File name: Pandora163s1_Seoul-SNU_20210115_L2Fit_fnvs5c14d20210114p1-8.txt File generation date: 20250326T105514.8Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c14p1-8 Local principal investigator: Jinsoo Park Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 163 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora163_OF_v8d20190605.txt Instrument calibration file used: Pandora163s1_CF_v14d20210114.txt Level 1 file used: Pandora163s1_Seoul-SNU_20210115_L1_smca1c14d20210114p1-8.txt Full location name: School of Earth and Environmental Sciences, Seoul National University Short location name: Seoul-SNU Country of location: Korea, Republic of Location latitude [deg]: 37.4580 Location longitude [deg]: 126.9510 Location altitude [m]: 116 Local noon date: 20210115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 920 1465 Nominal wavelengths inside fitting window [nm]: 400.0755 400.2076 400.3397 400.4718 400.6039 400.7359 400.8680 401.0000 401.1320 401.2640 401.3960 401.5280 401.6599 401.7919 401.9238 402.0557 402.1876 402.3195 402.4514 402.5832 402.7151 402.8469 402.9787 403.1105 403.2423 403.3741 403.5059 403.6376 403.7694 403.9011 404.0328 404.1645 404.2961 404.4278 404.5595 404.6911 404.8227 404.9543 405.0859 405.2175 405.3491 405.4806 405.6122 405.7437 405.8752 406.0067 406.1382 406.2696 406.4011 406.5325 406.6640 406.7954 406.9268 407.0582 407.1895 407.3209 407.4522 407.5836 407.7149 407.8462 407.9775 408.1087 408.2400 408.3712 408.5025 408.6337 408.7649 408.8961 409.0272 409.1584 409.2896 409.4207 409.5518 409.6829 409.8140 409.9451 410.0761 410.2072 410.3382 410.4692 410.6002 410.7312 410.8622 410.9932 411.1241 411.2551 411.3860 411.5169 411.6478 411.7786 411.9095 412.0404 412.1712 412.3020 412.4328 412.5636 412.6944 412.8252 412.9559 413.0866 413.2174 413.3481 413.4788 413.6094 413.7401 413.8708 414.0014 414.1320 414.2626 414.3932 414.5238 414.6544 414.7849 414.9155 415.0460 415.1765 415.3070 415.4375 415.5679 415.6984 415.8288 415.9592 416.0896 416.2200 416.3504 416.4808 416.6111 416.7415 416.8718 417.0021 417.1324 417.2627 417.3929 417.5232 417.6534 417.7836 417.9138 418.0440 418.1742 418.3044 418.4345 418.5647 418.6948 418.8249 418.9550 419.0850 419.2151 419.3452 419.4752 419.6052 419.7352 419.8652 419.9952 420.1251 420.2551 420.3850 420.5149 420.6448 420.7747 420.9046 421.0344 421.1643 421.2941 421.4239 421.5537 421.6835 421.8133 421.9430 422.0728 422.2025 422.3322 422.4619 422.5916 422.7213 422.8509 422.9806 423.1102 423.2398 423.3694 423.4990 423.6285 423.7581 423.8876 424.0172 424.1467 424.2762 424.4056 424.5351 424.6645 424.7940 424.9234 425.0528 425.1822 425.3116 425.4409 425.5703 425.6996 425.8289 425.9582 426.0875 426.2168 426.3460 426.4753 426.6045 426.7337 426.8629 426.9921 427.1213 427.2504 427.3796 427.5087 427.6378 427.7669 427.8960 428.0250 428.1541 428.2831 428.4121 428.5411 428.6701 428.7991 428.9281 429.0570 429.1859 429.3149 429.4438 429.5727 429.7015 429.8304 429.9592 430.0880 430.2169 430.3457 430.4744 430.6032 430.7320 430.8607 430.9894 431.1181 431.2468 431.3755 431.5042 431.6328 431.7614 431.8901 432.0187 432.1473 432.2758 432.4044 432.5329 432.6615 432.7900 432.9185 433.0470 433.1754 433.3039 433.4323 433.5607 433.6892 433.8176 433.9459 434.0743 434.2026 434.3310 434.4593 434.5876 434.7159 434.8442 434.9724 435.1007 435.2289 435.3571 435.4853 435.6135 435.7417 435.8698 435.9980 436.1261 436.2542 436.3823 436.5104 436.6385 436.7665 436.8945 437.0226 437.1506 437.2786 437.4065 437.5345 437.6624 437.7904 437.9183 438.0462 438.1741 438.3019 438.4298 438.5576 438.6855 438.8133 438.9411 439.0689 439.1966 439.3244 439.4521 439.5798 439.7075 439.8352 439.9629 440.0906 440.2182 440.3458 440.4735 440.6011 440.7286 440.8562 440.9838 441.1113 441.2388 441.3663 441.4938 441.6213 441.7488 441.8762 442.0037 442.1311 442.2585 442.3859 442.5133 442.6406 442.7680 442.8953 443.0226 443.1499 443.2772 443.4045 443.5317 443.6590 443.7862 443.9134 444.0406 444.1678 444.2949 444.4221 444.5492 444.6764 444.8035 444.9305 445.0576 445.1847 445.3117 445.4388 445.5658 445.6928 445.8198 445.9467 446.0737 446.2006 446.3275 446.4545 446.5813 446.7082 446.8351 446.9619 447.0888 447.2156 447.3424 447.4692 447.5960 447.7227 447.8495 447.9762 448.1029 448.2296 448.3563 448.4830 448.6096 448.7362 448.8629 448.9895 449.1161 449.2426 449.3692 449.4957 449.6223 449.7488 449.8753 450.0018 450.1283 450.2547 450.3812 450.5076 450.6340 450.7604 450.8868 451.0131 451.1395 451.2658 451.3921 451.5184 451.6447 451.7710 451.8973 452.0235 452.1497 452.2759 452.4021 452.5283 452.6545 452.7806 452.9068 453.0329 453.1590 453.2851 453.4112 453.5372 453.6633 453.7893 453.9153 454.0413 454.1673 454.2933 454.4192 454.5452 454.6711 454.7970 454.9229 455.0488 455.1746 455.3005 455.4263 455.5521 455.6779 455.8037 455.9295 456.0552 456.1810 456.3067 456.4324 456.5581 456.6838 456.8094 456.9351 457.0607 457.1863 457.3119 457.4375 457.5631 457.6886 457.8142 457.9397 458.0652 458.1907 458.3162 458.4416 458.5671 458.6925 458.8179 458.9433 459.0687 459.1941 459.3194 459.4447 459.5701 459.6954 459.8207 459.9459 460.0712 460.1964 460.3217 460.4469 460.5721 460.6972 460.8224 460.9476 461.0727 461.1978 461.3229 461.4480 461.5731 461.6981 461.8232 461.9482 462.0732 462.1982 462.3232 462.4481 462.5731 462.6980 462.8229 462.9478 463.0727 463.1975 463.3224 463.4472 463.5720 463.6968 463.8216 463.9464 464.0712 464.1959 464.3206 464.4453 464.5700 464.6947 464.8194 464.9440 465.0686 465.1932 465.3178 465.4424 465.5670 465.6915 465.8161 465.9406 466.0651 466.1896 466.3140 466.4385 466.5629 466.6873 466.8117 466.9361 467.0605 467.1849 467.3092 467.4335 467.5578 467.6821 467.8064 467.9307 468.0549 468.1791 468.3033 468.4275 468.5517 468.6759 468.8000 468.9242 469.0483 469.1724 469.2965 469.4205 469.5446 469.6686 469.7926 469.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-709: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 710-1255: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210115T020902.8Z 7685.089616 156 1 1.69 2 62.48 155.59 74.03 132.04 0.00 1 0.00 1 0 33 3.574e-03 3.338e-03 3.064e-03 2.893e-03 -7.886508e+01 5.621809e+02 5.775583e+01 3.213737e+02 7.054455e+02 277.76 -2.00 20.00 -2.00 447.44 0.00e+00 -4.846059e-04 3.306926e-04 9.510789e-06 2.214683e-05 3.839948e-04 277.76 -2.00 20.00 -2.00 456.70 0.00e+00 2.161066e-03 2.653298e-05 1.435085e-05 1.325482e-05 3.274194e-05 227.20 -2.00 2.12 -2.00 438.69 0.00e+00 4.933926e+05 4.038711e+05 2.833317e+04 2.005983e+05 5.150543e+05 259.56 -2.00 11.03 -2.00 459.10 0.00e+00 7.183072e-01 7.548208e-02 5.938277e-03 8.002097e-03 1.111330e-01 224.04 -2.00 3.44 -2.00 456.06 0.00e+00 -3.042604e-05 9.764223e-06 3.833675e-07 9.972421e-07 1.363588e-05 277.76 -2.00 20.00 -2.00 457.01 0.00e+00 2.153 0.000 397.00 473.00 4 6.0822e+00 3.1381e-03 5.4418e-03 4.1536e-04 3.6284e-03 -1.0114e-01 3.9179e-03 1.1307e-03 3.2187e-04 4.5781e-03 1.0540e-03 2.1570e-03 1.5158e-04 2.2008e-04 2.5044e-03 2.8767e-03 7.3977e-04 2.2756e-05 5.3268e-05 8.5913e-04 1.1311e-04 3.7990e-04 9.9141e-06 2.1957e-05 4.3374e-04 2.7344e-03 -3.6547e-02 1.8297e-03 5.3223e-05 1.5198e-04 2.1080e-03 2.8700e-06 2.9638e-05 1.8325e-07 8.4631e-07 3.5979e-05 -7.5525e-05 3.9936e-05 1.5942e-07 6.9433e-07 4.9171e-05 -2.6841e-02 8.2557e-05 3.3114e-01 3.0492e-01 3.8396e-03 1.2716e-02 3.3662e-01 12 9 9 12 1 1 999.00 26.00 1.26 -0.02684 -0.02036 2 18 1 4 0 505.040 26.00 20.00 22.34 15.40 30.3 1002.99 74 -644 -335 -831 -362 24 91 -66 964 420 234 451 -475 411 -243 277 -92 288 -469 -294 112 351 783 159 143 210 -192 1051 -437 -245 495 -6 7 440 -63 -129 49 209 182 341 -135 80 528 300 -70 322 209 60 -254 -484 -105 301 439 170 32 -758 126 -235 -268 486 -631 -100 60 240 420 153 85 -339 -194 -114 -1060 -10 70 336 -510 -491 -1981 -697 -1473 -567 -434 -203 -875 340 551 -214 -156 -364 -542 493 -636 -298 -158 219 215 247 215 -127 81 -442 -216 -360 757 -340 230 727 40 -85 403 373 810 459 -127 679 250 177 265 391 112 -368 -18 -561 -135 -302 -53 -13 -633 -117 -321 -415 -514 390 -416 204 48 -374 -798 -339 124 316 251 19 522 73 207 116 139 215 57 669 28 618 -2 367 5 140 -118 -297 -419 254 118 226 543 309 335 -237 408 -36 20 -334 -22 389 -224 203 -263 464 93 358 -151 186 -180 -551 216 495 428 -338 219 327 -423 129 256 -176 -203 279 -112 14 -228 175 -5 148 296 317 568 -305 -67 -129 -158 634 420 -203 -129 250 170 -45 335 236 536 98 82 162 274 522 519 -518 -174 -68 226 -201 -54 686 266 91 487 181 157 -783 294 -118 -196 -242 181 220 -120 76 -518 -339 52 94 -26 -15 -514 267 368 -381 -390 98 -335 -558 -258 -826 -800 -874 -482 -1382 -512 -1445 -628 -91 -624 -76 -53 401 185 -61 -391 -349 36 -487 89 -66 -83 279 -67 69 118 63 509 437 467 685 337 409 -211 -449 482 -54 737 26 382 148 269 361 571 -70 88 284 -82 -166 -381 515 537 232 434 -7 -220 -104 4 -80 474 314 14 -22 -575 -573 -370 339 64 -61 306 -185 84 -112 21 -49 -418 -402 396 -30 253 -158 71 -199 -123 -302 216 51 289 136 -5 30 424 -174 21 -161 -144 273 327 255 201 -197 -101 139 -152 195 -62 474 -156 62 -123 289 56 -589 112 308 179 -327 408 -33 196 -49 -117 122 309 -505 -525 -197 20 316 428 -123 -204 -229 -61 -16 439 176 -479 70 -168 5 -465 -1 -297 -71 -277 -196 -206 -181 -300 -353 -742 -239 -259 -189 -54 266 128 152 149 173 94 225 -225 -149 203 419 134 565 -241 409 -153 214 433 -266 58 344 -106 -335 7 181 -548 -186 -324 296 -19 266 208 -6 -185 339 -316 195 512 -211 -105 -98 -78 -400 -475 460 -163 12 -650 -203 44 -527 -220 90 280 111 -270 205 -32 290 429 -185 -314 251 -378 206 428 52 -265 -167 345 572 -215 -334 377 148 -84 134 10 -221 -46 157 98 176 42 446 73 -33 167 387 306 -43 18 402 379 -232 -291 -366 -143 457 56 -1 -65 327 74 -78 -33 15 30 43 -153 -134 -250 -148 -336 157 -125 489 -105 -492 -63 227 -500 -20 -139 -109 111 -237 190 468 -148 -197 56 -494 -249 -602 -258 17 67 -51 747 318 178 342 -363 314 -187 216 -72 225 -371 -235 89 275 611 119 107 159 -147 842 -356 -202 404 -5 6 331 -46 -96 39 170 147 280 -109 63 421 232 -55 253 167 47 -195 -374 -82 245 358 138 26 -615 101 -187 -217 393 -517 -84 51 204 355 128 74 -303 -173 -101 -925 -8 60 276 -406 -382 -1545 -528 -1118 -458 -361 -176 -746 290 475 -191 -138 -329 -489 436 -561 -260 -138 193 189 215 192 -112 70 -375 -179 -299 638 -303 206 666 37 -75 353 321 702 398 -114 605 222 156 230 336 96 -322 -16 -502 -124 -282 -49 -12 -581 -106 -286 -374 -452 331 -352 173 41 -331 -717 -303 110 280 222 17 454 64 184 103 127 196 51 592 24 515 -2 310 4 122 -107 -268 -384 232 109 209 497 279 297 -209 362 -33 19 -304 -19 323 -181 165 -222 412 84 326 -134 165 -158 -481 190 433 381 -310 195 298 -380 112 222 -155 -177 246 -102 13 -207 155 -4 128 263 287 520 -282 -62 -113 -133 519 346 -165 -108 220 150 -40 296 207 466 85 73 141 230 433 435 -447 -153 -58 194 -168 -43 526 197 67 364 136 115 -562 212 -87 -148 -189 153 196 -113 73 -512 -328 49 83 -22 -13 -440 239 343 -363 -376 93 -317 -523 -230 -697 -648 -700 -402 -1220 -469 -1357 -585 -85 -583 -68 -48 363 169 -56 -367 -331 34 -465 86 -66 -81 272 -64 66 112 59 480 405 434 645 318 390 -201 -409 415 -45 622 22 348 134 245 330 527 -64 83 269 -79 -158 -359 481 491 212 398 -6 -207 -102 4 -80 460 306 14 -22 -567 -576 -370 333 64 -61 299 -183 83 -110 20 -48 -404 -390 378 -30 247 -154 69 -191 -120 -290 210 50 281 132 -5 29 394 -163 20 -150 -136 254 310 248 195 -195 -101 137 -150 196 -62 479 -160 63 -125 292 55 -567 110 303 179 -336 416 -33 196 -49 -118 124 314 -522 -550 -209 21 330 453 -133 -222 -252 -67 -18 476 190 -516 76 -181 5 -504 -2 -325 -78 -299 -212 -217 -190 -309 -361 -767 -249 -271 -200 -59 287 142 173 170 196 106 252 -251 -167 223 458 148 624 -270 459 -174 247 497 -313 69 406 -124 -398 9 216 -650 -226 -393 356 -23 322 253 -7 -222 405 -373 232 607 -254 -125 -119 -96 -498 -593 564 -200 14 -792 -254 55 -659 -275 112 350 140 -338 259 -41 374 553 -239 -404 321 -489 266 554 68 -347 -221 454 749 -284 -438 489 192 -109 173 13 -293 -60 205 128 231 56 593 97 -44 216 492 390 -56 24 527 499 -307 -387 -492 -194 628 75 -2 -87 434 95 -100 -43 19 39 58 -202 -179 -337 -199 -448 206 -163 637 -139 -666 -83 302 -668 -26 -184 -145 148 -318 256 625 -197 -263 SQ 20210115T041633.7Z 7685.178168 234 1 51.42 2 59.12 189.51 59.86 159.95 0.00 1 0.00 1 0 33 2.809e-03 2.655e-03 2.352e-03 2.193e-03 -1.876115e+02 4.406593e+02 3.428926e+01 3.210856e+02 5.543604e+02 277.76 -2.00 20.00 -2.00 447.75 0.00e+00 4.980187e-04 2.530050e-04 6.531928e-06 2.181330e-05 3.050806e-04 277.76 -2.00 20.00 -2.00 457.22 0.00e+00 1.507725e-03 2.034665e-05 1.009444e-05 1.331371e-05 2.565600e-05 227.68 -2.00 2.12 -2.00 438.50 0.00e+00 1.014794e+06 3.157448e+05 1.502836e+04 2.003339e+05 4.048959e+05 259.55 -2.00 11.03 -2.00 459.99 0.00e+00 3.524949e-01 5.660673e-02 3.518954e-03 7.785840e-03 8.750272e-02 224.04 -2.00 3.44 -2.00 456.60 0.00e+00 -4.014250e-06 7.440389e-06 2.662665e-07 9.973293e-07 1.071447e-05 277.76 -2.00 20.00 -2.00 457.64 0.00e+00 1.941 0.000 397.00 473.00 4 8.2130e+00 2.4761e-03 4.8935e-03 4.1486e-04 2.8434e-03 1.6794e-02 2.9091e-03 1.0182e-03 3.0273e-04 3.5319e-03 -1.7470e-02 1.7021e-03 1.3398e-04 2.2169e-04 2.0327e-03 -1.8242e-03 5.6214e-04 2.6806e-05 5.1482e-05 6.7872e-04 2.1715e-03 2.8999e-04 1.7286e-05 2.1273e-05 3.4165e-04 3.2802e-04 -4.0068e-03 1.6575e-03 3.8911e-05 1.5504e-04 1.6938e-03 -1.5509e-04 2.3370e-05 1.7245e-07 6.7898e-07 2.8269e-05 -1.4462e-05 3.0150e-05 1.7235e-07 6.7363e-07 3.8643e-05 -1.8162e-02 4.3749e-06 3.9423e-01 2.3891e-01 2.5176e-03 1.2004e-02 2.6401e-01 12 8 8 10 0 0 99.96 26.00 1.35 -0.01816 -0.02034 33 6 1 4 0 1557.800 26.00 20.00 22.32 17.43 30.5 1014.22 -97 360 -223 61 280 186 -155 530 -225 -86 -158 1 -167 -337 542 464 -178 -25 333 -194 -538 -386 236 -274 -160 611 -667 -435 -105 -198 -471 -79 371 -247 391 -439 -46 -12 -199 83 -218 184 -81 250 7 -530 322 318 -426 134 -1 556 -15 -269 379 248 -70 388 112 -324 -199 33 -53 526 76 372 273 -28 -251 682 -225 91 -118 139 -665 -416 193 517 130 -55 -99 401 260 -126 125 310 221 137 261 513 35 81 -250 -77 -156 -82 243 -57 228 38 -101 102 137 462 -19 417 33 460 -435 -101 -28 -93 -425 -321 325 -129 -60 315 -251 -167 38 260 -698 -368 -48 -213 -291 -189 14 -302 -75 -7 -119 -874 691 -682 97 173 -323 4 -260 -193 45 16 32 455 37 3 382 -291 -317 -69 -120 -510 643 -397 81 15 -107 712 555 249 -779 183 192 -370 87 401 118 -345 59 -169 24 4 -136 -509 368 -132 42 -15 118 497 -290 691 -342 -112 -411 308 -311 80 -496 -446 -62 -449 -322 114 -106 -175 -21 295 41 -15 -44 -120 7 213 -333 -231 173 -345 -211 129 80 52 -195 -193 392 -98 -511 -57 -420 85 216 468 393 411 24 85 75 -143 357 -354 377 293 284 -47 -232 206 -547 -192 -457 579 317 411 134 -146 149 17 591 -266 -209 136 279 436 427 379 -200 151 -62 428 3 -261 -761 147 -82 63 -190 -2 163 192 -206 66 200 -107 187 -43 -13 190 -72 -33 -520 -13 -3 49 227 -288 380 -154 735 -375 96 -117 176 214 -27 410 69 -328 -27 -167 140 694 10 65 -418 -301 225 -155 255 -242 235 -393 22 -479 -292 -44 -380 -512 -260 -83 113 399 -71 -311 -163 -103 252 199 17 49 124 211 123 448 -256 238 -272 119 -248 140 210 48 -417 -490 -46 -37 418 6 23 -124 647 -235 -217 348 -111 201 -196 -226 -387 -172 410 152 35 515 210 275 240 -546 151 -277 129 -95 474 -561 124 -161 649 177 45 88 -293 -279 -68 219 166 -151 -304 60 124 267 342 6 211 296 373 246 -502 -432 -230 429 601 -109 48 -105 -61 -215 -275 -388 -580 -271 -403 -150 -196 67 -208 205 -266 34 -3 -50 -335 106 43 -259 27 16 355 -154 191 336 1 444 -195 -59 258 204 -406 -210 -120 49 99 -51 227 -19 -187 -255 -124 -272 -59 -238 124 -14 47 -168 -397 416 -101 172 -69 2 89 139 44 -255 -4 195 184 -685 242 96 -81 -27 -148 153 -184 -30 292 -97 -232 154 553 -78 -18 7 270 426 -98 -242 -88 -104 -123 -81 -29 -114 22 117 10 51 93 10 145 -204 598 -242 386 114 126 58 -24 22 -167 77 -215 -45 105 -90 318 -111 -403 240 -174 30 107 279 -139 -123 -187 196 77 188 -33 378 -316 119 -248 -78 49 138 -79 -30 -7 -179 3 -40 180 -346 -74 280 -169 45 203 136 -117 413 -180 -69 -128 0 -135 -274 438 383 -149 -21 276 -164 -454 -322 188 -210 -119 455 -524 -361 -91 -173 -411 -67 300 -189 288 -328 -36 -10 -172 71 -183 150 -65 200 5 -435 258 248 -330 103 -1 469 -13 -227 317 206 -59 318 90 -264 -169 29 -47 461 67 334 254 -27 -239 634 -208 82 -104 119 -549 -324 142 376 98 -45 -85 354 233 -114 114 289 212 133 253 488 34 76 -237 -73 -147 -77 227 -53 206 33 -88 89 121 424 -19 407 32 431 -394 -90 -25 -86 -401 -303 302 -119 -55 284 -225 -151 35 246 -680 -364 -48 -209 -281 -180 13 -279 -67 -6 -103 -763 607 -615 88 156 -292 3 -233 -171 39 14 28 416 35 3 348 -259 -270 -57 -100 -429 552 -353 74 14 -101 672 528 238 -745 170 175 -336 80 374 111 -320 51 -136 18 3 -110 -448 338 -121 38 -13 100 418 -250 606 -307 -101 -379 279 -278 69 -416 -378 -53 -391 -286 102 -94 -151 -18 247 36 -13 -41 -113 7 184 -272 -179 130 -264 -170 109 70 46 -170 -166 334 -83 -432 -47 -336 67 171 375 322 340 20 64 53 -94 224 -223 240 187 177 -29 -138 123 -351 -135 -358 496 293 398 132 -141 137 15 463 -203 -165 115 254 410 404 358 -187 136 -52 330 2 -186 -567 117 -70 55 -173 -2 145 166 -175 56 173 -95 170 -39 -12 178 -68 -32 -505 -13 -3 46 208 -263 340 -136 643 -335 88 -108 156 177 -21 306 52 -263 -23 -143 121 593 8 58 -376 -275 205 -140 226 -210 198 -331 18 -413 -262 -41 -366 -493 -246 -77 103 370 -68 -305 -158 -99 238 187 16 47 117 199 115 408 -230 213 -248 110 -234 130 191 43 -378 -451 -43 -34 386 5 21 -110 557 -199 -181 291 -94 172 -171 -202 -355 -158 377 140 32 478 199 266 235 -540 147 -265 119 -86 429 -526 119 -158 632 172 44 84 -284 -271 -66 215 165 -153 -311 62 128 282 364 6 226 316 398 261 -534 -454 -240 447 628 -116 51 -112 -64 -223 -280 -385 -568 -262 -395 -149 -195 68 -215 217 -289 38 -4 -56 -374 117 47 -283 29 17 383 -167 209 371 1 503 -227 -70 309 244 -482 -247 -142 59 119 -63 275 -23 -228 -314 -154 -338 -72 -289 148 -16 56 -200 -480 508 -126 216 -87 3 112 173 55 -320 -5 245 232 -873 307 123 -105 -36 -197 206 -249 -40 391 -131 -313 207 744 -107 -24 10 373 587 -135 -333 -120 -144 -169 -111 -40 -155 30 158 13 68 127 14 198 -276 794 -320 507 152 172 79 -33 30 -230 107 -305 -64 150 -127 441 -151 -529 307 -223 38 142 375 -190 -170 -259 271 106 255 -45 509 -431 163 -345 -108 68 189 -109 -41 -10 -248 5 -55 245 -466