File name: Pandora77s1_Singapore-NUS_20241204_L2Fit_fwvt1c3d20230113p1-8.txt File generation date: 20241204T170847.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Santo V. Salinas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 77 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora77_OF_v2d20220405.txt Instrument calibration file used: Pandora77s1_CF_v3d20230113.txt Level 1 file used: Pandora77s1_Singapore-NUS_20241204_L1_smca1c3d20230113p1-8.txt Full location name: Centre for Remote Imaging Sensing and Processing (CRISP), National University of Short location name: Singapore-NUS Country of location: Singapore Location latitude [deg]: 1.2990 Location longitude [deg]: 103.7710 Location altitude [m]: 77 Local noon date: 20241204 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1613 1761 Nominal wavelengths inside fitting window [nm]: 492.0937 492.2153 492.3368 492.4583 492.5798 492.7012 492.8227 492.9441 493.0655 493.1869 493.3083 493.4297 493.5511 493.6724 493.7937 493.9150 494.0363 494.1576 494.2788 494.4001 494.5213 494.6425 494.7637 494.8849 495.0060 495.1271 495.2483 495.3694 495.4905 495.6115 495.7326 495.8536 495.9747 496.0957 496.2166 496.3376 496.4586 496.5795 496.7004 496.8213 496.9422 497.0631 497.1840 497.3048 497.4256 497.5464 497.6672 497.7880 497.9088 498.0295 498.1502 498.2709 498.3916 498.5123 498.6329 498.7536 498.8742 498.9948 499.1154 499.2360 499.3565 499.4771 499.5976 499.7181 499.8386 499.9591 500.0795 500.2000 500.3204 500.4408 500.5612 500.6816 500.8019 500.9223 501.0426 501.1629 501.2832 501.4035 501.5237 501.6439 501.7642 501.8844 502.0046 502.1247 502.2449 502.3650 502.4852 502.6053 502.7253 502.8454 502.9655 503.0855 503.2055 503.3255 503.4455 503.5655 503.6854 503.8054 503.9253 504.0452 504.1651 504.2850 504.4048 504.5247 504.6445 504.7643 504.8841 505.0038 505.1236 505.2433 505.3630 505.4827 505.6024 505.7221 505.8417 505.9614 506.0810 506.2006 506.3202 506.4397 506.5593 506.6788 506.7983 506.9178 507.0373 507.1568 507.2762 507.3957 507.5151 507.6345 507.7538 507.8732 507.9925 508.1119 508.2312 508.3505 508.4698 508.5890 508.7083 508.8275 508.9467 509.0659 509.1851 509.3042 509.4234 509.5425 509.6616 509.7807 509.8998 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241203T232246.3Z 9103.974147 46 1 32.79 2 84.10 112.54 116.28 120.18 0.00 1 0.00 1 0 22 3.960e-03 3.898e-03 2.861e-04 2.855e-04 2.397131e+04 2.235405e+01 1.512264e+03 -6.000000e+00 2.264533e+02 293.71 -2.00 20.00 -2.00 505.33 0.00e+00 6.933237e-03 8.117633e-06 3.938592e-04 -6.000000e+00 1.139347e-04 293.71 -2.00 20.00 -2.00 500.54 0.00e+00 9.273256e-01 5.628253e-03 1.303320e-01 -6.000000e+00 7.782447e-02 226.54 -2.00 3.05 -2.00 502.10 0.00e+00 8.639 0.001 489.00 513.00 1 4.2183e+00 4.3218e-04 1.8955e-02 -6.0000e+00 5.9825e-03 -1.0760e-02 1.0948e-04 3.1348e-03 -6.0000e+00 1.5631e-03 6.9612e-03 1.5282e-03 2.3770e-05 1.8536e-04 -6.0000e+00 3.8634e-04 -5.0144e-03 7.9814e-05 12 9 1 12 1 1 72.02 25.31 0.84 -0.00501 0.00559 92 27 1 4 0 352.520 27.56 20.00 25.31 33.61 11.5 1004.88 -609 -361 -157 271 398 583 651 449 449 205 -72 -182 -369 -449 -491 -219 -107 -97 95 27 15 224 260 306 580 515 216 -41 -179 -629 -465 -220 -120 196 194 62 3 -116 -208 -171 -7 123 272 429 511 474 402 92 -234 -478 -839 -853 -755 -408 -112 38 153 120 221 292 360 454 373 314 208 82 -116 -309 -254 -441 -394 -187 -115 -26 -174 -191 -435 -514 -414 -497 -524 -305 -259 -178 -146 -304 -194 -53 129 499 622 770 956 762 509 389 -117 -442 -858 -1027 -842 -643 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8.020043e+00 1.166290e+03 -6.000000e+00 2.077138e+02 293.71 -2.00 20.00 -2.00 505.31 0.00e+00 5.293655e-03 3.030759e-06 3.011838e-04 -6.000000e+00 1.045046e-04 293.71 -2.00 20.00 -2.00 500.50 0.00e+00 6.547696e-01 2.103052e-03 1.023654e-01 -6.000000e+00 7.137931e-02 226.54 -2.00 3.05 -2.00 502.08 0.00e+00 6.238 0.000 489.00 513.00 1 3.0885e+00 1.6155e-04 1.4293e-02 -6.0000e+00 5.4871e-03 -6.1213e-03 4.1114e-05 2.4351e-03 -6.0000e+00 1.4335e-03 3.1841e-02 1.3347e-03 9.2820e-06 1.4477e-04 -6.0000e+00 3.5438e-04 -6.4804e-03 9.4064e-05 10 0 0 10 0 0 67.74 25.35 0.71 -0.00648 0.00278 631 119 1 4 0 79.930 27.56 20.00 25.35 33.93 11.6 1007.38 -646 -404 -200 242 356 516 615 459 423 213 -84 -175 -341 -447 -453 -256 -105 -65 142 82 77 244 239 296 516 495 193 6 -146 -614 -443 -159 -111 115 208 66 -25 -104 -170 -140 -15 111 232 399 435 479 383 103 -158 -438 -802 -755 -661 -436 -170 15 98 103 217 292 333 383 347 312 257 110 -93 -281 -214 -375 -318 -136 -95 -27 -80 -177 -387 -484 -473 -550 -545 -374 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119.24 0.00 1 0.00 1 0 22 3.539e-03 3.501e-03 1.142e-04 1.140e-04 1.576370e+04 8.401331e+00 1.017471e+03 -6.000000e+00 2.024175e+02 293.71 -2.00 20.00 -2.00 505.30 0.00e+00 4.603430e-03 3.233117e-06 2.620389e-04 -6.000000e+00 1.018408e-04 293.71 -2.00 20.00 -2.00 500.49 0.00e+00 5.346210e-01 2.245823e-03 9.058788e-02 -6.000000e+00 6.956135e-02 226.54 -2.00 3.05 -2.00 502.06 0.00e+00 5.291 0.000 489.00 513.00 1 3.3755e+00 1.7251e-04 1.2390e-02 -6.0000e+00 5.3473e-03 -5.0111e-03 4.4041e-05 2.1405e-03 -6.0000e+00 1.3971e-03 2.7930e-02 1.3339e-03 1.0097e-05 1.2602e-04 -6.0000e+00 3.4534e-04 -6.8777e-03 9.4168e-05 10 0 0 10 0 0 89.99 25.35 0.68 -0.00688 0.00238 597 113 1 4 0 84.450 27.56 20.00 25.35 34.16 11.5 1008.18 -627 -416 -231 214 349 516 598 440 439 219 -64 -175 -302 -445 -437 -249 -115 -58 139 74 91 253 248 274 506 465 163 5 -136 -604 -429 -167 -131 101 196 54 9 -93 -166 -155 -8 119 236 381 426 484 387 93 -127 -408 -796 -746 -645 -474 -178 24 119 91 201 289 326 382 328 330 257 94 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