File name: Pandora196s1_Sapporo_20240927_L2Fit_fout2c7d20240502p1-8.txt File generation date: 20240927T143803.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v7d20240502.txt Level 1 file used: Pandora196s1_Sapporo_20240927_L1_smca1c7d20240502p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20240927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration after repairs + OOB session First and last pixel inside fitting window: 208 349 Nominal wavelengths inside fitting window [nm]: 305.1398 305.2812 305.4227 305.5641 305.7055 305.8469 305.9883 306.1297 306.2710 306.4124 306.5537 306.6951 306.8364 306.9777 307.1190 307.2603 307.4016 307.5428 307.6841 307.8253 307.9666 308.1078 308.2490 308.3902 308.5314 308.6726 308.8137 308.9549 309.0960 309.2372 309.3783 309.5194 309.6605 309.8016 309.9426 310.0837 310.2247 310.3658 310.5068 310.6478 310.7888 310.9298 311.0708 311.2118 311.3527 311.4937 311.6346 311.7755 311.9164 312.0573 312.1982 312.3391 312.4799 312.6208 312.7616 312.9025 313.0433 313.1841 313.3249 313.4657 313.6064 313.7472 313.8880 314.0287 314.1694 314.3101 314.4508 314.5915 314.7322 314.8729 315.0135 315.1542 315.2948 315.4354 315.5760 315.7166 315.8572 315.9978 316.1384 316.2789 316.4195 316.5600 316.7005 316.8410 316.9815 317.1220 317.2624 317.4029 317.5433 317.6838 317.8242 317.9646 318.1050 318.2454 318.3858 318.5261 318.6665 318.8068 318.9472 319.0875 319.2278 319.3681 319.5084 319.6486 319.7889 319.9291 320.0694 320.2096 320.3498 320.4900 320.6302 320.7704 320.9105 321.0507 321.1908 321.3310 321.4711 321.6112 321.7513 321.8914 322.0314 322.1715 322.3115 322.4516 322.5916 322.7316 322.8716 323.0116 323.1516 323.2915 323.4315 323.5714 323.7114 323.8513 323.9912 324.1311 324.2709 324.4108 324.5507 324.6905 324.8304 324.9702 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240927T014207.1Z 9036.070916 424 1 49.09 2 45.90 164.78 44.11 260.75 0.00 1 0.00 1 0 25 1.254e-02 9.416e-03 4.521e-04 2.398e-04 1.947590e-01 1.241716e-04 2.304792e-03 -6.000000e+00 7.341764e-03 227.68 -2.00 3.56 -2.00 316.01 0.00e+00 7.337171e-04 1.345815e-05 1.415668e-04 -6.000000e+00 3.313470e-04 284.60 -2.00 20.00 -2.00 315.28 0.00e+00 1.435 0.000 302.00 328.00 3 1.8068e+00 3.2169e-04 1.7377e-02 -6.0000e+00 1.8222e-02 -3.1906e-03 3.6046e-04 9.8657e-03 -6.0000e+00 1.9794e-02 1.8052e-03 2.0687e-04 4.8072e-03 -6.0000e+00 1.1801e-02 -8.5166e-03 9.3342e-05 1.3889e-03 -6.0000e+00 4.9677e-03 1.7175e-02 1.8886e-03 7.0550e-06 1.5483e-05 -6.0000e+00 3.5457e-04 -4.3990e-04 0.0000e+00 12 8 8 10 0 0 99.95 22.58 0.26 -0.00044 0.01375 1841 455 1 5 0 26.130 26.41 20.00 22.58 28.43 2.6 1010.74 -417 -854 -1248 -2116 -888 -1705 -790 -1132 -1963 -2539 -2365 -584 -802 707 555 957 1404 2212 1894 2375 1465 2205 1359 857 194 -707 -937 -772 -272 -553 -588 -1025 -2067 -4462 -3483 -3595 -2294 -1155 -848 -728 -135 486 354 679 854 235 91 -160 43 594 825 982 1257 777 1078 907 664 445 891 1218 1662 1683 1710 616 -190 -277 -659 500 966 293 583 245 340 -89 -1348 -1840 -3105 -2600 -2451 -2773 -2281 -2483 -1508 -332 190 944 1055 1012 1013 664 237 -943 -631 -262 -240 141 393 160 -420 -484 -1304 -802 -295 -784 -1096 -221 -1 879 1525 1489 961 582 272 -310 -75 64 128 307 327 124 407 430 11 258 -355 -1009 -95 -285 -470 -524 -831 -411 205 512 400 636 725 262 32 -245 -843 -644 -88 -187 -294 -446 -171 -337 -169 -270 -504 -653 -598 -158 -243 215 187 334 498 808 710 918 564 844 547 362 85 -315 -398 -304 -102 -214 -241 -445 -958 -1987 -1477 -1636 -1177 -636 -543 -511 -99 362 268 508 641 173 65 -112 29 419 621 771 953 608 852 733 536 354 705 985 1426 1548 1660 606 -173 -233 -536 418 912 280 580 245 329 -87 -1211 -1505 -2619 -2241 -2176 -2735 -2283 -2658 -1663 -389 222 1152 1324 1272 1230 748 263 -961 -665 -269 -269 161 490 212 -547 -593 -1598 -936 -358 -972 -1424 -299 -1 1199 2187 2224 1443 836 364 -407 -93 79 166 427 454 177 570 588 16 342 -454 -1224 -115 -371 -648 -754 -1142 -573 296 783 602 977 1140 415 50 -369 -1316 -991 SS 20240927T014703.0Z 9036.074341 427 1 5.08 2 45.68 166.48 44.99 261.68 0.00 1 0.00 1 0 25 1.262e-02 9.730e-03 1.223e-03 7.594e-04 1.953970e-01 3.948238e-04 2.309634e-03 -6.000000e+00 7.391039e-03 227.68 -2.00 3.56 -2.00 315.41 0.00e+00 6.920002e-04 3.813148e-05 9.198201e-05 -6.000000e+00 3.335049e-04 284.60 -2.00 20.00 -2.00 314.74 0.00e+00 1.429 0.000 302.00 328.00 3 2.0372e+00 1.0161e-03 1.7344e-02 -6.0000e+00 1.8345e-02 6.4413e-03 1.1342e-03 9.8886e-03 -6.0000e+00 1.9926e-02 -1.4204e-03 6.4790e-04 4.8072e-03 -6.0000e+00 1.1879e-02 -6.9737e-03 2.8700e-04 1.3816e-03 -6.0000e+00 5.0019e-03 1.3659e-02 2.0286e-03 2.2160e-05 1.5932e-05 -6.0000e+00 3.5689e-04 -1.6640e-03 0.0000e+00 12 9 9 12 1 1 79.31 22.58 0.22 -0.00166 0.01358 54 129 1 5 0 92.110 26.41 20.00 22.58 28.86 2.5 1013.73 -299 -1190 -915 -2240 -413 -2030 -437 -1298 -1690 -2722 -1913 -398 -1000 935 806 1147 1410 2664 1958 2565 1352 2298 1290 889 333 -596 -903 -791 110 -636 -227 -1125 -2104 -4646 -3329 -3501 -2105 -1324 -850 -767 -135 468 397 885 846 243 60 -291 -77 457 735 927 1197 732 1124 878 594 468 1023 1296 1812 1616 1762 520 -205 -205 -697 432 888 209 549 342 301 45 -1350 -1851 -3139 -2372 -2442 -2701 -2376 -2460 -1528 -392 231 965 1072 1079 949 529 255 -1087 -538 -303 -236 63 427 181 -340 -510 -1307 -701 -234 -779 -1137 -210 -53 895 1518 1436 972 657 319 -255 99 131 149 336 367 235 351 346 -90 262 -227 -1005 -84 -364 -387 -499 -783 -483 299 570 402 696 595 212 -24 -244 -908 -675 -83 -340 -254 -610 -102 -519 -120 -367 -511 -830 -569 -127 -359 369 324 478 598 1159 878 1183 623 1051 620 449 162 -295 -457 -372 49 -293 -111 -583 -1079 -2469 -1678 -1894 -1192 -822 -574 -567 -104 368 317 696 668 188 45 -214 -56 340 582 765 973 613 951 760 514 399 865 1120 1660 1503 1726 518 -189 -184 -606 387 847 206 563 351 300 45 -1223 -1617 -2609 -2010 -2314 -2681 -2446 -2705 -1645 -449 268 1172 1340 1348 1148 623 275 -1138 -540 -319 -258 75 530 227 -419 -621 -1560 -796 -276 -959 -1469 -270 -70 1180 2104 2074 1351 911 430 -332 122 161 191 441 492 323 475 477 -119 343 -287 -1207 -101 -468 -504 -678 -1082 -677 414 839 595 1047 919 330 -37 -360 -1307 -1001 SS 20240927T015644.4Z 9036.081070 430 1 48.85 2 45.32 169.83 46.72 263.48 0.00 1 0.00 1 0 25 1.235e-02 9.488e-03 2.274e-04 1.392e-04 1.929637e-01 7.254318e-05 2.277224e-03 -6.000000e+00 7.234874e-03 227.68 -2.00 3.56 -2.00 315.48 0.00e+00 7.401540e-04 7.058112e-06 9.053741e-05 -6.000000e+00 3.264211e-04 284.60 -2.00 20.00 -2.00 314.80 0.00e+00 1.420 0.000 302.00 328.00 3 9.1656e-01 1.8654e-04 1.7192e-02 -6.0000e+00 1.7957e-02 -8.1805e-04 2.0821e-04 9.7618e-03 -6.0000e+00 1.9504e-02 2.0297e-04 1.1926e-04 4.7449e-03 -6.0000e+00 1.1628e-02 -7.0503e-03 5.2998e-05 1.3812e-03 -6.0000e+00 4.8965e-03 4.2549e-02 2.1100e-03 4.0611e-06 1.6011e-05 -6.0000e+00 3.4933e-04 -2.2718e-03 0.0000e+00 12 8 8 10 0 0 71.90 22.60 0.25 -0.00227 0.01358 1867 461 1 5 0 25.760 26.41 20.00 22.60 30.69 2.4 1028.32 -364 -581 -1262 -2028 -1141 -1666 -824 -973 -1974 -2484 -2109 -533 -519 764 677 1068 1560 2225 1991 2295 1512 2223 1529 904 353 -547 -807 -626 -152 -513 -537 -940 -2065 -4344 -3454 -3509 -2290 -1046 -811 -690 -140 475 407 720 852 182 141 -172 90 570 874 870 1266 799 1083 944 614 487 898 1243 1659 1634 1671 611 -247 -247 -633 553 945 253 534 213 324 -76 -1276 -1816 -3000 -2579 -2456 -2726 -2264 -2498 -1515 -372 196 919 1032 1000 982 659 238 -936 -611 -240 -262 157 396 158 -408 -451 -1274 -789 -262 -756 -1100 -237 -10 858 1518 1469 936 587 303 -235 -33 130 186 362 325 136 410 457 49 313 -272 -923 -4 -236 -424 -492 -799 -404 231 474 377 589 639 197 -24 -277 -866 -712 -98 -160 -342 -535 -277 -412 -221 -290 -581 -733 -665 -165 -179 293 264 432 640 942 864 1028 673 985 710 442 179 -282 -395 -284 -71 -228 -253 -470 -1102 -2224 -1685 -1835 -1255 -670 -565 -493 -104 361 314 548 650 136 103 -130 67 436 667 694 1055 687 941 788 513 426 780 1038 1471 1554 1583 587 -232 -215 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