File name: Pandora196s1_Sapporo_20240828_L2Fit_fout2c7d20240502p1-8.txt File generation date: 20240828T144540.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v7d20240502.txt Level 1 file used: Pandora196s1_Sapporo_20240828_L1_smca1c7d20240502p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20240828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration after repairs + OOB session First and last pixel inside fitting window: 208 349 Nominal wavelengths inside fitting window [nm]: 305.1398 305.2812 305.4227 305.5641 305.7055 305.8469 305.9883 306.1297 306.2710 306.4124 306.5537 306.6951 306.8364 306.9777 307.1190 307.2603 307.4016 307.5428 307.6841 307.8253 307.9666 308.1078 308.2490 308.3902 308.5314 308.6726 308.8137 308.9549 309.0960 309.2372 309.3783 309.5194 309.6605 309.8016 309.9426 310.0837 310.2247 310.3658 310.5068 310.6478 310.7888 310.9298 311.0708 311.2118 311.3527 311.4937 311.6346 311.7755 311.9164 312.0573 312.1982 312.3391 312.4799 312.6208 312.7616 312.9025 313.0433 313.1841 313.3249 313.4657 313.6064 313.7472 313.8880 314.0287 314.1694 314.3101 314.4508 314.5915 314.7322 314.8729 315.0135 315.1542 315.2948 315.4354 315.5760 315.7166 315.8572 315.9978 316.1384 316.2789 316.4195 316.5600 316.7005 316.8410 316.9815 317.1220 317.2624 317.4029 317.5433 317.6838 317.8242 317.9646 318.1050 318.2454 318.3858 318.5261 318.6665 318.8068 318.9472 319.0875 319.2278 319.3681 319.5084 319.6486 319.7889 319.9291 320.0694 320.2096 320.3498 320.4900 320.6302 320.7704 320.9105 321.0507 321.1908 321.3310 321.4711 321.6112 321.7513 321.8914 322.0314 322.1715 322.3115 322.4516 322.5916 322.7316 322.8716 323.0116 323.1516 323.2915 323.4315 323.5714 323.7114 323.8513 323.9912 324.1311 324.2709 324.4108 324.5507 324.6905 324.8304 324.9702 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240827T211242.0Z 9005.883819 245 1 9.77 2 76.73 89.13 15.94 157.61 0.00 1 0.00 1 0 25 1.795e-01 1.063e-02 1.188e-01 3.919e-03 4.912271e-01 2.073643e-03 6.033943e-03 -6.000000e+00 1.063762e-01 230.76 -2.00 3.56 -2.00 320.04 0.00e+00 3.694616e-03 7.182151e-04 2.964578e-03 -6.000000e+00 4.803118e-03 287.59 -2.00 20.00 -2.00 319.30 0.00e+00 4.247 0.001 302.00 328.00 3 2.5038e+00 6.2092e-03 5.0621e-02 -6.0000e+00 2.6572e-01 -4.0058e-02 7.5977e-03 2.9383e-02 -6.0000e+00 2.8777e-01 -5.4158e-03 6.3691e-03 1.5810e-02 -6.0000e+00 1.7144e-01 -1.9789e-03 3.2352e-03 5.2039e-03 -6.0000e+00 7.1972e-02 3.8875e-04 2.2829e-03 1.1461e-04 7.4383e-05 -6.0000e+00 5.0811e-03 -5.0603e-03 0.0000e+00 12 9 9 12 1 1 27.64 22.86 0.20 -0.00506 0.01209 14 18 1 5 0 650.270 26.62 20.00 22.86 27.15 2.4 999.69 50835 -85248 -13576 -70515 32946 -44538 -56941 -31286 -79598 1027 -54284 18765 -59199 70724 -23380 1529 -17870 3990 9775 -3498 7064 -10508 7659 -12793 7048 -16225 1200 -20663 5826 -17685 6103 -2035 -4139 -7115 -8512 -2350 -7565 -1291 -3026 -1142 -4860 3153 -1012 1866 1230 7146 -918 2258 1421 1759 2981 2008 1484 685 4139 -542 1975 915 1908 1536 4122 3504 2830 1731 1359 2710 -825 2107 747 1396 -654 1134 -941 1036 -2846 -1662 -5930 -4202 -3271 -3570 -1031 -3465 -969 -904 1356 527 1644 1310 1958 935 -500 -1832 -1235 -736 -996 636 279 640 -800 -923 -2188 -767 -562 -287 -652 -57 -166 1001 1734 1399 1201 241 673 -589 163 -330 230 -417 148 376 315 697 -15 -182 -567 -704 -324 -456 -686 -216 -1006 -388 -49 673 288 315 690 46 293 -199 -460 -332 255 -1702 -140 -1186 195 -579 -936 -466 -2038 13 -1203 250 -2066 857 -840 48 -744 146 368 -154 289 -509 343 -730 359 -1042 66 -1380 308 -1335 422 -172 -383 -658 -811 -229 -878 -171 -486 -203 -933 611 -205 385 263 1457 -200 507 324 435 810 596 479 227 1417 -195 696 321 681 551 1574 1499 1305 848 641 1263 -390 1044 421 854 -416 728 -591 612 -1579 -848 -3124 -2363 -2065 -2514 -777 -2926 -818 -821 1254 519 1650 1319 1897 876 -445 -1603 -1086 -690 -1036 717 338 815 -1022 -1139 -2556 -849 -639 -344 -803 -74 -224 1404 2594 2221 1930 385 1041 -886 238 -481 348 -663 241 608 506 1086 -23 -271 -838 -997 -479 -718 -1161 -383 -1839 -719 -94 1345 593 660 1472 98 614 -401 -905 -644 SS 20240827T212339.3Z 9005.891427 248 1 47.76 2 74.73 91.00 15.32 166.06 0.00 1 0.00 1 0 25 3.051e-01 1.136e-02 1.157e-01 2.869e-03 4.433498e-01 1.509227e-03 5.330487e-03 -6.000000e+00 1.814807e-01 230.76 -2.00 3.56 -2.00 319.69 0.00e+00 2.356443e-03 4.613098e-04 2.097036e-03 -6.000000e+00 8.311403e-03 287.59 -2.00 20.00 -2.00 318.91 0.00e+00 3.725 0.001 302.00 328.00 3 4.0040e+00 4.3906e-03 4.4396e-02 -6.0000e+00 4.5280e-01 -2.4139e-02 5.2539e-03 2.5341e-02 -6.0000e+00 4.9053e-01 1.7755e-02 4.1342e-03 1.3007e-02 -6.0000e+00 2.9169e-01 -1.7520e-02 2.1237e-03 3.9362e-03 -6.0000e+00 1.2221e-01 1.4749e-04 1.7108e-03 8.5059e-05 5.0351e-05 -6.0000e+00 8.6380e-03 -1.5341e-03 0.0000e+00 12 8 8 10 0 0 99.75 22.87 0.42 -0.00153 0.01132 24 6 1 5 0 1989.500 26.62 20.00 22.87 27.74 2.4 1004.33 17242 -85482 135150 -28479 900000 -47303 284583 -66767 -8878 -32638 -39791 -8378 -51764 52282 -13949 -8737 -17512 19691 -8457 5252 -5665 4023 -1415 -2402 -5514 -8591 -12215 -10904 2493 -11133 1612 -2304 186 -6321 6212 -8265 3975 -6475 -106 -3250 -9 -324 -340 -1761 3009 6253 -49 1497 -1688 2049 5048 5293 2421 1038 2973 2504 615 3033 1350 2164 3690 2630 2954 -240 1729 3101 -1169 310 1965 413 -1035 325 -993 367 -2647 -540 -5409 -3940 -3635 -2851 -2176 -2946 -1575 -1232 463 1034 1772 850 1244 1235 194 -1393 -1017 -752 36 230 -7 976 -563 -1374 -1423 -958 -657 -481 -1013 63 -359 1258 1186 1678 820 1194 -109 -466 -100 -12 89 -44 647 445 360 190 -26 -28 332 -1354 -142 -434 -201 -490 -1379 -632 -221 873 -174 968 685 174 262 -300 -742 -214 185 -2684 508 -488 900000 -979 796 -2135 -175 -849 -1168 -220 -2471 1104 -651 -430 -1015 883 -511 292 -352 240 -96 -176 -425 -703 -1047 -894 182 -1030 150 -249 22 -756 642 -1074 532 -1126 -21 -735 -2 -80 -87 -460 768 1554 -13 401 -482 608 1556 1751 887 406 1176 1028 258 1223 552 904 1647 1272 1559 -132 918 1562 -617 173 1201 280 -725 224 -686 234 -1615 -299 -3077 -2372 -2451 -2106 -1744 -2591 -1436 -1171 463 1055 1850 895 1263 1200 183 -1248 -909 -712 37 260 -9 1248 -723 -1716 -1669 -1078 -740 -588 -1269 82 -488 1759 1768 2613 1323 1876 -168 -693 -142 -17 132 -69 1026 710 572 295 -40 -42 480 -1903 -205 -677 -325 -852 -2455 -1134 -416 1703 -352 1969 1400 356 528 -596 -1416 -409 SS 20240827T213357.0Z 9005.898577 251 1 48.07 2 72.86 92.78 15.00 174.44 0.00 1 0.00 1 0 17 5.256e-02 8.948e-03 1.209e-02 1.062e-03 4.023447e-01 5.537589e-04 4.747479e-03 -6.000000e+00 3.112740e-02 230.76 -2.00 3.56 -2.00 319.22 0.00e+00 2.224701e-03 1.450554e-04 1.390861e-03 -6.000000e+00 1.406261e-03 287.59 -2.00 20.00 -2.00 318.41 0.00e+00 3.341 0.001 302.00 328.00 3 2.5662e+00 1.5652e-03 3.9575e-02 -6.0000e+00 7.7753e-02 -4.5353e-02 1.8280e-03 2.1690e-02 -6.0000e+00 8.4219e-02 1.7106e-02 1.3331e-03 1.1081e-02 -6.0000e+00 5.0172e-02 -1.4150e-02 6.9059e-04 3.5528e-03 -6.0000e+00 2.1051e-02 9.5143e-04 1.9042e-03 3.1498e-05 4.1316e-05 -6.0000e+00 1.4874e-03 -1.6623e-03 0.0000e+00 11 8 0 10 0 0 99.93 22.88 0.27 -0.00166 0.01265 156 39 1 5 0 308.080 26.62 20.00 22.88 28.39 2.4 1010.17 -6196 -26328 -6853 -18294 3954 -21939 -7449 -16571 -18752 -10033 -23065 -4968 -16602 5938 -6822 799 -5938 4471 -942 3274 339 67 2283 -3413 -107 -5503 -3506 -5183 -600 -4886 -891 -3642 -1396 -5301 -4191 -4727 -2697 -2038 -1318 -132 -1583 885 -730 1048 1219 1653 342 871 -190 1660 1969 1419 1800 630 1874 488 691 42 1018 1359 2784 2247 2905 1376 764 734 -911 793 1247 755 227 406 -62 82 -1963 -1845 -3880 -3136 -2772 -2702 -2086 -2643 -1457 -450 410 931 1462 1091 1471 795 273 -1198 -744 -658 -166 293 258 259 -549 -601 -1692 -724 -625 -545 -1252 -216 -2 1095 1493 1393 901 466 231 -512 8 -253 98 101 210 178 524 556 135 41 -461 -1170 -190 -307 -637 -391 -890 -448 42 476 244 646 671 310 76 -244 -552 -381 -145 -810 -175 -479 79 -591 -194 -534 -674 -342 -932 -196 -884 302 -460 55 -467 341 -80 279 30 6 214 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