File name: Pandora196s1_Sapporo_20240509_L2Fit_fout2c7d20240502p1-8.txt File generation date: 20240516T064505.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v7d20240502.txt Level 1 file used: Pandora196s1_Sapporo_20240509_L1_smca1c7d20240502p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20240509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration after repairs + OOB session First and last pixel inside fitting window: 208 349 Nominal wavelengths inside fitting window [nm]: 305.1398 305.2812 305.4227 305.5641 305.7055 305.8469 305.9883 306.1297 306.2710 306.4124 306.5537 306.6951 306.8364 306.9777 307.1190 307.2603 307.4016 307.5428 307.6841 307.8253 307.9666 308.1078 308.2490 308.3902 308.5314 308.6726 308.8137 308.9549 309.0960 309.2372 309.3783 309.5194 309.6605 309.8016 309.9426 310.0837 310.2247 310.3658 310.5068 310.6478 310.7888 310.9298 311.0708 311.2118 311.3527 311.4937 311.6346 311.7755 311.9164 312.0573 312.1982 312.3391 312.4799 312.6208 312.7616 312.9025 313.0433 313.1841 313.3249 313.4657 313.6064 313.7472 313.8880 314.0287 314.1694 314.3101 314.4508 314.5915 314.7322 314.8729 315.0135 315.1542 315.2948 315.4354 315.5760 315.7166 315.8572 315.9978 316.1384 316.2789 316.4195 316.5600 316.7005 316.8410 316.9815 317.1220 317.2624 317.4029 317.5433 317.6838 317.8242 317.9646 318.1050 318.2454 318.3858 318.5261 318.6665 318.8068 318.9472 319.0875 319.2278 319.3681 319.5084 319.6486 319.7889 319.9291 320.0694 320.2096 320.3498 320.4900 320.6302 320.7704 320.9105 321.0507 321.1908 321.3310 321.4711 321.6112 321.7513 321.8914 322.0314 322.1715 322.3115 322.4516 322.5916 322.7316 322.8716 323.0116 323.1516 323.2915 323.4315 323.5714 323.7114 323.8513 323.9912 324.1311 324.2709 324.4108 324.5507 324.6905 324.8304 324.9702 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240508T204724.3Z 8894.866253 82 1 3.19 2 75.30 79.75 78.79 69.37 0.00 1 0.00 1 0 17 3.875e-01 1.175e-02 1.604e-01 4.052e-03 6.627902e-01 2.181761e-03 8.120685e-03 -6.000000e+00 2.303343e-01 230.49 -2.00 3.56 -2.00 320.52 0.00e+00 6.847969e-03 8.703450e-04 4.163877e-03 -6.000000e+00 1.028549e-02 281.39 -2.00 20.00 -2.00 319.93 0.00e+00 3.861 0.001 302.00 328.00 3 1.6011e+00 6.6912e-03 5.4027e-02 -6.0000e+00 5.7557e-01 6.7135e-02 8.5588e-03 3.8823e-02 -6.0000e+00 6.2419e-01 -1.2339e-01 8.1253e-03 2.4410e-02 -6.0000e+00 3.6988e-01 4.5612e-02 4.0175e-03 1.0488e-02 -6.0000e+00 1.5428e-01 1.0497e-03 1.7439e-03 1.0951e-04 1.4336e-04 -6.0000e+00 1.0971e-02 -6.5125e-03 0.0000e+00 12 9 9 12 1 1 47.60 21.61 0.25 -0.00651 0.00659 13 52 1 5 0 226.950 25.28 20.03 21.61 11.66 2.6 884.61 -131989 -153964 2752 -169476 900000 -200194 55055 -158768 -44889 -122199 -73472 -107301 -87034 -32246 -63714 9409 -33309 52205 -54665 39961 -41641 1867 -44610 739 -10606 -19066 -15328 -12887 -10544 -24600 7140 -27796 13949 -17691 14836 -15972 9174 -6084 6661 768 -1799 2626 -1308 6751 -543 10573 -2010 9441 -2208 10994 2439 7694 4188 4196 3929 1397 3187 -425 2344 2286 5205 1853 5960 2648 4673 1301 1594 1323 859 1965 1415 318 -684 1440 -2811 -629 -4783 -2031 -3318 -1147 -2829 -1844 -1682 -573 -28 -187 1972 -36 1439 -1208 691 -2042 -1510 -1655 -630 553 654 -509 -751 -243 -1522 -5 -537 -530 -1603 -623 -266 1184 1056 1259 367 523 -93 -307 34 141 -35 -37 160 64 1211 793 681 259 -196 -852 461 -26 -448 -124 -550 -210 -112 131 1 676 233 249 -272 90 -414 -619 -1434 -2331 11 -2901 900000 -4613 217 -2979 -322 -2019 -818 -2119 -1844 -510 -1716 142 -861 637 -2061 617 -1451 43 -1746 20 -331 -671 -517 -426 -364 -1157 297 -1907 711 -1213 719 -1141 593 -555 641 89 -232 345 -171 907 -81 1462 -301 1451 -372 1795 490 1603 986 1048 1019 384 861 -116 619 623 1513 631 2197 1086 1845 526 662 553 417 1035 784 177 -363 690 -1266 -282 -2261 -958 -1887 -742 -1975 -1406 -1352 -488 -23 -166 1755 -32 1241 -1070 566 -1649 -1250 -1439 -628 586 789 -638 -941 -302 -1727 -5 -596 -595 -1905 -777 -333 1600 1511 1981 580 868 -151 -470 50 210 -54 -62 257 107 1920 1219 1011 393 -290 -1221 691 -43 -770 -232 -1038 -414 -223 280 1 1450 509 540 -593 184 -843 -1236 SS 20240508T205656.2Z 8894.872872 85 1 48.16 2 73.58 81.30 77.20 70.78 0.00 1 0.00 1 0 17 2.625e-01 8.188e-03 1.335e-02 5.510e-04 6.064274e-01 2.931727e-04 7.135093e-03 -6.000000e+00 1.553378e-01 230.49 -2.00 3.56 -2.00 320.18 0.00e+00 4.775179e-03 1.049506e-04 2.650451e-03 -6.000000e+00 6.843693e-03 281.39 -2.00 20.00 -2.00 319.56 0.00e+00 3.481 0.001 302.00 328.00 3 8.4641e-01 8.7286e-04 4.8082e-02 -6.0000e+00 3.8858e-01 1.9020e-02 1.0823e-03 3.3336e-02 -6.0000e+00 4.2138e-01 -5.5416e-02 9.8253e-04 1.9774e-02 -6.0000e+00 2.5016e-01 1.5156e-02 4.9604e-04 8.2865e-03 -6.0000e+00 1.0444e-01 3.4392e-03 1.6706e-03 1.5232e-05 9.9119e-05 -6.0000e+00 7.4275e-03 -3.8767e-03 0.0000e+00 11 8 0 10 0 0 99.87 21.62 0.21 -0.00388 0.00868 664 164 1 5 0 72.410 25.28 19.94 21.62 12.12 2.5 888.49 -93402 -91591 -81576 -99115 -86651 -100802 -74825 -83822 -75559 -78691 -76128 -62017 -46342 -30838 -25365 -19734 -17600 -12535 -15197 -7795 -13714 -13350 -14559 -13744 -14659 -15919 -17470 -18132 -14799 -13386 -6112 -4164 -3400 -6765 -6649 -7654 -3729 -3114 -834 -1288 -655 751 1407 2303 2754 2728 2411 2166 1867 3115 3175 3430 3438 2342 2053 1275 331 112 943 1599 2831 2989 3277 2326 1702 1168 399 1241 1581 846 795 222 23 -228 -1710 -2109 -3523 -2787 -2402 -2252 -1851 -2278 -1658 -620 -66 707 913 937 1200 893 510 -901 -945 -660 -401 39 129 -71 -498 -545 -1161 -532 -262 -884 -1313 -395 21 825 1243 1022 452 159 85 -307 199 315 276 28 169 86 534 650 252 88 -305 -815 227 -141 -384 -344 -630 -335 79 191 145 409 513 54 -54 -116 -517 -220 -1109 -1186 -990 -1331 -987 -1381 -880 -1220 -1116 -1272 -1305 -1146 -941 -679 -649 -548 -530 -397 -523 -263 -492 -489 -581 -586 -665 -757 -835 -866 -719 -746 -379 -291 -264 -532 -512 -647 -353 -356 -112 -197 -108 129 228 412 507 513 470 402 368 666 762 895 976 712 649 420 110 37 303 526 1007 1194 1460 1023 800 543 191 586 860 508 500 140 13 -126 -865 -1093 -1702 -1471 -1492 -1614 -1387 -1884 -1436 -569 -60 667 883 903 1114 835 450 -769 -826 -596 -414 42 159 -90 -629 -689 -1335 -601 -299 -1028 -1602 -505 29 1135 1894 1605 747 261 135 -458 302 482 415 45 280 141 838 985 392 132 -445 -1146 334 -221 -668 -614 -1185 -623 156 401 302 862 1098 116 -109 -237 -1000 -417 SS 20240508T210403.3Z 8894.877816 89 1 48.20 2 72.30 82.46 75.99 71.83 0.00 1 0.00 1 0 17 2.001e-01 8.062e-03 8.744e-03 4.390e-04 5.675164e-01 2.316854e-04 6.633100e-03 -6.000000e+00 1.184296e-01 230.49 -2.00 3.56 -2.00 319.91 0.00e+00 4.351485e-03 7.560728e-05 2.086416e-03 -6.000000e+00 5.217454e-03 281.39 -2.00 20.00 -2.00 319.27 0.00e+00 3.243 0.001 302.00 328.00 3 7.0663e-01 6.7269e-04 4.4536e-02 -6.0000e+00 2.9625e-01 9.7301e-03 8.1617e-04 3.0360e-02 -6.0000e+00 3.2126e-01 -4.2221e-02 7.0578e-04 1.7460e-02 -6.0000e+00 1.9072e-01 9.9076e-03 3.6124e-04 7.3114e-03 -6.0000e+00 7.9624e-02 5.1839e-03 1.7112e-03 1.2195e-05 8.2096e-05 -6.0000e+00 5.6625e-03 -4.1508e-03 0.0000e+00 11 8 0 10 0 0 99.69 21.65 0.26 -0.00415 0.00871 834 206 1 5 0 57.640 25.39 20.07 21.65 12.35 2.5 889.87 -76741 -68030 -63774 -67199 -64109 -78084 -59950 -72757 -54390 -63982 -52915 -48428 -30552 -24923 -16138 -14166 -11817 -7033 -8158 -4147 -9167 -5694 -9712 -9004 -12511 -10314 -14281 -11039 -11127 -7279 -4241 -3419 -3091 -5992 -5558 -6436 -2663 -2583 -301 -1655 -220 185 1109 1563 2577 2180 2112 1734 1820 2735 2559 3289 2620 2346 1609 1257 157 178 669 1509 2588 2809 3079 2074 1423 824 396 967 1638 527 809 117 108 -319 -1471 -2032 -3326 -2631 -2263 -2229 -2069 -2226 -1690 -617 -99 714 908 889 1069 850 500 -861 -821 -584 -212 29 216 -159 -545 -529 -1134 -434 -212 -875 -1217 -378 -108 775 1219 1043 479 199 52 -203 216 413 317 114 106 31 573 597 260 166 -297 -768 306 -160 -310 -413 -666 -344 88 200 174 406 453 104 -71 -97 -534 -235 -1156 -1037 -961 -969 -859 -1253 -893 -1392 -952 -1301 -1037 -1113 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