File name: Pandora196s1_Sapporo_20240303_L2Fit_fout2c9d20230627p1-8.txt File generation date: 20250123T135914.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v9d20230627.txt Level 1 file used: Pandora196s1_Sapporo_20240303_L1_smca1c9d20230627p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20240303 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 349 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1606 305.3019 305.4432 305.5845 305.7258 305.8670 306.0083 306.1495 306.2907 306.4320 306.5732 306.7144 306.8555 306.9967 307.1379 307.2790 307.4202 307.5613 307.7024 307.8435 307.9846 308.1257 308.2668 308.4078 308.5489 308.6899 308.8310 308.9720 309.1130 309.2540 309.3950 309.5359 309.6769 309.8178 309.9588 310.0997 310.2406 310.3815 310.5224 310.6633 310.8042 310.9450 311.0859 311.2267 311.3675 311.5084 311.6492 311.7900 311.9307 312.0715 312.2123 312.3530 312.4937 312.6345 312.7752 312.9159 313.0566 313.1973 313.3379 313.4786 313.6192 313.7599 313.9005 314.0411 314.1817 314.3223 314.4629 314.6034 314.7440 314.8845 315.0251 315.1656 315.3061 315.4466 315.5871 315.7276 315.8680 316.0085 316.1489 316.2893 316.4298 316.5702 316.7106 316.8510 316.9913 317.1317 317.2720 317.4124 317.5527 317.6930 317.8333 317.9736 318.1139 318.2542 318.3944 318.5347 318.6749 318.8151 318.9554 319.0956 319.2358 319.3759 319.5161 319.6563 319.7964 319.9365 320.0767 320.2168 320.3569 320.4970 320.6370 320.7771 320.9172 321.0572 321.1972 321.3372 321.4773 321.6173 321.7572 321.8972 322.0372 322.1771 322.3171 322.4570 322.5969 322.7368 322.8767 323.0166 323.1565 323.2963 323.4362 323.5760 323.7158 323.8556 323.9954 324.1352 324.2750 324.4148 324.5545 324.6943 324.8340 324.9737 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240302T224542.1Z 8827.948404 252 1 26.61 2 73.72 116.12 79.16 218.43 0.00 1 0.00 1 0 25 4.995e-01 1.741e-02 2.507e-01 7.768e-03 6.840314e-01 4.044492e-03 8.577118e-03 -6.000000e+00 2.788146e-01 225.42 -2.00 3.56 -2.00 321.01 0.00e+00 4.158820e-03 1.740551e-03 5.622139e-03 -6.000000e+00 1.270756e-02 274.43 -2.00 20.00 -2.00 320.52 0.00e+00 3.510 0.001 302.00 328.00 3 5.1143e+00 1.2670e-02 5.4750e-02 -6.0000e+00 6.9191e-01 2.6910e-02 1.7389e-02 4.5981e-02 -6.0000e+00 7.5635e-01 -1.2753e-01 1.8597e-02 2.7168e-02 -6.0000e+00 4.4607e-01 4.9518e-02 9.0451e-03 9.5993e-03 -6.0000e+00 1.8766e-01 4.4357e-05 4.5914e-04 2.0291e-04 1.4858e-04 -6.0000e+00 1.2941e-02 1.0230e-02 0.0000e+00 12 9 9 12 5 1 99.99 16.24 0.57 0.01023 0.01368 10 5 1 5 0 2418.220 19.96 14.99 16.24 3.05 2.7 809.31 -236462 -70428 -106715 -167719 -241776 900000 -188455 900000 -16730 -175770 900000 -164317 -107730 -123440 900000 -82557 -57476 -30450 -42270 -54980 3699 -11156 -64983 123584 -51173 51954 -30331 -45126 -16775 11719 -4209 32525 -27538 4637 10657 31671 -15508 19184 11491 5869 -998 -9137 274 3978 1043 1095 15437 9144 3831 6982 1292 18710 8273 17143 1231 4837 5570 6438 100 3327 1514 8995 8091 7649 6344 5624 4926 1630 4093 3255 256 -2416 3295 -804 1522 -6445 -4745 -9740 -6950 -3420 -3009 397 -3730 -1371 268 733 1313 3941 1182 1986 2671 -3108 -3282 -4744 -2059 -1619 1410 217 1029 -1533 -1690 -2206 -2974 -2093 -1216 -514 -131 28 556 1970 2404 2254 397 -505 -1308 -1039 -1026 -595 -77 877 1790 1184 1554 851 723 -1442 -1142 -1582 -540 -7 -89 -296 -520 -839 849 -421 1187 925 927 -216 -394 -772 -1167 -4151 -533 -808 -2045 -5475 900000 -2649 900000 -127 -3077 900000 -3003 -1460 -2567 900000 -1846 -1158 -529 -898 -1409 55 -192 -1950 935 -1600 639 -852 -1430 -395 227 -116 762 -1368 185 385 908 -771 805 638 415 -86 -907 26 382 105 113 1433 942 435 822 181 2487 1340 2785 247 972 1147 1306 21 663 317 1943 2010 2163 1924 1665 1469 514 1398 1297 115 -1147 1463 -351 594 -2420 -1659 -3664 -2872 -1628 -1643 238 -2527 -947 195 561 1046 3133 961 1544 1923 -2219 -2286 -3471 -1658 -1478 1425 249 1258 -1892 -1950 -2329 -2920 -2091 -1286 -566 -151 34 728 2809 3731 3621 644 -799 -1992 -1529 -1536 -925 -125 1448 2874 1837 2341 1251 1030 -2036 -1565 -2304 -874 -12 -167 -582 -1065 -1797 1891 -974 2739 2174 2148 -485 -845 -1592 -2370 SS 20240302T225526.6Z 8827.955169 255 1 2.85 2 72.14 118.03 80.27 220.29 0.00 1 0.00 1 0 17 4.604e-01 1.955e-02 2.858e-01 1.197e-02 6.417711e-01 6.184028e-03 7.746766e-03 -6.000000e+00 2.585117e-01 225.42 -2.00 3.56 -2.00 320.40 0.00e+00 1.246829e-03 2.297279e-03 3.727331e-03 -6.000000e+00 1.174943e-02 274.43 -2.00 20.00 -2.00 319.90 0.00e+00 3.216 0.001 302.00 328.00 3 3.9698e+00 1.8326e-02 4.8637e-02 -6.0000e+00 6.4302e-01 -6.4027e-02 2.3582e-02 3.8621e-02 -6.0000e+00 7.0357e-01 -3.5110e-02 2.4076e-02 2.0069e-02 -6.0000e+00 4.1296e-01 1.8309e-02 1.2150e-02 5.9057e-03 -6.0000e+00 1.7504e-01 1.9717e-04 2.4030e-04 3.1180e-04 8.7187e-05 -6.0000e+00 1.2149e-02 9.9931e-03 0.0000e+00 12 9 9 12 5 1 999.00 16.25 0.49 0.00999 0.01180 1 9 1 5 0 1422.320 19.96 15.00 16.25 3.08 2.7 810.45 -177204 900000 -199003 900000 -198873 900000 -166215 900000 900000 -119870 -1169 -137222 900000 -111955 900000 -60516 117128 -35329 -9700 -20801 7478 60602 -45272 179907 -21639 126906 -13354 57501 -35256 53796 -17291 53135 -21904 1080 13314 30322 14138 -10945 20752 -1836 23650 -8475 16249 -10979 6424 -7517 12498 3613 -1297 10789 -689 15028 2575 6712 -1405 14313 -744 14170 -2832 2716 -1007 2407 7813 5076 5524 -613 5396 -3643 -511 -601 4960 -3914 1367 -1586 -1671 -868 -2805 -4378 -6061 821 -4800 -509 -3848 -2085 -2904 166 1294 3197 3052 1534 -1308 -2708 -2822 -5498 1261 -1256 747 1374 503 1180 -1153 -2521 -1775 -569 -2234 1105 -430 79 1194 3031 2626 2559 875 -832 -1589 -454 -1624 -91 653 353 700 350 1733 1051 616 -2610 -1247 -1489 -697 -674 90 -1561 -81 -678 -290 -41 218 1786 828 1400 -44 -597 -1617 -2548 900000 -4725 900000 -4323 900000 -2786 900000 900000 -1911 -14 -3007 900000 -3123 900000 -1597 1366 -925 -217 -553 157 758 -1655 2098 -773 1480 -488 1030 -1502 1034 -790 1472 -1464 64 670 1269 760 -887 1536 -204 2340 -1222 1960 -1752 886 -1207 1700 552 -218 1725 -136 2875 601 1638 -392 3624 -223 3723 -837 751 -296 750 2621 1955 2220 -251 2089 -1560 -232 -312 2676 -2339 777 -878 -862 -402 -1251 -2011 -3119 461 -3207 -365 -3038 -1694 -2500 147 1178 2931 2791 1375 -1132 -2256 -2284 -4660 1114 -1262 821 1653 642 1485 -1402 -2859 -1882 -611 -2575 1285 -523 100 1610 4376 4053 4067 1400 -1305 -2409 -664 -2418 -139 1032 571 1114 542 2609 1549 886 -3739 -1726 -2158 -1098 -1141 161 -2901 -154 -1338 -596 -87 460 3781 1754 2858 -87 -1145 -3079 SS 20240302T230131.0Z 8827.959387 259 1 48.00 2 71.16 119.24 80.99 221.43 0.00 1 0.00 1 0 25 2.860e-01 1.243e-02 8.550e-02 1.917e-03 6.055114e-01 9.658659e-04 7.194424e-03 -6.000000e+00 1.577908e-01 225.42 -2.00 3.56 -2.00 320.40 0.00e+00 2.052392e-03 3.555797e-04 2.991790e-03 -6.000000e+00 6.812459e-03 274.43 -2.00 20.00 -2.00 319.90 0.00e+00 3.060 0.000 302.00 328.00 3 3.8346e+00 2.8512e-03 4.5131e-02 -6.0000e+00 3.9123e-01 -8.6837e-02 3.6671e-03 3.4488e-02 -6.0000e+00 4.2721e-01 2.2598e-02 3.7519e-03 1.9203e-02 -6.0000e+00 2.5372e-01 -1.4443e-02 1.8999e-03 6.4569e-03 -6.0000e+00 1.0715e-01 2.7220e-04 5.8947e-04 4.9788e-05 8.0434e-05 -6.0000e+00 7.2187e-03 1.0319e-02 0.0000e+00 12 9 8 11 4 0 97.97 16.26 0.31 0.01032 0.01475 80 21 1 5 0 599.900 19.96 15.00 16.26 3.32 2.7 813.36 -144700 -81794 -106753 -92712 -101686 15013 -98532 -47186 -56722 -102440 -77633 -106348 -14823 -54899 32271 -26312 -16326 -21358 -17620 -8369 -15916 4660 -32567 6944 -25693 5032 -18255 -10954 -26970 -5935 -12558 -2786 -3749 -3260 -3981 -10120 -5560 -5829 1777 -2178 1186 -1640 4089 2594 407 790 2254 -905 -1710 1350 1260 4183 2366 4161 1823 2942 2491 507 -1137 -929 800 1885 4336 4685 3698 350 683 -2087 306 934 1854 1406 1195 1131 -180 -2824 -4455 -5619 -4755 -2920 -2335 -916 -2398 -1659 -866 621 1472 2189 2304 1473 1468 -1248 -1834 -3029 -1405 -979 551 1341 1126 -46 -1061 -2314 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