File name: Pandora196s1_Sapporo_20250117_L2Fit_fout2c8d20240502p1-8.txt File generation date: 20250118T000906.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v2d20230511.txt Instrument calibration file used: Pandora196s1_CF_v8d20240502.txt Level 1 file used: Pandora196s1_Sapporo_20250117_L1_smca1c8d20240502p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20250117 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 349 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1606 305.3019 305.4432 305.5845 305.7258 305.8670 306.0083 306.1495 306.2907 306.4320 306.5732 306.7144 306.8555 306.9967 307.1379 307.2790 307.4202 307.5613 307.7024 307.8435 307.9846 308.1257 308.2668 308.4078 308.5489 308.6899 308.8310 308.9720 309.1130 309.2540 309.3950 309.5359 309.6769 309.8178 309.9588 310.0997 310.2406 310.3815 310.5224 310.6633 310.8042 310.9450 311.0859 311.2267 311.3675 311.5084 311.6492 311.7900 311.9307 312.0715 312.2123 312.3530 312.4937 312.6345 312.7752 312.9159 313.0566 313.1973 313.3379 313.4786 313.6192 313.7599 313.9005 314.0411 314.1817 314.3223 314.4629 314.6034 314.7440 314.8845 315.0251 315.1656 315.3061 315.4466 315.5871 315.7276 315.8680 316.0085 316.1489 316.2893 316.4298 316.5702 316.7106 316.8510 316.9913 317.1317 317.2720 317.4124 317.5527 317.6930 317.8333 317.9736 318.1139 318.2542 318.3944 318.5347 318.6749 318.8151 318.9554 319.0956 319.2358 319.3759 319.5161 319.6563 319.7964 319.9365 320.0767 320.2168 320.3569 320.4970 320.6370 320.7771 320.9172 321.0572 321.1972 321.3372 321.4773 321.6173 321.7572 321.8972 322.0372 322.1771 322.3171 322.4570 322.5969 322.7368 322.8767 323.0166 323.1565 323.2963 323.4362 323.5760 323.7158 323.8556 323.9954 324.1352 324.2750 324.4148 324.5545 324.6943 324.8340 324.9737 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250116T233640.9Z 9147.983807 309 1 48.28 2 77.04 135.43 86.81 282.90 0.00 1 0.00 1 0 25 6.134e-01 1.817e-02 3.032e-01 4.916e-03 7.548543e-01 2.714410e-03 9.207482e-03 -6.000000e+00 3.471608e-01 223.58 -2.00 3.56 -2.00 321.47 0.00e+00 7.598471e-03 1.343595e-03 5.523762e-03 -6.000000e+00 1.818990e-02 273.21 -2.00 20.00 -2.00 321.03 0.00e+00 4.346 0.002 302.00 328.00 3 4.2962e+00 9.0693e-03 6.1408e-02 -6.0000e+00 8.6462e-01 -1.5861e-01 1.4681e-02 4.6840e-02 -6.0000e+00 9.5218e-01 2.4976e-02 1.7754e-02 3.4239e-02 -6.0000e+00 5.5779e-01 -9.7228e-03 8.2065e-03 1.6068e-02 -6.0000e+00 2.3635e-01 4.6938e-05 5.2415e-04 1.3236e-04 2.0837e-04 -6.0000e+00 1.6175e-02 4.6604e-03 0.0000e+00 12 8 8 10 0 0 70.36 21.70 0.37 0.00466 0.00860 22 5 1 5 0 2194.270 25.47 19.96 21.70 1.79 3.7 812.16 -344110 900000 -281834 900000 -203850 900000 -19816 900000 -195274 900000 900000 -176455 900000 -145021 900000 -73090 900000 -148315 900000 -91388 900000 -56292 900000 47165 22859 900000 -65057 -3557 27562 900000 23655 900000 -101165 87976 176158 900000 -24096 67103 347 52289 -23904 16554 6644 -12212 -12585 16606 100854 17648 26302 14264 9132 18104 27049 7613 -4065 26120 2914 11039 3951 22424 1025 29086 1573 11236 -3570 11412 10436 -4209 846 2459 4048 -5589 7066 -4695 717 -8826 6294 -11704 -5448 -3685 -1417 -235 -6712 -4894 -2165 2765 470 5948 1498 4915 885 -1194 -6156 -2205 -3439 -1373 1725 1836 1295 -778 -205 -3894 -1278 -2032 -214 -1206 167 -851 2241 1742 2276 2224 2108 -831 -2328 -620 -1711 -113 -502 2110 832 585 810 -127 228 -1235 -2376 -1468 99 -785 587 -946 -387 -900 334 -503 587 1311 746 959 -262 -757 -891 -3380 900000 -2202 900000 -974 900000 -95 900000 -933 900000 900000 -893 900000 -1033 900000 -449 900000 -2617 900000 -1135 900000 -523 900000 225 123 900000 -935 -28 163 900000 208 900000 -4583 716 842 900000 -614 840 10 1143 -1254 642 305 -707 -759 791 2233 931 1382 916 700 1455 2212 832 -532 2678 386 1356 505 2382 139 3363 276 2092 -822 2262 2103 -1014 216 723 1293 -2038 2265 -1575 209 -2543 1497 -3418 -1720 -1380 -611 -115 -3781 -2861 -1312 1702 309 3830 1001 3081 539 -705 -3699 -1346 -2407 -1093 1534 1853 1420 -858 -212 -3771 -1104 -1800 -200 -1186 171 -935 2628 2283 3260 3348 3184 -1250 -3398 -867 -2455 -168 -778 3274 1274 868 1165 -179 312 -1666 -3162 -2060 155 -1360 1085 -1858 -790 -1934 747 -1169 1367 3080 1741 2148 -565 -1556 -1813 SS 20250117T002503.4Z 9148.017400 333 1 48.13 2 71.42 145.63 95.14 290.80 0.00 1 0.00 1 0 25 1.924e-01 1.341e-02 9.562e-02 1.821e-03 5.483103e-01 9.050023e-04 6.551132e-03 -6.000000e+00 1.059797e-01 223.58 -2.00 3.56 -2.00 320.04 0.00e+00 2.427715e-03 2.979666e-04 2.325698e-03 -6.000000e+00 4.634787e-03 273.21 -2.00 20.00 -2.00 319.54 0.00e+00 3.100 0.001 302.00 328.00 3 3.9439e+00 2.5915e-03 4.2312e-02 -6.0000e+00 2.6153e-01 -1.2355e-01 3.2120e-03 2.9721e-02 -6.0000e+00 2.8598e-01 4.8878e-02 3.1362e-03 1.6925e-02 -6.0000e+00 1.6959e-01 -2.4151e-02 1.6297e-03 6.1568e-03 -6.0000e+00 7.1765e-02 2.5859e-04 4.4114e-04 4.7838e-05 6.8544e-05 -6.0000e+00 4.8517e-03 3.6330e-03 0.0000e+00 12 9 8 11 8 0 99.79 21.82 0.36 0.00363 0.00695 46 11 1 5 0 1046.040 25.58 20.00 21.82 2.34 3.7 817.29 -92210 22936 -43601 20768 -49951 900000 -87868 104671 -61781 2795 -28443 -45876 -32238 -32957 72750 -17584 9397 -14059 20288 -11963 11155 -13526 -10808 -9451 -11372 -6067 -13089 -15077 -10064 -5465 -8440 316 -12770 -5869 -9087 -4906 -10887 -1759 -4253 1636 -2756 1424 261 108 -720 3395 6187 96 -871 -605 1812 1862 3287 2337 606 3070 1468 1418 217 371 1158 2684 2717 4911 2136 1092 -100 -2835 -363 1310 1266 966 1351 519 -493 -3249 -3790 -6712 -4536 -3830 -2102 -1520 -2597 -1640 -534 1037 1446 2657 2426 2203 930 -485 -2610 -2594 -1893 -1298 641 1908 1492 40 -813 -2465 -2307 -1510 -957 -688 -514 137 1445 1877 2585 1863 1205 -230 -1374 -1456 -1092 -606 5 877 678 1109 1072 285 -124 -1262 -1885 -1078 -681 -395 -445 -765 -866 -353 374 114 778 1075 904 318 -158 -585 -756 -1015 96 -393 103 -436 900000 -1161 240 -829 23 -328 -682 -520 -685 662 -480 221 -462 516 -448 346 -535 -432 -410 -546 -295 -709 -810 -495 -269 -502 20 -1092 -515 -786 -394 -1022 -178 -524 231 -463 246 48 21 -140 652 1176 20 -188 -137 444 491 931 728 204 1044 526 508 77 128 410 1031 1139 2271 1026 525 -47 -1397 -184 762 787 629 869 319 -291 -1756 -1977 -3592 -2540 -2437 -1526 -1207 -2197 -1444 -483 990 1445 2620 2398 2159 853 -433 -2253 -2279 -1786 -1358 732 2386 1965 52 -1032 -2937 -2592 -1683 -1157 -846 -665 183 2009 2814 4106 3019 1934 -364 -2107 -2132 -1613 -937 8 1415 1110 1742 1678 431 -185 -1832 -2640 -1577 -1062 -665 -791 -1396 -1606 -690 760 238 1637 2251 1884 650 -312 -1128 -1432 SS 20250117T003133.8Z 9148.021919 337 1 18.77 2 70.76 147.08 96.23 291.90 0.00 1 0.00 1 0 25 1.671e-01 1.380e-02 5.798e-02 2.284e-03 5.312265e-01 1.123164e-03 6.345607e-03 -6.000000e+00 9.161519e-02 223.58 -2.00 3.56 -2.00 319.90 0.00e+00 2.227341e-03 3.522839e-04 2.209935e-03 -6.000000e+00 3.961374e-03 273.21 -2.00 20.00 -2.00 319.39 0.00e+00 3.000 0.000 302.00 328.00 3 3.5553e+00 3.1896e-03 4.0901e-02 -6.0000e+00 2.2631e-01 -1.0774e-01 3.8957e-03 2.8655e-02 -6.0000e+00 2.4743e-01 2.4709e-02 3.6436e-03 1.5998e-02 -6.0000e+00 1.4705e-01 -1.3010e-02 1.9061e-03 5.6184e-03 -6.0000e+00 6.2338e-02 4.2655e-04 4.0477e-04 6.0140e-05 6.3422e-05 -6.0000e+00 4.2146e-03 4.0547e-03 0.0000e+00 12 9 9 12 1 1 99.43 21.83 0.40 0.00405 0.00710 28 18 1 5 0 646.870 25.58 20.00 21.83 2.60 3.7 819.27 -59040 -77624 -29604 -73585 -55225 1271 -64099 -22246 -58029 -37263 -58864 -43639 -46934 -15336 1117 4149 -8134 -10261 10269 -5117 2605 -10533 2321 -11706 -8538 -3673 -3000 -14504 -13340 -11168 -4224 -7400 -6702 -3303 -8102 -7432 -11296 -3055 -2818 3029 -2419 3242 119 2825 -877 3264 2759 1281 79 764 1286 2324 2120 2813 1866 2184 2136 -358 578 -120 601 3128 3021 4794 2337 1355 -411 -2094 -1400 1393 1480 1712 643 508 -216 -2787 -3638 -6602 -4412 -3437 -2083 -1677 -2987 -1673 -798 684 1818 2325 2439 2096 673 -601 -2605 -2446 -2127 -856 209 1872 1435 71 -752 -2447 -2914 -1455 -1159 -678 -182 104 1433 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