311.9164 312.0573 312.1982 312.3391 312.4799 312.6208 312.7616 312.9025 313.0433 313.1841 313.3249 313.4657 313.6064 313.7472 313.8880 314.0287 314.1694 314.3101 314.4508 314.5915 314.7322 314.8729 315.0135 315.1542 315.2948 315.4354 315.5760 315.7166 315.8572 315.9978 316.1384 316.2789 316.4195 316.5600 316.7005 316.8410 316.9815 317.1220 317.2624 317.4029 317.5433 317.6838 317.8242 317.9646 318.1050 318.2454 318.3858 318.5261 318.6665 318.8068 318.9472 319.0875 319.2278 319.3681 319.5084 319.6486 319.7889 319.9291 320.0694 320.2096 320.3498 320.4900 320.6302 320.7704 320.9105 321.0507 321.1908 321.3310 321.4711 321.6112 321.7513 321.8914 322.0314 322.1715 322.3115 322.4516 322.5916 322.7316 322.8716 323.0116 323.1516 323.2915 323.4315 323.5714 323.7114 323.8513 323.9912 324.1311 324.2709 324.4108 324.5507 324.6905 324.8304 324.9702 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231231T235506.8Z 8765.996607 337 1 7.29 2 75.97 141.84 75.88 273.39 0.00 1 0.00 1 0 25 4.347e-01 1.116e-02 2.232e-01 6.411e-03 6.347096e-01 3.374680e-03 7.996978e-03 -6.000000e+00 2.498571e-01 222.97 -2.00 3.56 -2.00 320.77 0.00e+00 8.877842e-03 1.407429e-03 4.301569e-03 -6.000000e+00 1.100279e-02 274.14 -2.00 20.00 -2.00 320.28 0.00e+00 4.034 0.001 302.00 328.00 3 3.0460e+00 1.0324e-02 5.2867e-02 -6.0000e+00 6.1569e-01 -1.0128e-02 1.3639e-02 3.5608e-02 -6.0000e+00 6.7242e-01 -8.8991e-02 1.4119e-02 2.6873e-02 -6.0000e+00 3.9987e-01 4.0379e-02 6.9573e-03 1.4092e-02 -6.0000e+00 1.6823e-01 2.3379e-04 1.8688e-03 1.7763e-04 1.7909e-04 -6.0000e+00 1.2274e-02 4.9513e-03 0.0000e+00 12 9 9 12 5 1 92.02 16.15 0.24 0.00495 0.01899 6 12 1 5 0 1039.460 19.85 14.98 16.15 0.79 2.7 785.00 -160810 -123453 -98037 -161899 -119763 -180339 -90845 -190635 -133544 -149447 -42493 -99820 149540 -27605 -27697 -19313 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9.6353e-03 5.6699e-03 0.0000e+00 11 9 0 11 4 0 99.75 16.16 0.24 0.00567 0.01819 495 128 1 5 0 96.270 19.85 15.01 16.16 1.32 2.7 790.89 -122163 -119006 -103772 -128694 -102646 -145607 -109943 -111593 -88345 -101484 -85186 -75889 -52599 -50208 -33641 -26693 -25729 -17920 -23655 -11941 -22477 -14557 -24240 -14048 -22043 -16856 -19987 -20573 -21053 -15238 -9822 -10900 -5426 -11218 -7136 -10566 -3275 -4414 -867 -1378 -251 -16 1470 2634 2037 2781 2048 3377 2631 4990 3725 4373 4128 3047 2364 517 -15 -360 753 779 2639 3089 3854 3191 2842 2129 1316 1614 1729 1073 767 420 -68 -342 -2106 -2542 -3876 -2848 -2218 -2049 -1844 -2097 -1548 -702 -105 685 1128 1087 1420 880 424 -1029 -1090 -829 -409 117 204 91 -362 -325 -1006 -423 -614 -1230 -1669 -632 -85 826 1215 1076 526 330 9 -363 34 5 -96 -359 -279 -63 466 646 143 286 -301 -526 186 15 -216 -118 -383 -186 54 114 -53 392 327 32 -5 -111 -451 -112 -970 -1019 -787 -1160 -756 -1559 -1004 -1161 -798 -1106 -870 -894 -640 -764 -535 -456 -485 -345 -511 -241 -503 -309 -607 -339 -606 -455 -553 -575 -632 -510 -374 -485 -255 -543 -327 -547 -184 -304 -69 -124 -24 -2 155 279 226 314 243 414 345 706 600 761 784 618 499 115 -3 -79 162 174 638 841 1169 1037 902 674 431 575 711 484 362 197 -30 -141 -796 -910 -1424 -1153 -1059 -1128 -1153 -1440 -1114 -537 -85 578 972 933 1171 680 310 -733 -803 -684 -387 114 227 109 -431 -363 -1018 -394 -586 -1278 -1816 -723 -103 1090 1779 1727 884 550 14 -553 50 8 -149 -591 -475 -104 744 998 214 411 -423 -714 267 25 -392 -232 -728 -370 114 257 -124 928 789 76 -12 -240 -926 -227 SS 20240101T001856.2Z 8766.013151 347 1 2.89 2 73.43 146.87 80.16 277.19 0.00 1 0.00 1 0 17 2.557e-01 1.011e-02 1.660e-01 6.073e-03 5.601310e-01 3.133146e-03 6.548738e-03 -6.000000e+00 1.469918e-01 222.97 -2.00 3.56 -2.00 320.06 0.00e+00 5.245998e-03 1.063120e-03 1.768529e-03 -6.000000e+00 6.472033e-03 274.14 -2.00 20.00 -2.00 319.54 0.00e+00 3.452 0.001 302.00 328.00 3 2.7779e+00 9.0130e-03 4.4554e-02 -6.0000e+00 3.6221e-01 -3.3090e-02 1.1054e-02 2.8573e-02 -6.0000e+00 3.9557e-01 -2.3867e-02 1.0246e-02 1.8018e-02 -6.0000e+00 2.3523e-01 7.5956e-03 5.2648e-03 9.2487e-03 -6.0000e+00 9.8982e-02 5.7080e-04 2.2114e-03 1.7135e-04 9.5362e-05 -6.0000e+00 7.2201e-03 3.8546e-03 0.0000e+00 12 9 9 12 5 1 88.36 16.18 0.18 0.00385 0.02047 4 21 1 5 0 576.400 19.85 15.00 16.18 2.90 2.6 802.17 -114517 43337 -117786 3705 -117316 -57850 -111130 -61388 -23694 -104107 -46821 -67355 -32182 -51054 -2436 -22916 2735 -29690 -571 5861 960 -6999 -17529 -12326 -21138 -18727 -19444 -2268 -20190 250 -16854 642 -8655 -3545 -5120 1708 -3406 -5596 3192 -2689 2418 212 7526 -444 6615 3181 7379 -1036 4256 3883 3875 3673 2082 3767 386 3477 671 1684 1903 2888 3108 1394 2622 2020 2447 938 388 -1123 1578 848 1140 -1222 -767 334 -2461 -1293 -4655 -1699 -2766 -1650 -1423 -1939 -1605 -251 -907 846 922 400 846 -193 -230 -1411 -945 -699 732 -222 436 170 -696 -99 -382 -485 -1085 -618 -2064 202 -144 924 1573 1513 -76 590 207 69 96 -470 574 -651 -116 -610 838 428 649 255 570 -558 24 7 153 -132 -652 -582 -197 417 108 734 59 -142 -48 -241 -482 -43 -2131 257 -2551 23 -2243 -655 -2313 -898 -268 -2684 -742 -1631 -701 -1690 -60 -790 81 -1324 -20 203 35 -282 -840 -599 -1178 -1050 -1084 -109 -1189 14 -1318 48 -790 -297 -430 146 -358 -727 440 -442 407 39 1324 -86 1233 626 1436 -228 936 940 1019 1049 655 1226 131 1175 233 582 653 1017 1167 598 1205 985 1148 439 186 -579 914 525 733 -796 -472 193 -1314 -658 -2461 -939 -1775 -1173 -1117 -1630 -1382 -229 -866 834 911 396 819 -180 -206 -1219 -835 -672 760 -253 547 221 -900 -123 -442 -534 -1233 -741 -2565 255 -191 1292 2331 2395 -124 944 324 104 141 -705 872 -1043 -188 -1000 1327 660 981 379 817 -794 35 12 259 -234 -1193 -1094 -385 850 225 1525 125 -301 -98 -485 -936 -83 SS 20240101T002308.0Z 8766.016064 350 1 2.72 2 73.02 147.78 80.91 277.86 0.00 1 0.00 1 0 17 2.227e-01 1.333e-02 2.537e-01 1.114e-02 5.520862e-01 5.760403e-03 6.495331e-03 -6.000000e+00 1.280439e-01 222.97 -2.00 3.56 -2.00 319.94 0.00e+00 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