File name: Pandora196s1_Sapporo_20240606_L2Fit_fout2c7d20240502p1-8.txt File generation date: 20240606T144008.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v7d20240502.txt Level 1 file used: Pandora196s1_Sapporo_20240606_L1_smca1c7d20240502p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20240606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration after repairs + OOB session First and last pixel inside fitting window: 208 349 Nominal wavelengths inside fitting window [nm]: 305.1398 305.2812 305.4227 305.5641 305.7055 305.8469 305.9883 306.1297 306.2710 306.4124 306.5537 306.6951 306.8364 306.9777 307.1190 307.2603 307.4016 307.5428 307.6841 307.8253 307.9666 308.1078 308.2490 308.3902 308.5314 308.6726 308.8137 308.9549 309.0960 309.2372 309.3783 309.5194 309.6605 309.8016 309.9426 310.0837 310.2247 310.3658 310.5068 310.6478 310.7888 310.9298 311.0708 311.2118 311.3527 311.4937 311.6346 311.7755 311.9164 312.0573 312.1982 312.3391 312.4799 312.6208 312.7616 312.9025 313.0433 313.1841 313.3249 313.4657 313.6064 313.7472 313.8880 314.0287 314.1694 314.3101 314.4508 314.5915 314.7322 314.8729 315.0135 315.1542 315.2948 315.4354 315.5760 315.7166 315.8572 315.9978 316.1384 316.2789 316.4195 316.5600 316.7005 316.8410 316.9815 317.1220 317.2624 317.4029 317.5433 317.6838 317.8242 317.9646 318.1050 318.2454 318.3858 318.5261 318.6665 318.8068 318.9472 319.0875 319.2278 319.3681 319.5084 319.6486 319.7889 319.9291 320.0694 320.2096 320.3498 320.4900 320.6302 320.7704 320.9105 321.0507 321.1908 321.3310 321.4711 321.6112 321.7513 321.8914 322.0314 322.1715 322.3115 322.4516 322.5916 322.7316 322.8716 323.0116 323.1516 323.2915 323.4315 323.5714 323.7114 323.8513 323.9912 324.1311 324.2709 324.4108 324.5507 324.6905 324.8304 324.9702 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240605T235934.1Z 8922.999700 228 1 1.13 2 37.70 110.27 30.65 114.74 0.00 1 0.00 1 0 17 1.164e-02 8.228e-03 2.955e-03 1.722e-03 2.231581e-01 9.110704e-04 2.630708e-03 -6.000000e+00 6.937092e-03 232.42 -2.00 3.56 -2.00 315.66 0.00e+00 5.573157e-04 9.018682e-05 7.283374e-05 -6.000000e+00 3.071770e-04 284.33 -2.00 20.00 -2.00 314.96 0.00e+00 1.263 0.000 302.00 328.00 3 2.1514e+00 2.3714e-03 1.7299e-02 -6.0000e+00 1.7419e-02 1.8353e-02 2.6392e-03 1.1555e-02 -6.0000e+00 1.8852e-02 -5.2114e-03 1.5059e-03 5.5802e-03 -6.0000e+00 1.1193e-02 -4.5586e-03 6.6592e-04 1.5579e-03 -6.0000e+00 4.6672e-03 1.3324e-02 1.9164e-03 5.0084e-05 1.8230e-05 -6.0000e+00 3.2953e-04 -4.2298e-03 0.0000e+00 12 9 1 12 1 1 -138.39 22.18 0.20 -0.00423 0.01017 10 117 1 5 0 101.210 25.90 20.00 22.18 25.05 2.1 989.29 83 -2340 -1316 -4037 1044 -2806 -64 -2529 -1317 -2527 -1420 167 -63 1223 169 1261 921 2048 1315 2622 968 2310 1657 786 627 -569 -372 -515 376 -219 263 -980 -1326 -4315 -2009 -2436 -1722 -1557 -756 -1209 -697 -148 56 477 448 152 -171 -31 -148 967 674 985 971 811 1018 845 865 229 1323 1143 1831 1518 1348 -11 12 31 7 728 958 152 207 168 -152 275 -1158 -569 -2092 -1390 -2160 -2463 -2218 -2346 -1530 -681 -4 473 726 520 784 484 498 -542 461 282 -46 180 301 -89 -487 -494 -1130 -506 -280 -850 -1389 -132 -340 696 1316 1032 420 394 308 -298 280 589 604 163 222 -199 205 323 -5 409 -10 -302 508 56 -266 -87 -674 -265 247 462 11 477 460 227 -102 -410 -810 -655 21 -599 -340 -954 227 -644 -15 -678 -373 -726 -398 48 -21 428 64 493 370 848 562 1106 410 1005 730 367 303 -271 -174 -233 162 -97 120 -480 -668 -2184 -954 -1244 -931 -965 -510 -875 -511 -111 43 358 338 112 -127 -22 -106 710 516 788 794 665 846 718 734 192 1123 968 1597 1391 1276 -10 11 28 6 647 914 150 214 174 -153 265 -1077 -503 -1768 -1198 -1991 -2400 -2313 -2559 -1682 -778 -4 577 891 640 950 568 548 -575 479 301 -51 211 370 -114 -626 -611 -1328 -590 -330 -1052 -1769 -171 -449 952 1822 1467 603 550 417 -388 350 736 770 219 305 -279 283 442 -6 530 -13 -371 629 73 -352 -118 -934 -373 352 671 17 726 704 350 -156 -621 -1191 -966 SS 20240606T000815.4Z 8923.005734 235 1 4.68 2 36.23 112.52 29.25 117.33 0.00 1 0.00 1 0 17 1.369e-02 9.769e-03 7.512e-03 4.132e-03 2.250874e-01 2.183898e-03 2.615182e-03 -6.000000e+00 8.157796e-03 232.42 -2.00 3.56 -2.00 315.81 0.00e+00 6.266334e-04 2.241755e-04 1.035561e-04 -6.000000e+00 3.611701e-04 284.33 -2.00 20.00 -2.00 315.11 0.00e+00 1.239 0.000 302.00 328.00 3 4.9622e+00 5.6991e-03 1.7139e-02 -6.0000e+00 2.0485e-02 4.7366e-02 6.3490e-03 1.1553e-02 -6.0000e+00 2.2168e-02 -8.0077e-03 3.6238e-03 5.5745e-03 -6.0000e+00 1.3162e-02 -5.2787e-03 1.6157e-03 1.5621e-03 -6.0000e+00 5.4894e-03 8.0773e-04 2.1724e-03 1.2041e-04 1.7589e-05 -6.0000e+00 3.8746e-04 -5.4874e-03 0.0000e+00 12 9 9 12 1 1 999.00 22.20 0.44 -0.00549 0.01084 2 8 1 5 0 1556.370 25.90 20.00 22.20 26.04 2.1 997.70 -3214 -670 -1833 458 2116 -1704 2450 -3668 -1281 -4637 -156 -446 -1267 940 147 -721 1004 1025 3371 1275 1531 3612 34 632 -271 195 -1008 811 -865 -632 -1290 524 -2444 -3226 -3614 -2078 -2172 4 -1306 -1255 -422 -11 -150 -194 625 -53 659 -1076 701 634 1169 359 685 1764 1802 1910 160 1242 1121 2292 1505 2424 1223 562 -294 -128 -320 164 988 -494 776 174 1050 -266 -1133 -2086 -3630 -2200 -2561 -2245 -1929 -2413 -2059 -766 -477 1089 798 805 678 868 103 -857 -853 -402 20 533 685 6 -505 -1045 -724 -929 580 -310 -763 -843 -791 599 1318 1112 881 546 -51 336 -265 765 362 619 -187 281 260 436 168 519 769 -816 122 -278 -313 -653 -226 -378 349 662 160 -14 407 78 -17 -193 -807 -745 -755 -158 -429 96 417 -354 519 -919 -325 -1219 -40 -121 -391 311 53 -273 383 408 1343 523 619 1472 15 283 -123 91 -453 342 -357 -268 -571 241 -1198 -1540 -1663 -1007 -1172 2 -876 -883 -308 -9 -111 -146 469 -39 480 -779 492 462 887 282 549 1440 1491 1612 137 1034 929 1921 1324 2224 1176 537 -272 -112 -275 143 930 -502 796 180 1060 -261 -1052 -1809 -3076 -1889 -2365 -2199 -1989 -2622 -2275 -880 -564 1336 992 999 829 1016 116 -900 -880 -427 23 635 847 8 -643 -1304 -862 -1077 675 -382 -970 -1105 -1063 814 1857 1612 1284 774 -70 435 -331 952 463 829 -260 397 361 599 226 669 965 -1016 149 -359 -415 -891 -312 -533 500 972 242 -22 633 122 -26 -290 -1195 -1106 SS 20240606T005101.8Z 8923.035437 263 1 19.74 2 29.39 125.74 22.95 133.26 0.00 1 0.00 1 0 17 1.211e-02 8.732e-03 3.748e-03 2.138e-03 2.101421e-01 1.130058e-03 2.452570e-03 -6.000000e+00 7.216062e-03 232.42 -2.00 3.56 -2.00 315.69 0.00e+00 4.130146e-04 1.129922e-04 1.105075e-04 -6.000000e+00 3.196156e-04 284.33 -2.00 20.00 -2.00 315.00 0.00e+00 1.147 0.000 302.00 328.00 3 5.4600e+00 2.9453e-03 1.5944e-02 -6.0000e+00 1.8120e-02 4.6723e-02 3.2784e-03 1.0783e-02 -6.0000e+00 1.9612e-02 -5.2811e-03 1.8699e-03 5.2077e-03 -6.0000e+00 1.1644e-02 -6.6885e-03 8.2921e-04 1.4260e-03 -6.0000e+00 4.8540e-03 5.5294e-04 1.8345e-03 6.2469e-05 1.6836e-05 -6.0000e+00 3.4283e-04 -2.7045e-03 0.0000e+00 12 9 1 12 1 1 99.93 22.25 0.24 -0.00270 0.01108 9 6 1 5 0 1972.970 26.00 19.99 22.25 26.50 2.0 1000.31 -1188 -351 -1160 -1569 2023 -2047 3370 -1026 -1903 -2902 -3020 314 -1126 2753 -737 305 -107 2373 757 1916 659 1217 1453 354 865 -588 -1699 543 264 358 -37 -496 -1999 -3579 -2790 -3144 -1829 -1607 -713 -1313 -241 -423 169 52 563 208 -475 -368 514 1087 1259 1173 1219 461 1118 1491 948 988 1324 1384 2081 1506 989 374 268 -188 -327 359 719 -138 721 -64 85 -1 -995 -963 -2475 -2229 -2022 -2071 -2297 -2777 -1268 -644 66 927 616 490 917 507 342 -969 -627 -197 -393 337 229 20 -509 -301 -1258 -655 -100 -269 -1213 -332 -201 861 842 1011 771 490 91 -267 110 562 483 374 388 35 405 283 78 660 150 -759 126 -343 -87 -418 -766 -514 349 659 469 669 234 189 -108 -190 -1049 -765 -295 -89 -289 -360 416 -444 758 -260 -519 -799 -819 90 -354 934 -277 118 -43 957 317 822 283 520 646 162 406 -282 -781 234 112 156 -17 -237 -997 -1755 -1302 -1575 -1002 -983 -478 -947 -180 -326 127 40 431 156 -347 -268 366 798 960 936 995 389 951 1257 801 841 1117 1193 1849 1409 959 366 248 -165 -283 313 691 -139 747 -67 86 -1 -924 -828 -2081 -1917 -1844 -2042 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