File name: Pandora196s1_Sapporo_20240703_L2Fit_fout2c7d20240502p1-8.txt File generation date: 20240703T144731.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v7d20240502.txt Level 1 file used: Pandora196s1_Sapporo_20240703_L1_smca1c7d20240502p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20240703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration after repairs + OOB session First and last pixel inside fitting window: 208 349 Nominal wavelengths inside fitting window [nm]: 305.1398 305.2812 305.4227 305.5641 305.7055 305.8469 305.9883 306.1297 306.2710 306.4124 306.5537 306.6951 306.8364 306.9777 307.1190 307.2603 307.4016 307.5428 307.6841 307.8253 307.9666 308.1078 308.2490 308.3902 308.5314 308.6726 308.8137 308.9549 309.0960 309.2372 309.3783 309.5194 309.6605 309.8016 309.9426 310.0837 310.2247 310.3658 310.5068 310.6478 310.7888 310.9298 311.0708 311.2118 311.3527 311.4937 311.6346 311.7755 311.9164 312.0573 312.1982 312.3391 312.4799 312.6208 312.7616 312.9025 313.0433 313.1841 313.3249 313.4657 313.6064 313.7472 313.8880 314.0287 314.1694 314.3101 314.4508 314.5915 314.7322 314.8729 315.0135 315.1542 315.2948 315.4354 315.5760 315.7166 315.8572 315.9978 316.1384 316.2789 316.4195 316.5600 316.7005 316.8410 316.9815 317.1220 317.2624 317.4029 317.5433 317.6838 317.8242 317.9646 318.1050 318.2454 318.3858 318.5261 318.6665 318.8068 318.9472 319.0875 319.2278 319.3681 319.5084 319.6486 319.7889 319.9291 320.0694 320.2096 320.3498 320.4900 320.6302 320.7704 320.9105 321.0507 321.1908 321.3310 321.4711 321.6112 321.7513 321.8914 322.0314 322.1715 322.3115 322.4516 322.5916 322.7316 322.8716 323.0116 323.1516 323.2915 323.4315 323.5714 323.7114 323.8513 323.9912 324.1311 324.2709 324.4108 324.5507 324.6905 324.8304 324.9702 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240702T201846.3Z 8949.846369 160 1 46.23 2 78.04 69.67 47.08 96.15 0.00 1 0.00 1 0 17 4.641e-01 2.562e-02 2.503e-01 8.465e-03 6.469819e-01 4.746045e-03 8.490414e-03 -6.000000e+00 2.820745e-01 233.03 -2.00 3.56 -2.00 321.13 0.00e+00 2.766826e-03 2.251761e-03 7.974288e-03 -6.000000e+00 1.289587e-02 286.87 -2.00 20.00 -2.00 320.49 0.00e+00 4.676 0.002 302.00 328.00 3 4.4625e+00 1.6275e-02 6.9680e-02 -6.0000e+00 7.0940e-01 2.1221e-01 2.1842e-02 6.2962e-02 -6.0000e+00 7.6853e-01 -3.1090e-01 1.9553e-02 2.8545e-02 -6.0000e+00 4.5283e-01 1.0798e-01 9.1595e-03 5.6999e-03 -6.0000e+00 1.8833e-01 2.8753e-05 3.5070e-03 2.4704e-04 1.4605e-04 -6.0000e+00 1.3465e-02 -1.6788e-02 0.0000e+00 12 8 8 10 0 0 87.41 22.80 0.57 -0.01679 0.00956 12 3 1 5 0 3851.430 26.51 20.00 22.80 24.32 2.3 983.52 17535 -160224 900000 -113755 900000 -123187 900000 -179972 -93675 -2843 -128562 -48062 -66450 900000 -108674 -75904 -73258 232756 -9278 30985 -82911 -29612 11273 37657 -5620 -100521 -76658 55006 158065 17138 -19107 12982 -18744 6191 900000 -6092 88020 -7051 39131 -9792 9243 12773 6447 -441 47935 73641 29807 8559 18653 43626 39410 26318 36036 -6745 33815 3885 2741 20787 29388 17860 14588 5452 4840 -1568 11678 20365 6384 7692 3114 -971 -3091 -848 -7656 3270 -7135 10943 -11776 -2885 -5217 -2857 -4135 -7487 1192 -5751 407 1735 5239 -3480 -442 4909 -3851 -1381 -1192 -1325 995 3305 -2960 131 -1154 -741 -5018 1498 -4043 2588 901 1149 -3110 3511 -1270 368 -408 1999 329 34 -26 2191 216 -2778 1914 1423 151 -96 243 1273 2111 -1091 339 -1259 -676 1383 -2153 71 154 1803 -383 934 -827 -710 675 -74 -1088 -48 145 -3319 900000 -1407 900000 -1651 900000 -5305 -1307 -23 -2809 -589 -1236 900000 -4525 -2648 -2726 1919 -213 498 -4014 -880 240 662 -160 -7375 -4441 858 1303 470 -871 503 -1082 277 900000 -326 2138 -523 2250 -1011 848 1192 660 -49 3429 4136 2670 990 2062 4132 4374 3625 4899 -1452 5170 807 576 3646 4657 3252 2991 1339 1339 -493 3137 5083 1835 2373 1164 -414 -1371 -375 -3429 1210 -2633 3243 -4298 -1066 -2338 -1448 -2360 -4871 751 -4061 295 1274 3818 -2757 -337 3309 -2673 -898 -798 -996 823 3057 -3232 151 -1342 -806 -5157 1366 -3961 2572 930 1255 -3800 4290 -1778 558 -640 3120 504 50 -38 3137 322 -4526 3090 2280 236 -146 363 1812 2897 -1491 485 -2026 -1181 2580 -4306 147 331 3993 -909 2217 -1993 -1699 1553 -165 -2329 -100 SS 20240702T202417.3Z 8949.850200 163 1 48.21 2 77.09 70.54 46.10 97.15 0.00 1 0.00 1 0 17 4.252e-01 2.206e-02 1.511e-01 6.503e-03 6.052686e-01 3.568734e-03 7.597553e-03 -6.000000e+00 2.541142e-01 233.03 -2.00 3.56 -2.00 320.91 0.00e+00 5.355204e-03 1.567824e-03 5.194213e-03 -6.000000e+00 1.153073e-02 286.87 -2.00 20.00 -2.00 320.24 0.00e+00 4.357 0.002 302.00 328.00 3 4.4262e+00 1.1756e-02 5.8262e-02 -6.0000e+00 6.3846e-01 1.8759e-01 1.5214e-02 4.2724e-02 -6.0000e+00 6.9039e-01 -3.2174e-01 1.3020e-02 2.3236e-02 -6.0000e+00 4.1071e-01 1.2457e-01 6.2263e-03 7.2354e-03 -6.0000e+00 1.7201e-01 4.2460e-05 1.9073e-03 1.8896e-04 1.3202e-04 -6.0000e+00 1.2144e-02 -4.8236e-03 0.0000e+00 12 9 8 11 8 0 98.29 22.81 0.39 -0.00482 0.00951 16 4 1 5 0 3012.590 26.51 20.00 22.81 24.61 2.2 985.63 -68460 -103403 900000 -97140 -183467 -109571 -125028 -158362 -92215 -143741 -56871 -74475 -32546 900000 -62368 -40972 -15151 60778 -9627 72204 -60070 -13387 5613 142433 -32370 -59320 -62913 26133 21700 14025 105 13886 4112 -10677 171546 -32775 35689 -7457 29330 -6515 17710 4678 -2106 -3173 36451 44402 11926 13835 18321 28857 14032 22199 15390 5107 18053 6556 6411 16256 15234 10716 20711 6412 6628 -3077 12414 11103 5964 -723 2880 -129 -706 -638 -5667 1888 -7074 6143 -11021 -4135 -5765 -4083 -4195 -5826 -3205 -3073 -2285 310 4475 -2111 1283 3035 -1333 -1814 -62 -2161 897 975 -92 -628 -1233 -1567 -2462 1031 -1773 1263 -367 1513 -2020 1323 -120 619 -979 1232 -103 -44 142 646 -74 -1163 1092 2285 1231 332 785 274 1737 -1650 -181 -734 -720 707 -1276 -307 132 1875 -193 1045 -36 -648 96 -444 -1436 32 -868 -2015 900000 -1632 -6694 -1997 -2892 -5646 -1873 -4943 -897 -1707 -619 900000 -2392 -1432 -446 933 -304 1072 -3212 -464 170 1196 -1577 -3760 -4039 712 643 517 5 669 242 -703 1873 -2815 1834 -690 2231 -797 1820 577 -287 -440 3590 4100 1522 1798 2390 3701 2331 3681 2955 1145 3665 1536 1501 3365 3151 2384 4550 1821 2095 -1109 3816 3391 1959 -268 1187 -60 -344 -309 -2736 780 -2878 2101 -4487 -1731 -2823 -2270 -2589 -4016 -2269 -2273 -1789 249 3546 -1782 1013 2252 -972 -1269 -44 -1737 786 951 -103 -750 -1474 -1769 -2601 998 -1799 1316 -407 1747 -2525 1745 -175 959 -1575 1968 -160 -64 205 946 -112 -1884 1801 3686 1936 511 1188 400 2486 -2350 -263 -1181 -1258 1324 -2515 -617 280 4104 -441 2402 -85 -1534 221 -971 -3065 66 SS 20240702T203013.7Z 8949.854326 166 1 47.05 2 76.07 71.47 45.04 98.25 0.00 1 0.00 1 0 17 3.533e-01 1.659e-02 1.797e-01 5.219e-03 5.749000e-01 2.866684e-03 6.820349e-03 -6.000000e+00 2.136515e-01 233.03 -2.00 3.56 -2.00 320.69 0.00e+00 -4.277359e-04 1.208243e-03 3.980722e-03 -6.000000e+00 9.802952e-03 286.88 -2.00 20.00 -2.00 320.01 0.00e+00 4.058 0.001 302.00 328.00 3 4.4557e+00 9.2329e-03 5.4476e-02 -6.0000e+00 5.3656e-01 -1.2761e-04 1.1945e-02 4.0689e-02 -6.0000e+00 5.8068e-01 -7.1963e-02 1.0678e-02 1.7601e-02 -6.0000e+00 3.4309e-01 1.8082e-02 5.1758e-03 4.3168e-03 -6.0000e+00 1.4295e-01 5.9216e-05 2.2200e-03 1.5438e-04 6.6558e-05 -6.0000e+00 1.0251e-02 -5.6282e-03 0.0000e+00 12 8 8 10 0 0 93.37 22.83 0.46 -0.00563 0.01105 18 4 1 5 0 2613.540 26.62 20.00 22.83 24.98 2.2 988.27 91390 -131603 900000 -57283 900000 -144628 900000 -154724 -77654 -6693 -107937 -12016 -78278 900000 -101184 -60150 -48653 145156 -34838 40541 -40903 -30070 25025 30821 47997 -59424 -45053 -27096 57469 -16629 -2874 -5902 -9881 -5484 76922 -14047 14266 -8404 13062 -5834 5919 -2987 -5624 -4495 15392 20971 5652 3925 7845 13900 9905 16441 11675 1334 13462 -196 4735 3574 12576 4846 6399 4900 3663 -748 4785 7594 397 1528 2911 310 -2452 -21 -4177 1644 -6530 2379 -6751 -3569 -3603 -2683 -4036 -4872 -321 -2444 216 776 2833 -2833 2258 3004 -1587 -2207 227 -674 195 1974 -1026 751 -2001 -453 -2492 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