File name: Pandora196s1_Sapporo_20241111_L2Fit_fout2c8d20240502p1-8.txt File generation date: 20241112T022518.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v8d20240502.txt Level 1 file used: Pandora196s1_Sapporo_20241111_L1_smca1c8d20240502p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20241111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 349 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1606 305.3019 305.4432 305.5845 305.7258 305.8670 306.0083 306.1495 306.2907 306.4320 306.5732 306.7144 306.8555 306.9967 307.1379 307.2790 307.4202 307.5613 307.7024 307.8435 307.9846 308.1257 308.2668 308.4078 308.5489 308.6899 308.8310 308.9720 309.1130 309.2540 309.3950 309.5359 309.6769 309.8178 309.9588 310.0997 310.2406 310.3815 310.5224 310.6633 310.8042 310.9450 311.0859 311.2267 311.3675 311.5084 311.6492 311.7900 311.9307 312.0715 312.2123 312.3530 312.4937 312.6345 312.7752 312.9159 313.0566 313.1973 313.3379 313.4786 313.6192 313.7599 313.9005 314.0411 314.1817 314.3223 314.4629 314.6034 314.7440 314.8845 315.0251 315.1656 315.3061 315.4466 315.5871 315.7276 315.8680 316.0085 316.1489 316.2893 316.4298 316.5702 316.7106 316.8510 316.9913 317.1317 317.2720 317.4124 317.5527 317.6930 317.8333 317.9736 318.1139 318.2542 318.3944 318.5347 318.6749 318.8151 318.9554 319.0956 319.2358 319.3759 319.5161 319.6563 319.7964 319.9365 320.0767 320.2168 320.3569 320.4970 320.6370 320.7771 320.9172 321.0572 321.1972 321.3372 321.4773 321.6173 321.7572 321.8972 322.0372 322.1771 322.3171 322.4570 322.5969 322.7368 322.8767 323.0166 323.1565 323.2963 323.4362 323.5760 323.7158 323.8556 323.9954 324.1352 324.2750 324.4148 324.5545 324.6943 324.8340 324.9737 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241111T001934.7Z 9081.013596 153 1 48.14 2 66.46 148.90 136.21 49.72 0.00 1 0.00 1 0 25 2.503e-02 1.462e-02 1.406e-03 3.367e-04 3.010618e-01 1.625775e-04 3.602726e-03 -6.000000e+00 1.370223e-02 223.09 -2.00 3.56 -2.00 317.72 0.00e+00 1.597434e-03 2.666591e-05 5.301796e-04 -6.000000e+00 6.076757e-04 278.99 -2.00 20.00 -2.00 317.04 0.00e+00 2.485 0.000 302.00 328.00 3 1.5999e+00 4.3014e-04 2.8862e-02 -6.0000e+00 3.3747e-02 -5.8767e-02 4.8855e-04 1.5141e-02 -6.0000e+00 3.6873e-02 2.3185e-02 3.0911e-04 7.6433e-03 -6.0000e+00 2.1995e-02 -1.7486e-02 1.5906e-04 2.4217e-03 -6.0000e+00 9.3804e-03 6.5756e-03 3.3855e-04 9.1333e-06 2.1397e-05 -6.0000e+00 6.3140e-04 4.5435e-03 0.0000e+00 12 8 8 10 0 0 98.67 21.59 0.31 0.00454 0.00709 631 156 1 5 0 76.280 25.39 19.99 21.59 18.25 3.1 935.34 -2354 -158 -819 -2822 -8283 -7406 -7021 -4834 -3407 -4791 -7104 -7887 -3742 -2371 1609 1839 1617 2092 2544 2784 2436 1162 1435 1289 112 598 -716 -1977 -4045 -2959 -1590 -1027 353 -1508 -5813 -7006 -6004 -3550 -886 715 564 540 1111 943 1432 1421 943 289 -804 -765 426 972 1242 1831 1173 1337 760 275 -504 -468 347 1712 2873 3889 1941 -218 -1598 -2699 -614 814 1551 1814 1257 1040 -234 -2145 -3980 -5708 -4564 -3328 -2402 -1681 -2368 -1693 -534 522 1412 2104 2514 1878 845 -681 -2258 -2801 -1901 -1088 369 1769 1488 302 -664 -2138 -2683 -1157 -975 -736 -317 135 1035 1955 2457 1965 1348 96 -1208 -1460 -1390 -672 277 975 760 1137 1161 399 116 -1213 -1737 -1006 -597 -473 -466 -723 -994 -303 284 414 917 1261 900 366 -126 -876 -1141 -169 -13 -69 -237 -645 -534 -529 -399 -314 -483 -729 -825 -429 -317 242 315 295 398 462 527 477 228 284 273 25 141 -174 -464 -901 -708 -369 -261 98 -453 -1699 -1978 -1831 -1228 -362 314 275 276 587 508 769 771 509 154 -430 -411 241 548 742 1157 775 899 527 191 -345 -318 241 1181 2154 3133 1613 -171 -1180 -1967 -468 704 1370 1670 1162 926 -196 -1756 -3003 -4183 -3505 -2898 -2190 -1695 -2414 -1789 -601 588 1664 2543 3040 2197 920 -731 -2260 -2755 -1997 -1192 447 2234 2004 401 -832 -2632 -3117 -1387 -1210 -957 -431 182 1463 2952 3729 3035 2014 143 -1663 -2008 -1928 -923 407 1438 1136 1748 1742 577 160 -1709 -2333 -1376 -841 -717 -709 -1133 -1594 -506 481 733 1578 2218 1592 629 -219 -1476 -1897 SS 20241111T002959.2Z 9081.020824 160 1 48.13 2 65.52 151.41 134.76 52.54 0.00 1 0.00 1 0 25 2.402e-02 1.453e-02 1.998e-03 4.595e-04 2.900654e-01 2.218355e-04 3.470059e-03 -6.000000e+00 1.315113e-02 223.09 -2.00 3.56 -2.00 317.83 0.00e+00 1.601258e-03 3.706725e-05 5.303347e-04 -6.000000e+00 5.831998e-04 278.99 -2.00 20.00 -2.00 317.16 0.00e+00 2.397 0.000 302.00 328.00 3 2.2048e+00 5.8727e-04 2.7820e-02 -6.0000e+00 3.2389e-02 -5.3634e-02 6.6672e-04 1.4575e-02 -6.0000e+00 3.5389e-02 2.6603e-02 4.2411e-04 7.3687e-03 -6.0000e+00 2.1109e-02 -1.9736e-02 2.1883e-04 2.3610e-03 -6.0000e+00 9.0039e-03 3.9577e-03 4.5509e-04 1.2533e-05 2.0777e-05 -6.0000e+00 6.0592e-04 3.7407e-03 0.0000e+00 12 8 8 10 0 0 99.99 21.60 0.27 0.00374 0.00716 600 148 1 5 0 80.200 25.39 19.99 21.60 18.69 3.0 938.40 -1199 -65 -375 -2809 -6739 -6326 -6571 -4259 -3188 -4884 -6948 -8085 -3139 -2211 1661 1766 1650 2218 2652 2792 2340 1351 1375 1650 -28 761 -764 -1823 -3736 -2700 -1378 -714 383 -1416 -5598 -6966 -5932 -3765 -879 479 422 320 893 700 1463 1292 785 196 -934 -843 614 974 1203 1875 1106 1387 757 404 -421 -226 440 1751 2954 3963 1991 -305 -1442 -2614 -701 838 1526 1785 1311 1121 -97 -2069 -3870 -5660 -4464 -3251 -2405 -1647 -2449 -1706 -496 514 1441 2196 2543 1859 967 -606 -2273 -2797 -1874 -1051 407 1833 1505 372 -664 -2159 -2642 -1156 -967 -710 -319 151 1063 1994 2444 1972 1281 58 -1238 -1579 -1471 -669 208 935 769 1060 1036 354 111 -1214 -1709 -1050 -633 -491 -427 -784 -987 -356 294 391 964 1272 872 345 -173 -804 -1082 -82 -5 -30 -226 -496 -432 -471 -334 -280 -470 -678 -805 -339 -278 235 284 282 394 494 541 470 271 279 356 -7 183 -190 -435 -844 -595 -323 -182 107 -427 -1638 -1971 -1811 -1188 -326 209 204 162 428 343 710 635 418 103 -490 -444 339 532 697 1145 706 900 506 271 -278 -148 295 1253 2118 3049 1576 -227 -1094 -1955 -548 686 1366 1666 1228 1011 -83 -1602 -2989 -4240 -3496 -2660 -2208 -1549 -2485 -1793 -554 571 1673 2615 3031 2143 1110 -645 -2255 -2721 -1943 -1206 481 2389 1961 479 -860 -2590 -3207 -1351 -1239 -954 -420 208 1532 2884 3737 3064 1924 87 -1725 -2084 -1956 -929 309 1384 1154 1654 1578 519 155 -1641 -2347 -1468 -899 -750 -648 -1224 -1575 -591 490 682 1712 2310 1594 612 -297 -1338 -1881 SS 20241111T004522.6Z 9081.031512 172 1 0.50 2 64.26 155.22 132.51 56.49 0.00 1 0.00 1 0 25 2.909e-02 1.510e-02 1.006e-02 3.037e-03 2.776841e-01 1.470884e-03 3.303380e-03 -6.000000e+00 1.593744e-02 223.09 -2.00 3.56 -2.00 317.29 0.00e+00 1.587404e-03 2.141076e-04 3.712290e-04 -6.000000e+00 7.064820e-04 278.99 -2.00 20.00 -2.00 316.62 0.00e+00 2.288 0.000 302.00 328.00 3 1.5147e+00 3.8533e-03 2.6536e-02 -6.0000e+00 3.9253e-02 -5.0365e-02 4.3593e-03 1.3860e-02 -6.0000e+00 4.2877e-02 2.0855e-02 2.6550e-03 6.9478e-03 -6.0000e+00 2.5575e-02 -1.6043e-02 1.3332e-03 2.2730e-03 -6.0000e+00 1.0918e-02 8.9143e-03 1.3492e-03 8.2137e-05 1.9979e-05 -6.0000e+00 7.3370e-04 -1.8187e-03 0.0000e+00 12 9 9 12 1 1 -4.56 21.59 0.42 -0.00182 0.00832 6 169 1 5 0 70.390 25.39 20.00 21.59 18.85 3.1 939.45 10148 -6109 8774 -10273 793 -12422 1026 -2357 -3478 -1997 -8902 -1113 -5889 2659 -753 4775 -1041 5231 -1018 5753 954 1690 -195 1079 1031 -547 1981 -2454 -851 -4480 1061 -2576 1986 -2930 -5124 -7129 -4861 -3353 -1203 680 -346 905 164 1632 602 1909 -557 68 -1291 -416 1169 892 1608 1739 1608 1065 995 -28 448 -1595 1233 1780 3159 3331 2318 -263 -1471 -1859 -1428 1527 631 2060 996 949 -298 -1445 -4273 -5601 -4430 -3142 -2383 -2142 -2269 -1995 -334 745 1726 1823 2958 1866 686 -654 -2315 -2918 -1611 -954 215 1642 1543 742 -940 -1557 -3202 -1114 -1233 -249 -379 431 1319 1760 2299 1890 1540 18 -1165 -1639 -745 -842 123 807 733 974 1001 336 300 -1084 -1873 -954 -993 85 -761 -544 -1058 43 357 476 642 916 1008 372 -154 -934 -909 872 -686 908 -1220 76 -1273 96 -255 -422 -257 -1216 -144 -890 425 -143 969 -233 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