File name: Pandora77s1_Singapore-NUS_20231029_L2Fit_fout2c3d20230113p1-8.txt File generation date: 20240314T223203.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Santo V. Salinas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 77 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora77_OF_v2d20220405.txt Instrument calibration file used: Pandora77s1_CF_v3d20230113.txt Level 1 file used: Pandora77s1_Singapore-NUS_20231029_L1_smca1c3d20230113p1-8.txt Full location name: Centre for Remote Imaging Sensing and Processing (CRISP), National University of Short location name: Singapore-NUS Country of location: Singapore Location latitude [deg]: 1.2990 Location longitude [deg]: 103.7710 Location altitude [m]: 77 Local noon date: 20231029 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0008 305.1420 305.2832 305.4244 305.5656 305.7068 305.8480 305.9891 306.1303 306.2714 306.4126 306.5537 306.6948 306.8359 306.9770 307.1181 307.2591 307.4002 307.5412 307.6822 307.8233 307.9643 308.1053 308.2463 308.3872 308.5282 308.6691 308.8101 308.9510 309.0919 309.2328 309.3737 309.5146 309.6555 309.7964 309.9372 310.0780 310.2189 310.3597 310.5005 310.6413 310.7821 310.9228 311.0636 311.2043 311.3451 311.4858 311.6265 311.7672 311.9079 312.0486 312.1893 312.3299 312.4706 312.6112 312.7518 312.8924 313.0331 313.1736 313.3142 313.4548 313.5953 313.7359 313.8764 314.0169 314.1574 314.2979 314.4384 314.5789 314.7194 314.8598 315.0003 315.1407 315.2811 315.4215 315.5619 315.7023 315.8427 315.9830 316.1234 316.2637 316.4040 316.5444 316.6847 316.8250 316.9652 317.1055 317.2458 317.3860 317.5262 317.6665 317.8067 317.9469 318.0871 318.2272 318.3674 318.5076 318.6477 318.7878 318.9279 319.0680 319.2081 319.3482 319.4883 319.6284 319.7684 319.9084 320.0485 320.1885 320.3285 320.4685 320.6085 320.7484 320.8884 321.0283 321.1683 321.3082 321.4481 321.5880 321.7279 321.8678 322.0076 322.1475 322.2873 322.4271 322.5670 322.7068 322.8466 322.9863 323.1261 323.2659 323.4056 323.5454 323.6851 323.8248 323.9645 324.1042 324.2439 324.3835 324.5232 324.6628 324.8025 324.9421 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231028T231504.6Z 8701.968804 231 1 50.90 2 83.89 103.50 95.89 284.96 0.00 1 0.00 1 0 33 5.601e-01 4.056e-02 2.482e-01 1.375e-02 7.098497e-01 9.093705e-03 1.331383e-02 -6.000000e+00 3.627134e-01 228.35 -2.00 3.05 -2.00 322.03 0.00e+00 2.905048e-02 6.109393e-03 2.370413e-02 -6.000000e+00 4.539117e-02 293.60 -2.00 20.00 -2.00 321.48 0.00e+00 8.399 0.000 302.00 328.00 3 1.6148e+00 3.9533e-02 1.4290e-01 -6.0000e+00 9.2947e-01 8.8848e-01 5.4293e-02 1.2639e-01 -6.0000e+00 1.0300e+00 -9.6281e-01 5.0366e-02 3.0609e-02 -6.0000e+00 5.9038e-01 3.4311e-01 2.3462e-02 7.4572e-03 -6.0000e+00 2.6935e-01 1.2057e-05 1.8645e-04 4.7797e-04 4.2437e-04 -6.0000e+00 1.9262e-02 2.1709e-03 2.1402e-05 12 9 8 11 32 0 59.33 24.60 1.04 0.00217 0.00357 17 3 1 5 0 2994.070 26.94 20.00 24.60 32.40 6.9 1017.61 900000 900000 900000 -17037 900000 900000 23716 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -127234 -53770 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -70453 900000 900000 900000 900000 900000 33313 900000 900000 74234 900000 900000 900000 -17101 900000 102620 49189 222074 900000 -18674 900000 11567 90061 900000 -22032 151834 162793 310795 47169 21314 28356 70357 91637 71847 34960 43670 47436 -15765 4609 32753 65640 6739 -10422 30458 8520 22357 6511 -12856 4245 20460 1325 -4396 1928 -6412 3733 2145 -2824 -4301 -520 3499 950 2860 -3631 1180 -2221 -2106 1768 -7208 -8936 5328 -5350 -3725 -14229 -4180 5307 1063 -739 -339 -1182 -5720 4524 -1502 791 -643 1365 4892 1411 6343 -355 2829 6717 1435 832 -406 92 -1814 678 -1077 -456 1027 413 830 711 -241 -1430 -609 -1830 432 900000 900000 900000 -226 900000 900000 314 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -10267 -1943 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -4582 900000 900000 900000 900000 900000 1244 900000 900000 2360 900000 900000 900000 -1631 900000 3399 3063 2942 900000 -2697 900000 1211 4176 900000 -3006 3822 4098 4117 4999 3163 3907 6245 6677 6853 5465 6885 7478 -4595 1026 4990 6435 1107 -2071 4560 1919 5213 2044 -5399 1591 6912 576 -2126 904 -3287 1681 921 -1190 -1766 -212 1548 510 1784 -2823 971 -1924 -1724 1256 -5071 -6310 3480 -4146 -3025 -13931 -4114 5400 1152 -876 -407 -1394 -6744 5131 -1670 908 -798 1734 5968 1720 7806 -453 3373 7466 1645 1011 -518 134 -2987 1174 -2014 -905 2153 920 1890 1650 -565 -3269 -1300 -3729 836 SS 20231028T232723.5Z 8701.977355 234 1 50.31 2 80.90 103.67 98.75 285.17 0.00 1 0.00 1 0 25 3.843e-01 8.710e-03 2.058e-01 2.593e-03 6.029123e-01 1.388940e-03 6.224250e-03 -6.000000e+00 2.222714e-01 228.35 -2.00 3.05 -2.00 320.90 0.00e+00 8.832321e-04 6.460354e-04 2.699686e-03 -6.000000e+00 1.040374e-02 293.60 -2.00 20.00 -2.00 320.17 0.00e+00 5.991 0.000 302.00 328.00 3 1.4072e+00 4.7270e-03 6.5953e-02 -6.0000e+00 5.5058e-01 3.6699e-02 6.3849e-03 3.2926e-02 -6.0000e+00 5.9605e-01 -7.4911e-02 6.0278e-03 1.4922e-02 -6.0000e+00 3.5752e-01 1.9769e-02 2.9280e-03 3.9203e-03 -6.0000e+00 1.5275e-01 2.1220e-04 -4.4490e-04 7.5038e-05 5.9536e-05 -6.0000e+00 1.0805e-02 4.3296e-04 -2.1305e-05 11 8 0 10 0 0 14.96 24.61 0.53 0.00043 -0.00291 101 19 1 5 0 498.100 26.94 20.01 24.61 33.37 6.9 1024.95 -143892 -54584 -31111 -158839 900000 -156741 -89675 88480 84978 -179938 73898 -124195 -93294 -27744 57020 39719 -4554 -37030 -28898 18411 15963 152577 -15060 -11890 17975 -21378 17735 -31660 61465 -19385 5181 -6047 13978 -15 -19149 8135 -15640 -4268 -739 1617 12071 4905 4382 -594 -5221 1691 5933 -5140 70 -2955 2576 -5244 3651 2320 6321 3432 -762 1288 3411 -2075 -813 2765 2449 4145 4769 1659 -2059 -2176 2699 1886 2753 1064 2193 -785 894 -839 -3207 -3243 -2986 -2265 -2858 -1397 -2174 -695 -711 817 535 1094 1000 1149 815 -144 -238 -1701 -764 -713 528 649 415 -249 -816 -1001 -1490 -1232 -1378 -858 -889 6 400 1141 1163 445 468 -50 -465 -232 -432 46 111 -41 636 708 429 336 -192 69 -132 102 30 -732 -366 -350 -202 -411 6 134 561 553 249 56 -318 -356 -303 -1124 -213 -107 -2008 900000 -1729 -536 224 215 -3929 187 -1798 -1201 -236 262 265 -54 -681 -538 228 234 579 -316 -265 327 -621 363 -1048 777 -568 136 -212 470 -1 -992 313 -818 -234 -48 126 980 467 445 -66 -615 190 652 -648 9 -403 366 -905 638 449 1264 743 -179 300 763 -482 -190 677 680 1276 1564 556 -699 -753 965 782 1271 483 990 -350 399 -344 -1241 -1243 -1244 -1099 -1491 -824 -1432 -482 -528 642 446 941 868 969 647 -108 -170 -1247 -611 -655 508 714 503 -308 -963 -1078 -1480 -1216 -1461 -965 -1057 8 504 1592 1794 734 778 -80 -714 -340 -634 70 180 -69 1081 1169 687 522 -288 100 -184 147 48 -1237 -676 -691 -417 -844 13 310 1329 1252 567 132 -712 -756 -626 SS 20231028T233731.3Z 8701.984390 239 1 50.53 2 78.44 103.84 101.10 285.37 0.00 1 0.00 1 0 17 1.697e-01 7.510e-03 2.242e-02 1.055e-03 5.014633e-01 5.468120e-04 5.176056e-03 -6.000000e+00 9.809579e-02 228.35 -2.00 3.05 -2.00 319.96 0.00e+00 1.271737e-03 1.835981e-04 1.533860e-03 -6.000000e+00 4.517197e-03 293.60 -2.00 20.00 -2.00 319.12 0.00e+00 4.824 0.000 302.00 328.00 3 1.0177e+00 1.6349e-03 5.2739e-02 -6.0000e+00 2.4307e-01 1.1027e-02 2.0030e-03 2.4504e-02 -6.0000e+00 2.6314e-01 -3.8196e-02 1.6404e-03 1.1626e-02 -6.0000e+00 1.5784e-01 6.3235e-03 8.4767e-04 3.0846e-03 -6.0000e+00 6.7373e-02 1.0229e-03 -4.0802e-04 3.0585e-05 3.9989e-05 -6.0000e+00 4.6883e-03 2.7215e-04 -2.1581e-05 11 8 0 10 0 0 -3.35 24.61 0.40 0.00027 -0.00279 263 50 1 5 0 192.120 26.94 20.01 24.61 34.46 6.9 1031.87 -60806 -66537 -50753 -52198 -45104 -71817 -67916 -23397 -54159 -51985 -47670 -42743 -34708 -24080 -14033 -18114 -3728 -21291 -3412 -10956 -2504 -2409 -7325 -7441 -3796 -4601 -7422 -5338 -7864 -6653 -9150 -3320 -2265 -3023 -5691 -6939 -6939 -3351 119 -1082 2075 959 2091 1519 409 1098 517 428 -221 8 587 1842 1874 1989 2446 1769 1159 156 1161 -729 670 1494 2670 2946 1953 1223 -656 -85 470 1388 1462 1777 922 495 -251 -938 -2155 -3316 -2120 -2493 -1643 -2054 -1666 -1661 -681 72 505 1014 1082 1260 616 171 -816 -422 -725 -248 502 678 388 -465 -471 -1444 -1074 -1038 -1089 -1223 -858 -410 69 1017 824 813 428 177 -328 -114 -326 150 231 192 293 475 630 333 176 -88 136 266 127 -116 -326 -241 -463 -42 -278 74 376 411 275 -85 -138 -421 -382 -739 -1027 -736 -776 -578 -1135 -1080 -269 -972 -1011 -932 -928 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