File name: Pandora196s1_Sapporo_20240625_L2Fit_fout2c8d20240502p1-8.txt File generation date: 20241002T110426.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v8d20240502.txt Level 1 file used: Pandora196s1_Sapporo_20240625_L1_smca1c8d20240502p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20240625 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 349 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1606 305.3019 305.4432 305.5845 305.7258 305.8670 306.0083 306.1495 306.2907 306.4320 306.5732 306.7144 306.8555 306.9967 307.1379 307.2790 307.4202 307.5613 307.7024 307.8435 307.9846 308.1257 308.2668 308.4078 308.5489 308.6899 308.8310 308.9720 309.1130 309.2540 309.3950 309.5359 309.6769 309.8178 309.9588 310.0997 310.2406 310.3815 310.5224 310.6633 310.8042 310.9450 311.0859 311.2267 311.3675 311.5084 311.6492 311.7900 311.9307 312.0715 312.2123 312.3530 312.4937 312.6345 312.7752 312.9159 313.0566 313.1973 313.3379 313.4786 313.6192 313.7599 313.9005 314.0411 314.1817 314.3223 314.4629 314.6034 314.7440 314.8845 315.0251 315.1656 315.3061 315.4466 315.5871 315.7276 315.8680 316.0085 316.1489 316.2893 316.4298 316.5702 316.7106 316.8510 316.9913 317.1317 317.2720 317.4124 317.5527 317.6930 317.8333 317.9736 318.1139 318.2542 318.3944 318.5347 318.6749 318.8151 318.9554 319.0956 319.2358 319.3759 319.5161 319.6563 319.7964 319.9365 320.0767 320.2168 320.3569 320.4970 320.6370 320.7771 320.9172 321.0572 321.1972 321.3372 321.4773 321.6173 321.7572 321.8972 322.0372 322.1771 322.3171 322.4570 322.5969 322.7368 322.8767 323.0166 323.1565 323.2963 323.4362 323.5760 323.7158 323.8556 323.9954 324.1352 324.2750 324.4148 324.5545 324.6943 324.8340 324.9737 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240624T210613.0Z 8941.879318 231 1 25.27 2 69.18 76.95 84.47 231.75 0.00 1 0.00 1 0 17 5.240e-02 1.248e-02 1.092e-02 1.059e-03 4.141562e-01 5.324722e-04 4.902648e-03 -6.000000e+00 2.977546e-02 233.00 -2.00 3.56 -2.00 318.94 0.00e+00 1.252935e-03 1.245349e-04 1.231182e-03 -6.000000e+00 1.311165e-03 286.14 -2.00 20.00 -2.00 318.16 0.00e+00 2.786 0.000 302.00 328.00 3 2.6093e+00 1.4802e-03 3.5814e-02 -6.0000e+00 7.4885e-02 -3.6905e-02 1.7095e-03 2.2567e-02 -6.0000e+00 8.1106e-02 2.2162e-02 1.2424e-03 1.0968e-02 -6.0000e+00 4.8202e-02 -1.6729e-02 6.5542e-04 2.9962e-03 -6.0000e+00 2.0279e-02 1.4704e-03 2.7815e-04 2.8486e-05 2.8752e-05 -6.0000e+00 1.3246e-03 6.9386e-04 0.0000e+00 12 9 9 12 1 1 99.98 22.68 0.32 0.00069 0.00278 108 51 1 5 0 231.720 26.41 20.00 22.68 25.82 2.2 994.52 -22532 -17908 -13972 -15873 -16531 -17022 -15030 -12286 -10950 -19298 -9209 -17961 -8554 -9455 3232 -1388 -2319 688 -504 121 -667 -987 -2383 845 -951 176 -2588 -2634 -5682 -3266 -2488 -1975 -1311 -2450 -5690 -7487 -5268 -3301 -170 1141 522 84 942 800 1082 1238 991 199 -1109 -249 451 1037 1446 2014 1370 2081 1092 835 -112 17 531 1626 2868 3761 1945 -93 -783 -2296 -151 1062 1599 1648 1152 1063 -195 -1862 -3427 -5297 -4154 -2951 -2229 -1611 -2398 -1821 -606 349 1278 1757 2239 1692 1024 -684 -1861 -2463 -1542 -1099 329 1471 1324 308 -662 -2007 -2314 -983 -896 -706 -462 53 755 1603 2014 1537 978 28 -1192 -1160 -1123 -417 321 871 823 1089 1194 495 258 -936 -1574 -766 -495 -415 -421 -742 -973 -349 349 280 785 1143 771 326 -234 -776 -928 -607 -538 -436 -498 -466 -455 -419 -378 -381 -801 -351 -773 -394 -534 194 -102 -188 58 -46 12 -67 -99 -248 92 -113 22 -341 -333 -697 -393 -331 -297 -221 -452 -1024 -1314 -990 -713 -39 316 163 28 326 284 384 445 358 72 -411 -93 182 459 685 935 672 1044 570 438 -58 9 277 912 1765 2528 1263 -62 -501 -1480 -103 763 1264 1363 955 845 -145 -1259 -2324 -3542 -2952 -2223 -1909 -1432 -2320 -1835 -605 371 1420 2006 2552 1864 1048 -701 -1793 -2365 -1599 -1197 399 1871 1809 417 -846 -2515 -2700 -1174 -1098 -907 -622 75 1066 2449 3118 2450 1524 43 -1743 -1607 -1568 -609 499 1346 1276 1737 1850 739 368 -1374 -2211 -1102 -739 -675 -691 -1266 -1711 -608 646 518 1474 2187 1480 604 -439 -1394 -1637 SS 20240624T211550.7Z 8941.886003 234 1 17.94 2 67.47 78.45 85.79 233.46 0.00 1 0.00 1 0 41 3.989e-02 1.263e-02 3.282e-03 4.459e-04 3.857436e-01 2.240552e-04 4.553710e-03 -6.000000e+00 2.266641e-02 233.00 -2.00 3.56 -2.00 318.53 0.00e+00 1.386725e-03 4.581293e-05 9.203432e-04 -6.000000e+00 9.981405e-04 286.14 -2.00 20.00 -2.00 317.73 0.00e+00 2.588 0.000 302.00 328.00 3 8.4882e-01 6.1449e-04 3.3166e-02 -6.0000e+00 5.7006e-02 -4.1512e-02 7.0238e-04 2.0609e-02 -6.0000e+00 6.1742e-02 1.8633e-02 4.7551e-04 1.0045e-02 -6.0000e+00 3.6694e-02 -1.5150e-02 2.4823e-04 2.8104e-03 -6.0000e+00 1.5437e-02 1.0773e-02 2.9775e-04 1.2009e-05 2.6077e-05 -6.0000e+00 1.0084e-03 1.0085e-03 0.0000e+00 12 9 9 12 1 1 99.63 22.69 0.31 0.00101 0.00325 419 279 1 5 0 42.480 26.41 20.00 22.69 26.29 2.2 998.88 -11173 -7996 -7055 -11589 -14243 -17566 -13998 -12604 -9008 -10402 -11911 -11205 -7385 -4488 -773 353 -352 1354 381 1849 754 58 149 1116 -372 496 -1289 -2220 -4556 -3385 -1429 -930 471 -1834 -5290 -7068 -5530 -3449 -577 731 544 380 1180 853 1370 1296 714 252 -972 -666 537 1109 1357 1928 1252 1544 1154 640 -101 -105 633 1788 2898 3845 1885 -337 -1188 -2226 -400 828 1566 1696 1218 1014 -160 -1845 -3386 -4862 -3946 -2956 -2154 -1535 -2368 -1825 -604 331 1208 1832 2310 1661 875 -498 -1879 -2389 -1614 -946 317 1599 1282 195 -664 -1959 -2424 -898 -941 -773 -480 42 817 1630 2033 1686 1011 32 -1149 -1186 -1014 -447 351 858 717 1046 1122 477 250 -978 -1372 -701 -519 -417 -443 -689 -959 -277 182 304 755 1147 775 279 -171 -774 -954 -408 -328 -308 -520 -583 -700 -570 -572 -450 -576 -676 -649 -480 -342 -68 36 -39 156 47 238 102 8 21 164 -59 83 -225 -374 -736 -541 -247 -180 92 -395 -1109 -1587 -1215 -868 -172 259 198 146 472 350 560 538 297 105 -410 -285 245 552 722 1009 691 872 674 376 -58 -60 369 1119 1987 2662 1363 -232 -837 -1564 -275 651 1261 1428 1029 822 -130 -1366 -2493 -3500 -2798 -2404 -1852 -1470 -2312 -1854 -652 358 1366 2127 2680 1865 970 -514 -1940 -2445 -1669 -1096 385 2039 1757 265 -849 -2443 -2826 -1071 -1163 -1003 -651 57 1165 2382 3176 2702 1581 47 -1668 -1631 -1403 -647 542 1327 1118 1584 1740 713 357 -1349 -1907 -997 -767 -636 -720 -1106 -1585 -478 320 559 1411 2093 1419 516 -303 -1386 -1680 SS 20240624T212050.7Z 8941.889475 238 1 9.73 2 66.57 79.23 86.49 234.34 0.00 1 0.00 1 0 25 3.732e-02 1.292e-02 1.204e-02 1.713e-03 3.761022e-01 8.612592e-04 4.426631e-03 -6.000000e+00 2.120734e-02 233.00 -2.00 3.56 -2.00 318.45 0.00e+00 1.168777e-03 1.733426e-04 8.866065e-04 -6.000000e+00 9.338896e-04 286.15 -2.00 20.00 -2.00 317.66 0.00e+00 2.496 0.000 302.00 328.00 3 2.9741e+00 2.3589e-03 3.2121e-02 -6.0000e+00 5.3336e-02 -3.2083e-02 2.6877e-03 2.0078e-02 -6.0000e+00 5.7768e-02 1.8449e-02 1.8007e-03 9.7594e-03 -6.0000e+00 3.4332e-02 -1.4780e-02 9.3877e-04 2.6971e-03 -6.0000e+00 1.4443e-02 1.4145e-03 3.7920e-04 4.6394e-05 2.5089e-05 -6.0000e+00 9.4348e-04 1.0075e-03 0.0000e+00 12 9 9 12 1 1 99.75 22.70 0.39 0.00101 0.00386 28 36 1 5 0 335.250 26.41 20.00 22.70 26.84 2.1 1004.04 -2017 -17176 -1761 -15959 -13744 -4320 -17943 -4614 -8972 -5944 -11944 -5539 -10234 -57 -24 2398 -1090 472 937 -580 1679 -267 1496 697 776 -564 -185 -2650 -2586 -5169 -2122 -959 1068 -2431 -5131 -6057 -5706 -913 -1482 1407 94 1011 717 746 706 1594 863 -77 -1253 -1066 687 687 1809 1891 1547 926 1090 413 229 -689 742 1613 2897 3569 1568 -69 -1415 -2062 -636 1163 1319 1859 866 1029 -142 -2032 -3336 -5316 -3760 -3215 -2027 -1251 -2260 -1873 -684 146 1262 1887 2444 1619 881 -384 -2342 -2809 -1602 -734 82 1810 1108 207 -665 -1666 -2493 -569 -822 -782 -482 -91 1032 1595 2149 1606 1042 84 -979 -1434 -886 -579 337 957 624 1113 1091 479 43 -649 -1711 -501 -667 -505 -503 -892 -997 -260 146 307 938 973 854 465 -100 -807 -1048 -73 -838 -79 -808 -604 -162 -818 -208 -483 -339 -728 -325 -730 -4 -2 250 -127 57 121 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