File name: Pandora196s1_Sapporo_20240922_L2Fit_fout2c7d20240502p1-8.txt File generation date: 20240922T143447.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v7d20240502.txt Level 1 file used: Pandora196s1_Sapporo_20240922_L1_smca1c7d20240502p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20240922 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration after repairs + OOB session First and last pixel inside fitting window: 208 349 Nominal wavelengths inside fitting window [nm]: 305.1398 305.2812 305.4227 305.5641 305.7055 305.8469 305.9883 306.1297 306.2710 306.4124 306.5537 306.6951 306.8364 306.9777 307.1190 307.2603 307.4016 307.5428 307.6841 307.8253 307.9666 308.1078 308.2490 308.3902 308.5314 308.6726 308.8137 308.9549 309.0960 309.2372 309.3783 309.5194 309.6605 309.8016 309.9426 310.0837 310.2247 310.3658 310.5068 310.6478 310.7888 310.9298 311.0708 311.2118 311.3527 311.4937 311.6346 311.7755 311.9164 312.0573 312.1982 312.3391 312.4799 312.6208 312.7616 312.9025 313.0433 313.1841 313.3249 313.4657 313.6064 313.7472 313.8880 314.0287 314.1694 314.3101 314.4508 314.5915 314.7322 314.8729 315.0135 315.1542 315.2948 315.4354 315.5760 315.7166 315.8572 315.9978 316.1384 316.2789 316.4195 316.5600 316.7005 316.8410 316.9815 317.1220 317.2624 317.4029 317.5433 317.6838 317.8242 317.9646 318.1050 318.2454 318.3858 318.5261 318.6665 318.8068 318.9472 319.0875 319.2278 319.3681 319.5084 319.6486 319.7889 319.9291 320.0694 320.2096 320.3498 320.4900 320.6302 320.7704 320.9105 321.0507 321.1908 321.3310 321.4711 321.6112 321.7513 321.8914 322.0314 322.1715 322.3115 322.4516 322.5916 322.7316 322.8716 323.0116 323.1516 323.2915 323.4315 323.5714 323.7114 323.8513 323.9912 324.1311 324.2709 324.4108 324.5507 324.6905 324.8304 324.9702 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240922T022444.0Z 9031.100509 449 1 1.24 2 42.92 179.05 99.05 312.10 0.00 1 0.00 1 0 25 1.242e-02 9.755e-03 4.496e-03 3.023e-03 1.775594e-01 1.580622e-03 2.091723e-03 -6.000000e+00 7.292513e-03 228.27 -2.00 3.56 -2.00 315.07 0.00e+00 4.950355e-04 1.420491e-04 7.170229e-05 -6.000000e+00 3.289854e-04 285.22 -2.00 20.00 -2.00 314.42 0.00e+00 1.364 0.000 302.00 328.00 3 3.2026e+00 4.0560e-03 1.6291e-02 -6.0000e+00 1.8122e-02 1.7436e-02 4.5182e-03 8.9868e-03 -6.0000e+00 1.9669e-02 -3.1012e-03 2.5798e-03 4.3562e-03 -6.0000e+00 1.1725e-02 -7.0126e-03 1.1254e-03 1.2289e-03 -6.0000e+00 4.9371e-03 4.6943e-03 2.5645e-03 8.8083e-05 1.5088e-05 -6.0000e+00 3.5128e-04 -5.5354e-03 0.0000e+00 12 9 9 12 1 1 76.18 22.42 0.26 -0.00554 0.01374 3 39 1 5 0 306.180 26.21 20.00 22.42 24.94 2.6 983.65 709 -911 -2660 -1764 434 -1664 -622 -1307 -2334 -3261 -1571 509 594 501 -344 1170 1311 2896 975 1224 1198 2307 2767 1109 687 -406 -687 -312 -1312 585 -253 -1596 -2015 -3641 -3477 -3305 -885 -1433 -848 -1123 -185 1040 -66 444 393 437 494 -196 260 641 714 602 1529 788 1033 663 565 577 1133 1376 1618 1528 1357 597 -177 -217 -1005 658 402 335 563 913 413 -234 -1161 -1687 -2980 -2391 -2365 -2088 -2538 -2504 -1287 -669 -30 951 1397 1083 877 606 316 -943 -1158 -572 -617 366 247 421 -545 -528 -1186 -867 -499 -901 -1065 -155 27 999 1657 1430 836 610 -88 43 173 -21 166 217 628 236 461 18 -64 451 29 -921 -148 -200 -61 -774 -217 -117 104 596 580 310 879 13 -536 -280 -734 -790 228 -304 -876 -535 119 -473 -191 -428 -821 -1151 -533 183 237 213 -155 537 611 1375 482 624 602 1148 1424 581 372 -224 -359 -157 -637 283 -131 -876 -1120 -2010 -1840 -1869 -534 -950 -627 -878 -144 825 -53 354 314 353 385 -149 201 490 581 493 1300 669 886 582 495 496 1001 1201 1499 1468 1330 590 -167 -194 -899 582 391 341 579 938 426 -228 -1101 -1504 -2613 -2060 -2194 -2065 -2677 -2729 -1398 -754 -35 1160 1698 1321 1064 701 345 -1003 -1186 -612 -677 421 304 530 -677 -634 -1367 -984 -588 -1099 -1323 -200 35 1347 2281 2000 1172 837 -115 54 213 -26 208 284 850 319 632 25 -85 577 35 -1110 -178 -250 -78 -1039 -286 -157 144 854 848 453 1308 20 -791 -411 -1050 -1148 SS 20240922T032041.7Z 9031.139371 483 1 48.53 2 44.56 199.21 105.52 322.85 0.00 1 0.00 1 0 17 1.730e-02 1.086e-02 4.313e-03 2.182e-03 1.854686e-01 1.130466e-03 2.203259e-03 -6.000000e+00 1.015092e-02 228.26 -2.00 3.56 -2.00 316.16 0.00e+00 4.338711e-04 1.266474e-04 1.966181e-04 -6.000000e+00 4.583764e-04 285.21 -2.00 20.00 -2.00 315.41 0.00e+00 1.402 0.000 302.00 328.00 3 5.9779e+00 2.9391e-03 1.6854e-02 -6.0000e+00 2.5224e-02 4.0113e-02 3.2911e-03 9.4117e-03 -6.0000e+00 2.7387e-02 4.0148e-03 1.8904e-03 4.5851e-03 -6.0000e+00 1.6325e-02 -1.1460e-02 8.6057e-04 1.2741e-03 -6.0000e+00 6.8669e-03 2.7441e-04 1.8423e-03 6.4597e-05 1.4804e-05 -6.0000e+00 4.8931e-04 5.5628e-04 0.0000e+00 12 8 8 10 0 0 99.99 22.47 0.81 0.00056 0.01440 46 11 1 5 0 1054.820 26.32 20.00 22.47 26.51 2.6 994.97 -508 -3204 971 -3682 8436 -2667 4562 -2686 -474 -3620 -1204 855 -3540 3470 -956 341 -220 3320 23 2957 750 2270 1293 759 228 -1280 -1619 -448 266 -1231 175 -1702 -2302 -4991 -2314 -4535 -1099 -2755 177 -964 113 103 -281 17 185 330 -207 -57 -689 1401 1073 1763 1260 544 2228 905 756 933 764 951 2090 1481 2210 867 355 118 -1169 395 1362 111 170 111 187 441 -1478 -1018 -4380 -3158 -2542 -2738 -2686 -2513 -1769 -443 410 839 1504 959 1102 588 -24 -1415 -546 -533 -305 267 334 3 -462 -181 -1571 -937 -714 -776 -950 35 -282 1167 1458 1751 1061 870 309 -558 -325 -260 3 62 552 358 360 169 9 189 -104 -1351 -104 -420 -322 -229 -1246 -503 -7 1095 399 884 427 506 99 -244 -1033 -849 -109 -724 204 -719 1401 -502 874 -595 -109 -858 -283 213 -993 1015 -320 117 -77 1169 9 1104 282 843 505 312 97 -556 -668 -170 99 -473 70 -707 -1013 -2112 -948 -2035 -526 -1536 111 -652 79 74 -205 12 133 231 -146 -39 -464 955 782 1290 971 433 1766 740 618 748 612 778 1800 1332 2078 827 311 98 -950 329 1233 110 170 111 187 415 -1315 -841 -3510 -2563 -2215 -2641 -2753 -2660 -1932 -513 490 1051 1873 1200 1368 697 -27 -1461 -554 -551 -334 317 421 4 -588 -222 -1865 -1059 -840 -967 -1238 46 -387 1648 2107 2623 1596 1249 424 -728 -410 -330 4 86 783 521 516 236 13 247 -134 -1664 -128 -552 -434 -321 -1736 -708 -10 1631 626 1408 682 810 159 -382 -1580 -1281 SS 20240922T033337.8Z 9031.148354 490 1 3.84 2 45.43 203.62 106.81 325.49 0.00 1 0.00 1 0 17 1.229e-02 9.822e-03 4.116e-03 2.652e-03 1.864818e-01 1.384268e-03 2.233294e-03 -6.000000e+00 7.205256e-03 228.26 -2.00 3.56 -2.00 315.27 0.00e+00 5.651560e-04 1.288982e-04 9.390006e-05 -6.000000e+00 3.257171e-04 285.21 -2.00 20.00 -2.00 314.60 0.00e+00 1.423 0.000 302.00 328.00 3 4.0508e+00 3.5578e-03 1.7077e-02 -6.0000e+00 1.7904e-02 2.4411e-02 3.9675e-03 9.5197e-03 -6.0000e+00 1.9447e-02 -4.8761e-03 2.2662e-03 4.6298e-03 -6.0000e+00 1.1592e-02 -5.5112e-03 9.9587e-04 1.2950e-03 -6.0000e+00 4.8694e-03 1.8584e-03 6.8974e-04 7.7392e-05 1.6096e-05 -6.0000e+00 3.4765e-04 8.5834e-03 0.0000e+00 12 9 9 12 1 1 77.88 22.48 0.22 0.00858 0.01377 4 16 1 5 0 767.490 26.32 20.01 22.48 26.81 2.5 996.70 -735 -298 -1600 -31 149 -1524 1511 -1235 -932 -2507 -842 -828 526 1023 187 -112 930 1673 1148 2042 1776 2060 760 1831 246 -366 -1415 -1093 -437 -203 -504 -1008 -1900 -5148 -4064 -3512 -1392 -1127 -38 -1411 -230 451 -218 432 587 -30 653 -95 -3 652 839 1076 1356 1449 867 633 1219 621 846 1268 1198 2079 951 1047 -144 -281 -404 870 1392 -31 456 -37 632 2 -1478 -1133 -2800 -2494 -2564 -2678 -2405 -2313 -1797 -350 253 579 1071 940 1217 694 306 -1101 -667 -676 -319 150 185 165 -120 -763 -1207 -877 110 -935 -1064 -299 -372 1032 1590 1430 743 1141 554 -404 -155 354 -188 369 239 280 161 583 -52 160 -407 -1004 417 -342 -200 -628 -577 -166 381 637 378 458 512 10 27 -584 -826 -454 -218 -90 -494 -8 39 -406 427 -384 -307 -835 -270 -288 194 406 80 -49 414 767 541 985 847 981 369 920 130 -194 -720 -532 -209 -96 -252 -532 -1032 -2705 -2096 -1867 -801 -721 -27 -1060 -178 358 -172 343 466 -23 503 -72 -2 495 660 881 1129 1237 753 548 1047 541 732 1120 1099 1975 939 1034 -135 -249 -354 784 1342 -31 466 -38 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