File name: Pandora196s1_Sapporo_20240609_L2Fit_fout2c8d20240502p1-8.txt File generation date: 20241002T105038.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v8d20240502.txt Level 1 file used: Pandora196s1_Sapporo_20240609_L1_smca1c8d20240502p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20240609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 349 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1606 305.3019 305.4432 305.5845 305.7258 305.8670 306.0083 306.1495 306.2907 306.4320 306.5732 306.7144 306.8555 306.9967 307.1379 307.2790 307.4202 307.5613 307.7024 307.8435 307.9846 308.1257 308.2668 308.4078 308.5489 308.6899 308.8310 308.9720 309.1130 309.2540 309.3950 309.5359 309.6769 309.8178 309.9588 310.0997 310.2406 310.3815 310.5224 310.6633 310.8042 310.9450 311.0859 311.2267 311.3675 311.5084 311.6492 311.7900 311.9307 312.0715 312.2123 312.3530 312.4937 312.6345 312.7752 312.9159 313.0566 313.1973 313.3379 313.4786 313.6192 313.7599 313.9005 314.0411 314.1817 314.3223 314.4629 314.6034 314.7440 314.8845 315.0251 315.1656 315.3061 315.4466 315.5871 315.7276 315.8680 316.0085 316.1489 316.2893 316.4298 316.5702 316.7106 316.8510 316.9913 317.1317 317.2720 317.4124 317.5527 317.6930 317.8333 317.9736 318.1139 318.2542 318.3944 318.5347 318.6749 318.8151 318.9554 319.0956 319.2358 319.3759 319.5161 319.6563 319.7964 319.9365 320.0767 320.2168 320.3569 320.4970 320.6370 320.7771 320.9172 321.0572 321.1972 321.3372 321.4773 321.6173 321.7572 321.8972 322.0372 322.1771 322.3171 322.4570 322.5969 322.7368 322.8767 323.0166 323.1565 323.2963 323.4362 323.5760 323.7158 323.8556 323.9954 324.1352 324.2750 324.4148 324.5545 324.6943 324.8340 324.9737 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240608T222921.9Z 8925.937059 163 1 47.82 2 53.77 91.33 75.90 66.73 0.00 1 0.00 1 0 25 1.308e-01 1.831e-02 4.715e-02 6.792e-03 2.841102e-01 3.406323e-03 3.368470e-03 -6.000000e+00 7.452169e-02 232.61 -2.00 3.56 -2.00 318.37 0.00e+00 1.575972e-04 6.447630e-04 6.648586e-04 -6.000000e+00 3.304310e-03 284.63 -2.00 20.00 -2.00 317.57 0.00e+00 1.688 0.000 302.00 328.00 3 7.0204e+00 9.2955e-03 2.2828e-02 -6.0000e+00 1.8713e-01 7.8303e-03 1.0576e-02 1.5280e-02 -6.0000e+00 2.0283e-01 4.4929e-02 6.8489e-03 7.2858e-03 -6.0000e+00 1.2025e-01 -3.1581e-02 3.5218e-03 1.9801e-03 -6.0000e+00 5.0447e-02 5.9896e-05 3.2054e-04 1.9010e-04 1.8454e-05 -6.0000e+00 3.3057e-03 3.2209e-03 0.0000e+00 12 9 8 11 8 0 99.97 22.56 0.75 0.00322 0.00563 60 15 1 5 0 796.800 26.32 20.00 22.56 24.48 2.2 985.62 -14626 2254 -20463 23474 -2321 900000 -6637 133457 -1687 13479 -7967 -1821 -3403 -1307 46927 -9812 -542 -8315 12412 -10941 538 -6000 1759 -6548 9833 1343 -5076 -4305 -533 7114 3493 7804 -8150 -1709 -7109 -905 -11614 2264 -5757 6332 -1595 737 1006 -1464 -19 2579 5859 -1433 -786 -2480 3498 -2393 2202 2485 -989 3844 1827 -106 520 183 280 3711 772 5044 389 1787 77 -350 -587 1825 -155 -270 596 1209 289 -2502 1786 -7576 -3160 -5795 -2232 -3032 -3851 -1079 -700 489 599 2813 1216 2745 1390 -359 -5289 -2592 -1646 -178 338 2674 1700 933 -39 -2104 -3458 -1681 -988 -1065 183 -1514 2441 1046 1920 365 1384 71 -1754 -1535 -2562 -532 -755 2451 2068 936 605 22 108 277 -2174 1 -1684 -305 824 -976 -468 -275 1734 -829 1349 343 600 386 479 -2195 -710 -918 136 -1609 1184 -133 900000 -394 2376 -121 911 -659 -143 -305 -132 3475 -1405 -75 -1290 1668 -1909 87 -1034 285 -1231 1679 260 -1065 -855 -95 1149 625 1456 -1942 -405 -1667 -191 -2958 584 -1921 2231 -668 316 445 -673 -9 1147 2502 -642 -344 -1104 1567 -1221 1137 1357 -576 2189 1088 -64 306 107 168 2310 537 3623 295 1232 50 -225 -398 1379 -131 -237 519 1015 229 -1836 1147 -5020 -2119 -4479 -1863 -2809 -3812 -1082 -752 554 708 3356 1478 3176 1510 -367 -5178 -2413 -1623 -191 396 3384 2288 1242 -50 -2496 -3932 -1963 -1237 -1401 246 -2159 3519 1627 3109 606 2192 106 -2481 -2056 -3485 -739 -1124 3768 3208 1450 916 33 150 371 -2837 1 -2396 -456 1270 -1557 -756 -460 3036 -1537 2501 658 1150 721 866 -3916 -1235 SS 20240608T223723.3Z 8925.942631 169 1 48.23 2 52.31 92.74 74.60 67.90 0.00 1 0.00 1 0 33 1.938e-02 1.241e-02 5.093e-03 1.341e-03 2.616059e-01 6.706979e-04 3.097088e-03 -6.000000e+00 1.099963e-02 232.61 -2.00 3.56 -2.00 317.67 0.00e+00 1.110205e-03 1.053227e-04 4.560396e-04 -6.000000e+00 4.819718e-04 284.63 -2.00 20.00 -2.00 316.87 0.00e+00 1.632 0.000 302.00 328.00 3 4.7302e+00 1.8018e-03 2.1459e-02 -6.0000e+00 2.7651e-02 -1.6613e-02 2.0316e-03 1.3703e-02 -6.0000e+00 2.9964e-02 2.1503e-02 1.2418e-03 6.6720e-03 -6.0000e+00 1.7798e-02 -1.9337e-02 6.1975e-04 1.8883e-03 -6.0000e+00 7.4835e-03 6.6199e-04 3.6603e-04 3.6881e-05 1.7394e-05 -6.0000e+00 4.8996e-04 1.6778e-04 0.0000e+00 12 8 8 10 0 0 100.00 22.56 0.16 0.00017 0.00292 193 48 1 5 0 249.850 26.32 20.00 22.56 24.51 2.1 985.30 -2447 1587 -2149 293 -6508 5470 -5206 4717 -2653 -1021 -4557 -4178 -2305 -1538 3631 804 205 -1435 2460 58 2232 -483 1653 -35 1101 285 -412 -1565 -2923 -1481 -412 513 -684 -512 -5359 -4844 -5197 -2113 -1722 808 -233 217 415 -207 505 680 495 -484 -476 -1171 1105 458 1570 1414 832 1377 970 618 -225 29 242 1738 2120 3644 1377 -2 -1362 -2115 -526 809 1120 1501 1307 728 181 -1652 -2320 -4920 -3373 -3183 -2098 -1741 -2348 -1763 -559 290 906 1803 1920 1741 709 -553 -2026 -2127 -1540 -635 198 1782 1286 241 -614 -1981 -2356 -1182 -872 -969 -340 -296 857 1470 1966 1453 1223 149 -1055 -1059 -1485 -648 -100 1029 638 1113 948 495 209 -841 -1333 -674 -469 -477 -339 -709 -848 -398 399 203 909 998 860 355 -137 -937 -1117 -208 146 -215 28 -580 407 -450 412 -279 -114 -521 -477 -289 -220 570 145 39 -288 498 13 486 -107 363 -8 269 73 -108 -398 -701 -343 -100 133 -196 -154 -1586 -1364 -1580 -715 -689 369 -117 113 222 -113 274 371 267 -258 -251 -618 597 267 947 897 549 919 660 421 -152 19 166 1254 1637 2962 1142 -2 -1010 -1539 -395 673 1008 1396 1218 663 157 -1334 -1722 -3561 -2511 -2628 -1886 -1689 -2410 -1859 -616 336 1095 2216 2368 2083 806 -592 -2049 -2094 -1581 -702 236 2284 1723 321 -780 -2387 -2737 -1407 -1105 -1274 -460 -415 1237 2211 3070 2299 1880 219 -1462 -1409 -1981 -894 -146 1557 979 1681 1408 714 291 -1142 -1744 -890 -653 -698 -513 -1094 -1323 -641 667 352 1592 1779 1540 622 -235 -1575 -1860 SS 20240608T230427.3Z 8925.961427 187 1 48.11 2 47.39 97.75 70.13 71.84 0.00 1 0.00 1 0 25 1.637e-02 1.264e-02 2.739e-03 1.006e-03 2.406062e-01 5.035706e-04 2.845113e-03 -6.000000e+00 9.288955e-03 232.61 -2.00 3.56 -2.00 316.91 0.00e+00 1.085482e-03 6.559273e-05 2.941565e-04 -6.000000e+00 4.070137e-04 284.63 -2.00 20.00 -2.00 316.15 0.00e+00 1.475 0.000 302.00 328.00 3 4.5555e+00 1.3360e-03 1.9504e-02 -6.0000e+00 2.3351e-02 5.0182e-03 1.4975e-03 1.2518e-02 -6.0000e+00 2.5304e-02 1.2354e-02 8.7999e-04 6.0660e-03 -6.0000e+00 1.5030e-02 -1.5785e-02 4.2340e-04 1.7170e-03 -6.0000e+00 6.3198e-03 9.4515e-04 2.7598e-04 2.7278e-05 1.6464e-05 -6.0000e+00 4.1376e-04 4.8720e-05 0.0000e+00 12 8 8 10 0 0 99.99 22.58 0.33 0.00005 0.00212 145 36 1 5 0 331.720 26.32 20.00 22.58 24.96 2.2 989.08 -704 -369 -291 -1682 -3689 -1929 -2529 939 -964 -712 -4385 -3762 -2447 -918 2609 1324 151 578 1500 1760 1484 466 809 1439 374 816 -102 -1166 -2389 -1658 -513 -321 652 -760 -4205 -5458 -4587 -2474 -1088 386 88 225 321 206 599 731 418 -323 -1319 -513 527 845 1229 1568 1094 1257 999 322 -333 -231 362 1546 2486 3140 1213 -276 -1139 -2212 -481 857 1250 1532 1135 1153 31 -1430 -2681 -4654 -3891 -3100 -2203 -1635 -2352 -1668 -592 191 933 1781 2104 1537 929 -462 -1815 -2291 -1446 -875 242 1639 1299 323 -463 -1835 -2364 -1121 -998 -726 -541 -174 808 1489 2106 1603 1171 211 -955 -1268 -1395 -612 263 896 791 920 974 491 375 -742 -1309 -845 -542 -466 -303 -675 -863 -180 274 307 755 994 780 275 -149 -888 -1108 -88 -52 -42 -239 -467 -230 -314 125 -143 -113 -710 -620 -426 -181 569 328 40 155 417 506 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