File name: Pandora77s1_Singapore-NUS_20250124_L2Fit_fnvs4c3d20230113p1-8.txt File generation date: 20250124T172530.2Z Data description: Level 2 spectral fitting results file Data file version: fnvs4c3p1-8 Local principal investigator: Santo V. Salinas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 77 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora77_OF_v2d20220405.txt Instrument calibration file used: Pandora77s1_CF_v3d20230113.txt Level 1 file used: Pandora77s1_Singapore-NUS_20250124_L1_smca1c3d20230113p1-8.txt Full location name: Centre for Remote Imaging Sensing and Processing (CRISP), National University of Short location name: Singapore-NUS Country of location: Singapore Location latitude [deg]: 1.2990 Location longitude [deg]: 103.7710 Location altitude [m]: 77 Local noon date: 20250124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 890 1433 Nominal wavelengths inside fitting window [nm]: 400.1322 400.2647 400.3973 400.5298 400.6623 400.7948 400.9272 401.0597 401.1922 401.3246 401.4570 401.5894 401.7218 401.8542 401.9865 402.1189 402.2512 402.3835 402.5158 402.6481 402.7804 402.9127 403.0449 403.1771 403.3094 403.4416 403.5738 403.7059 403.8381 403.9703 404.1024 404.2345 404.3666 404.4987 404.6308 404.7628 404.8949 405.0269 405.1589 405.2910 405.4229 405.5549 405.6869 405.8188 405.9508 406.0827 406.2146 406.3465 406.4784 406.6102 406.7421 406.8739 407.0057 407.1375 407.2693 407.4011 407.5329 407.6646 407.7964 407.9281 408.0598 408.1915 408.3232 408.4548 408.5865 408.7181 408.8497 408.9813 409.1129 409.2445 409.3761 409.5076 409.6392 409.7707 409.9022 410.0337 410.1651 410.2966 410.4281 410.5595 410.6909 410.8223 410.9537 411.0851 411.2165 411.3478 411.4791 411.6105 411.7418 411.8731 412.0043 412.1356 412.2668 412.3981 412.5293 412.6605 412.7917 412.9229 413.0540 413.1852 413.3163 413.4474 413.5785 413.7096 413.8407 413.9718 414.1028 414.2338 414.3649 414.4959 414.6268 414.7578 414.8888 415.0197 415.1507 415.2816 415.4125 415.5434 415.6742 415.8051 415.9359 416.0668 416.1976 416.3284 416.4592 416.5900 416.7207 416.8515 416.9822 417.1129 417.2436 417.3743 417.5050 417.6356 417.7663 417.8969 418.0275 418.1581 418.2887 418.4193 418.5498 418.6804 418.8109 418.9414 419.0719 419.2024 419.3328 419.4633 419.5937 419.7242 419.8546 419.9850 420.1154 420.2457 420.3761 420.5064 420.6367 420.7670 420.8973 421.0276 421.1579 421.2881 421.4184 421.5486 421.6788 421.8090 421.9392 422.0693 422.1995 422.3296 422.4598 422.5899 422.7200 422.8500 422.9801 423.1101 423.2402 423.3702 423.5002 423.6302 423.7602 423.8901 424.0201 424.1500 424.2799 424.4098 424.5397 424.6696 424.7994 424.9293 425.0591 425.1889 425.3187 425.4485 425.5783 425.7080 425.8378 425.9675 426.0972 426.2269 426.3566 426.4863 426.6159 426.7456 426.8752 427.0048 427.1344 427.2640 427.3936 427.5231 427.6526 427.7822 427.9117 428.0412 428.1706 428.3001 428.4296 428.5590 428.6884 428.8178 428.9472 429.0766 429.2059 429.3353 429.4646 429.5939 429.7232 429.8525 429.9818 430.1111 430.2403 430.3695 430.4987 430.6279 430.7571 430.8863 431.0155 431.1446 431.2737 431.4028 431.5319 431.6610 431.7901 431.9191 432.0482 432.1772 432.3062 432.4352 432.5642 432.6931 432.8221 432.9510 433.0799 433.2088 433.3377 433.4666 433.5955 433.7243 433.8531 433.9820 434.1108 434.2396 434.3683 434.4971 434.6258 434.7545 434.8833 435.0120 435.1406 435.2693 435.3980 435.5266 435.6552 435.7838 435.9124 436.0410 436.1696 436.2981 436.4267 436.5552 436.6837 436.8122 436.9406 437.0691 437.1975 437.3260 437.4544 437.5828 437.7112 437.8395 437.9679 438.0962 438.2246 438.3529 438.4812 438.6095 438.7377 438.8660 438.9942 439.1224 439.2506 439.3788 439.5070 439.6352 439.7633 439.8914 440.0196 440.1477 440.2758 440.4038 440.5319 440.6599 440.7880 440.9160 441.0440 441.1719 441.2999 441.4279 441.5558 441.6837 441.8116 441.9395 442.0674 442.1953 442.3231 442.4509 442.5788 442.7066 442.8343 442.9621 443.0899 443.2176 443.3453 443.4731 443.6007 443.7284 443.8561 443.9837 444.1114 444.2390 444.3666 444.4942 444.6218 444.7493 444.8769 445.0044 445.1319 445.2594 445.3869 445.5144 445.6418 445.7693 445.8967 446.0241 446.1515 446.2789 446.4062 446.5336 446.6609 446.7883 446.9156 447.0428 447.1701 447.2974 447.4246 447.5518 447.6791 447.8063 447.9334 448.0606 448.1878 448.3149 448.4420 448.5691 448.6962 448.8233 448.9503 449.0774 449.2044 449.3314 449.4584 449.5854 449.7124 449.8393 449.9663 450.0932 450.2201 450.3470 450.4739 450.6007 450.7276 450.8544 450.9812 451.1080 451.2348 451.3616 451.4883 451.6151 451.7418 451.8685 451.9952 452.1219 452.2485 452.3752 452.5018 452.6284 452.7550 452.8816 453.0082 453.1348 453.2613 453.3878 453.5143 453.6408 453.7673 453.8938 454.0202 454.1466 454.2731 454.3995 454.5258 454.6522 454.7786 454.9049 455.0312 455.1575 455.2838 455.4101 455.5364 455.6626 455.7889 455.9151 456.0413 456.1675 456.2936 456.4198 456.5459 456.6720 456.7982 456.9242 457.0503 457.1764 457.3024 457.4285 457.5545 457.6805 457.8065 457.9324 458.0584 458.1843 458.3102 458.4361 458.5620 458.6879 458.8138 458.9396 459.0654 459.1913 459.3171 459.4428 459.5686 459.6944 459.8201 459.9458 460.0715 460.1972 460.3229 460.4485 460.5742 460.6998 460.8254 460.9510 461.0766 461.2021 461.3277 461.4532 461.5787 461.7042 461.8297 461.9552 462.0806 462.2061 462.3315 462.4569 462.5823 462.7077 462.8330 462.9584 463.0837 463.2090 463.3343 463.4596 463.5849 463.7101 463.8354 463.9606 464.0858 464.2110 464.3361 464.4613 464.5864 464.7116 464.8367 464.9618 465.0868 465.2119 465.3370 465.4620 465.5870 465.7120 465.8370 465.9619 466.0869 466.2118 466.3368 466.4617 466.5865 466.7114 466.8363 466.9611 467.0859 467.2107 467.3355 467.4603 467.5851 467.7098 467.8346 467.9593 468.0840 468.2087 468.3333 468.4580 468.5826 468.7072 468.8318 468.9564 469.0810 469.2055 469.3301 469.4546 469.5791 469.7036 469.8281 469.9525 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-707: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 708-1251: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250124T074052.8Z 9155.320055 498 1 48.78 2 40.79 238.15 104.45 244.67 0.00 1 0.00 1 0 33 2.307e-03 2.287e-03 9.278e-04 9.096e-04 4.178709e+03 2.040581e+02 3.032615e+02 3.311536e+02 4.978949e+02 293.92 -2.00 20.00 -2.00 445.39 0.00e+00 5.557742e-04 1.007868e-04 2.974452e-05 2.005257e-05 2.553317e-04 293.92 -2.00 20.00 -2.00 455.08 0.00e+00 6.880218e-04 1.044122e-05 5.292591e-05 4.709429e-05 2.642678e-05 293.92 -2.00 20.00 -2.00 435.20 0.00e+00 4.359055e+05 1.332250e+05 7.975557e+04 1.923247e+05 3.365282e+05 273.83 -2.00 10.00 -2.00 458.40 0.00e+00 2.265198e-01 2.563730e-02 1.502284e-02 7.283112e-03 7.261649e-02 225.21 -2.00 3.05 -2.00 454.47 0.00e+00 -8.309861e-06 3.261280e-06 1.501225e-06 9.527826e-07 8.833980e-06 293.92 -2.00 20.00 -2.00 455.86 0.00e+00 1.319 0.000 397.00 473.00 4 8.1122e+00 9.9696e-04 4.0589e-03 4.1499e-04 2.4427e-03 5.1954e-02 1.1327e-03 7.0830e-04 2.7256e-04 2.8834e-03 -5.0737e-03 6.5827e-04 1.1690e-04 1.9945e-04 1.6582e-03 -3.2897e-03 2.2798e-04 4.6715e-05 5.2118e-05 5.7656e-04 -1.5974e-03 1.1440e-04 3.4589e-05 1.7368e-05 2.8249e-04 4.1689e-04 -7.2876e-03 6.4840e-04 2.8457e-04 1.5559e-04 1.5060e-03 -9.6791e-05 1.0193e-05 7.9223e-07 9.3481e-07 2.5127e-05 -5.0267e-06 1.3865e-05 1.1922e-06 1.1481e-06 3.4615e-05 -8.5848e-03 1.0204e-04 7.4766e-01 9.2727e-02 1.9700e-02 1.1622e-02 2.2021e-01 12 8 8 10 0 0 97.84 24.96 0.74 -0.00858 -0.01028 13 2 1 4 0 3751.700 27.26 20.00 24.96 33.86 12.2 1005.78 6 28 -211 -123 -353 -557 -118 39 -407 -44 -153 -141 -271 -570 225 -69 278 -200 118 -182 203 -268 -61 -251 181 66 -271 -68 45 66 379 -143 -57 195 117 -6 -27 51 314 259 280 -18 -75 64 -128 167 260 271 11 104 -17 75 64 254 125 331 -50 253 367 23 66 75 237 500 290 349 385 438 329 364 199 89 225 193 -164 -24 -995 -198 -182 -35 65 60 38 231 16 407 381 191 88 322 281 237 -32 -56 -61 105 170 -188 -146 -181 -841 133 250 -46 -61 -6 -196 0 -280 -176 -423 -223 44 -282 -35 44 -271 -503 -366 -298 -329 287 -143 -27 -173 -213 -312 -271 -266 -139 -190 140 -158 -215 -273 -136 -17 -177 -94 -333 -239 -285 29 -134 78 56 -143 38 -147 -21 -187 121 -211 -49 68 -27 160 174 192 -57 82 -89 24 130 224 202 -106 -1 -219 -179 -141 67 -351 -134 -246 -164 -83 127 349 -105 83 -84 61 -12 -36 77 107 -126 228 1 -56 -250 61 565 -102 -8 181 409 27 -14 -74 108 261 49 -175 63 190 -110 -194 -88 -272 78 24 120 16 -67 110 207 114 419 51 -84 644 66 287 -48 -168 453 -274 -177 -38 -248 -109 -517 -112 -110 -14 28 161 405 441 525 352 -1384 224 9 398 117 256 154 160 -130 201 71 401 -262 -86 41 130 -10 -150 -453 -336 -42 -9 246 191 179 138 76 89 -123 134 258 215 197 216 172 43 41 25 114 203 129 118 149 333 -73 -251 -143 -144 -276 75 439 -293 -168 165 329 42 85 131 197 120 213 -193 -12 -138 -88 -96 -267 -89 -168 -166 -448 108 -56 -640 -208 73 163 -28 -188 -256 82 74 148 116 -194 312 30 -94 6 2 -186 -22 -183 -230 160 40 215 105 202 107 -55 -42 480 -237 78 -59 -572 230 -57 28 -651 -126 -264 179 56 -107 -152 -209 -149 -74 -76 172 154 -97 -186 -138 116 101 -63 -81 -307 -588 -30 -247 -248 -347 -230 50 -126 -309 -69 -188 -413 -50 -106 99 -178 -93 -446 207 -239 -9 94 -66 -379 -195 307 -34 -178 145 -389 278 -76 106 23 -242 -146 219 43 37 21 13 84 508 20 46 291 226 116 225 390 187 -78 215 -5 250 191 117 306 59 -133 234 52 302 276 208 162 267 180 435 188 152 -63 370 124 -84 185 302 -67 269 105 30 178 29 -23 134 101 116 543 58 79 -98 -41 217 319 190 36 137 -189 -116 -46 128 -191 -75 -245 155 -222 -153 -100 86 -76 -153 20 -92 85 -145 -68 -586 -18 -179 208 -14 -284 -162 -312 -46 -103 -232 -193 -333 -204 -198 -153 -129 -128 -22 -138 -345 -51 -98 -100 -151 -98 -209 -154 48 -787 -198 -31 -54 -97 -174 434 27 -72 -9 209 -34 -229 159 264 219 219 5 197 130 388 247 270 360 297 5 24 -174 -103 -295 -458 -100 34 -360 -39 -135 -123 -239 -504 199 -61 247 -178 105 -164 180 -232 -52 -206 153 56 -241 -61 40 60 339 -126 -49 161 96 -5 -24 47 288 233 256 -16 -66 57 -114 146 223 237 10 90 -15 69 58 230 113 295 -44 231 334 21 62 72 227 478 282 335 378 431 322 349 194 84 207 178 -144 -21 -857 -173 -163 -33 62 58 37 229 16 403 384 193 88 318 286 242 -32 -56 -61 107 172 -187 -142 -173 -812 130 254 -47 -64 -6 -196 0 -276 -174 -430 -222 44 -282 -35 44 -270 -501 -369 -293 -333 297 -151 -28 -182 -221 -320 -273 -262 -140 -186 135 -153 -213 -264 -132 -17 -173 -91 -322 -238 -284 29 -129 78 57 -145 38 -142 -20 -177 114 -202 -48 67 -28 159 175 194 -58 83 -90 25 131 224 205 -106 -1 -224 -171 -128 60 -309 -125 -240 -161 -82 125 335 -100 79 -81 60 -12 -35 75 104 -125 216 1 -52 -238 59 554 -101 -7 171 380 26 -13 -72 107 259 47 -166 58 168 -95 -175 -80 -260 73 23 117 16 -64 104 193 102 382 47 -77 573 60 258 -43 -141 367 -221 -139 -30 -199 -87 -403 -85 -83 -11 22 136 368 424 519 362 -1395 222 8 364 101 221 140 151 -125 199 71 398 -254 -82 38 113 -8 -127 -392 -301 -40 -8 239 183 167 131 71 84 -115 129 250 211 196 210 170 43 40 25 113 198 124 112 139 307 -68 -239 -138 -137 -257 65 375 -252 -144 149 308 39 78 122 186 115 207 -181 -11 -133 -82 -87 -241 -79 -153 -158 -429 107 -55 -632 -201 69 156 -27 -184 -251 80 70 139 110 -185 297 28 -90 6 2 -171 -21 -174 -223 154 38 201 99 192 104 -52 -41 465 -227 73 -56 -523 205 -51 26 -597 -117 -241 166 53 -102 -143 -198 -143 -72 -76 167 151 -95 -185 -133 109 95 -60 -79 -307 -587 -29 -240 -240 -336 -223 49 -123 -305 -69 -189 -420 -51 -110 104 -187 -98 -468 214 -246 -9 94 -68 -391 -202 317 -36 -184 148 -390 279 -75 106 22 -241 -146 220 44 37 22 14 89 537 21 48 303 233 122 233 403 194 -81 224 -6 265 206 129 342 66 -149 258 57 327 302 229 180 296 199 483 212 171 -71 407 139 -93 202 329 -73 298 119 34 205 33 -26 151 113 130 609 65 89 -111 -47 248 367 222 42 163 -228 -139 -54 152 -227 -90 -293 184 -266 -184 -121 105 -93 -186 25 -112 103 -176 -82 -711 -21 -213 245 -16 -337 -193 -373 -54 -120 -267 -220 -382 -237 -234 -183 -155 -152 -26 -168 -409 -61 -116 -117 -180 -113 -235 -171 53 -896 -230 -37 -62 -113 -202 500 32 -85 -10 247 -39 -267 186 307 254 253 6 227 150 451 286 311 408 343 SQ 20250124T074534.7Z 9155.323318 501 1 42.53 2 41.79 238.87 105.47 244.57 0.00 1 0.00 1 0 33 1.328e-03 1.339e-03 7.857e-04 7.627e-04 2.060866e+03 1.686586e+02 1.854948e+02 3.310452e+02 2.866696e+02 293.92 -2.00 20.00 -2.00 445.90 0.00e+00 4.752040e-04 8.520637e-05 2.906162e-05 2.020218e-05 1.467260e-04 293.92 -2.00 20.00 -2.00 455.59 0.00e+00 6.575801e-04 8.752825e-06 5.174566e-05 4.709325e-05 1.520328e-05 293.92 -2.00 20.00 -2.00 436.08 0.00e+00 3.627382e+05 1.108885e+05 7.751241e+04 1.920947e+05 1.936361e+05 273.83 -2.00 10.00 -2.00 458.76 0.00e+00 1.337275e-01 2.107459e-02 1.478387e-02 7.147423e-03 4.177837e-02 225.21 -2.00 3.05 -2.00 454.96 0.00e+00 -7.999628e-06 2.695710e-06 1.263681e-06 9.544862e-07 5.082584e-06 293.92 -2.00 20.00 -2.00 456.26 0.00e+00 1.340 0.000 397.00 473.00 4 7.3696e+00 8.4620e-04 4.0586e-03 4.1432e-04 1.4037e-03 3.8106e-02 9.6092e-04 7.1321e-04 2.7644e-04 1.6631e-03 -6.4790e-04 5.5505e-04 1.0967e-04 2.0032e-04 9.5001e-04 -3.5697e-03 1.9274e-04 4.6033e-05 5.2170e-05 3.3174e-04 -2.3552e-03 9.7264e-05 3.2564e-05 1.7933e-05 1.6254e-04 8.6944e-04 -2.6072e-03 5.5881e-04 2.6287e-04 1.5863e-04 8.5412e-04 -1.3470e-04 8.5098e-06 5.5142e-07 9.4651e-07 1.4466e-05 1.2048e-05 1.1568e-05 8.2158e-07 1.1454e-06 1.9932e-05 -6.5370e-03 8.5771e-05 2.0117e-01 7.9322e-02 1.8302e-02 1.2590e-02 1.2701e-01 12 9 1 12 17 1 99.89 24.95 0.64 -0.00654 -0.01052 20 5 1 4 0 2023.650 27.26 19.99 24.95 33.91 12.2 1006.46 -136 -19 -19 -81 -195 -355 -130 -111 0 -195 82 -269 30 23 6 -43 28 -34 -47 -151 5 -79 -210 -98 102 -180 74 -91 -48 77 201 -33 -129 20 74 -46 -134 69 17 129 -101 67 13 -104 44 194 211 108 134 -138 73 -6 117 214 59 0 0 303 83 255 60 139 150 396 280 105 183 257 301 76 81 57 14 -27 63 14 75 -167 -104 -94 213 115 29 308 198 159 26 62 134 -6 220 23 77 139 -105 175 -130 -72 -218 3 320 109 53 -21 138 263 118 -52 -183 -99 -171 -201 61 -288 -15 -71 -312 -135 -245 -64 -97 13 -277 -191 -24 -45 -193 -148 -172 -199 -252 -164 -282 -123 -126 58 17 -190 -9 -220 -125 -135 3 -56 -89 71 -82 -39 -152 -236 -203 -47 -49 42 -4 -3 3 -111 33 -12 -133 -43 13 -38 128 39 20 -123 -201 -132 -56 59 32 -34 -90 -208 -38 46 116 -65 -85 -15 22 -39 100 73 116 -50 15 -50 38 -67 -71 -1 63 -148 62 148 -2 198 -17 9 27 89 -20 33 101 210 46 -15 -33 103 77 105 88 87 123 -43 187 130 25 37 118 -8 1 102 -105 104 -163 -118 -121 -76 -292 -156 -159 -187 7 -15 -40 109 214 226 156 311 153 244 36 240 101 18 -48 -91 84 148 181 -60 24 83 -15 -47 -98 -137 -208 -118 17 109 34 63 118 2 -29 100 61 252 167 57 196 78 305 77 26 24 227 56 142 208 151 -19 -206 15 -81 -185 -227 -31 77 -91 75 131 208 -25 -47 -22 115 -72 47 -61 -173 -102 -244 -34 -87 27 -125 -97 -37 -59 -102 64 25 -36 -187 -26 -52 -44 143 -24 67 23 -33 183 66 -13 -37 -72 -10 -99 -76 13 27 -74 -35 -120 48 -61 -69 -20 -33 -14 -51 -76 9 -169 -98 11 -85 -101 52 -216 -121 66 -156 -38 16 -166 17 -138 -88 30 -4 -202 -169 -140 -168 -262 -233 -89 -28 -229 -36 -253 -63 -164 -222 -226 -87 -216 -131 -3 4 -82 -177 -83 -31 15 31 -150 -56 -69 -2 89 -20 -127 26 -53 76 34 56 -28 -4 36 55 40 253 164 70 166 241 55 160 37 88 91 202 227 141 108 -26 184 164 105 144 218 87 76 38 88 159 242 104 87 274 70 382 28 170 193 273 36 145 -4 141 106 2 235 166 60 5 62 31 -9 97 142 152 -64 46 148 60 136 53 -117 64 -87 13 87 2 7 -138 4 -9 20 -118 -84 -66 -190 -109 -72 50 -135 -38 -54 -102 -38 -152 -24 -97 -55 -144 -147 -90 -215 -170 -80 -242 -133 -93 -117 -38 -257 -107 -158 -228 -217 -183 -99 -139 -259 -217 -131 7 -200 -75 -24 26 -178 32 131 8 27 -60 -8 -23 57 55 116 142 203 192 35 47 355 239 193 377 316 -113 -16 -15 -63 -150 -280 -106 -93 0 -166 69 -227 26 19 5 -37 24 -29 -40 -131 4 -65 -177 -79 81 -149 65 -78 -42 68 174 -28 -105 16 57 -37 -116 62 16 114 -88 56 11 -88 37 161 182 91 112 -120 62 -5 101 183 50 0 0 266 73 231 54 126 136 358 258 100 178 250 291 72 75 55 13 -24 53 12 63 -144 -90 -87 205 113 27 289 190 157 27 62 133 -6 213 22 75 136 -103 169 -125 -68 -215 3 310 108 52 -21 143 269 116 -49 -182 -93 -166 -199 61 -286 -15 -68 -297 -127 -235 -63 -98 13 -291 -202 -26 -47 -197 -149 -168 -191 -236 -151 -262 -116 -121 56 17 -184 -9 -212 -119 -129 3 -54 -89 73 -83 -39 -146 -219 -185 -43 -45 40 -3 -3 3 -110 33 -12 -133 -42 13 -38 128 39 19 -121 -206 -126 -48 52 29 -30 -88 -200 -36 45 111 -61 -80 -15 22 -40 97 70 111 -50 15 -46 36 -64 -69 -1 63 -144 59 138 -2 191 -16 9 26 84 -19 29 86 175 40 -14 -32 95 71 97 80 83 118 -41 169 115 22 33 106 -7 1 88 -85 83 -123 -86 -90 -57 -218 -114 -113 -132 5 -12 -33 100 204 231 156 312 147 231 31 209 88 15 -45 -90 81 144 175 -60 23 72 -13 -38 -80 -120 -185 -111 17 103 32 61 112 2 -27 97 57 238 160 55 193 78 306 77 25 23 216 53 132 200 144 -18 -191 14 -75 -172 -195 -25 63 -78 68 123 186 -22 -43 -20 108 -69 45 -58 -163 -93 -217 -30 -76 24 -116 -94 -35 -57 -96 62 24 -35 -179 -26 -51 -42 136 -23 64 22 -32 175 63 -12 -34 -66 -9 -95 -73 13 26 -70 -33 -115 47 -59 -68 -19 -32 -13 -46 -67 8 -155 -86 10 -76 -92 49 -206 -115 63 -148 -36 16 -165 18 -141 -89 30 -4 -191 -158 -134 -165 -263 -233 -88 -27 -222 -35 -246 -61 -161 -220 -226 -88 -220 -135 -3 5 -87 -187 -87 -33 16 31 -152 -59 -73 -2 94 -21 -135 27 -54 75 33 56 -27 -4 36 56 41 261 174 72 173 252 57 175 40 95 96 211 236 147 113 -27 194 175 113 159 245 98 85 42 97 173 266 116 97 306 78 427 31 193 218 322 41 164 -5 158 119 3 272 195 70 6 73 36 -11 112 164 176 -74 53 173 70 161 63 -143 79 -107 16 106 2 9 -170 5 -11 24 -146 -105 -83 -238 -136 -90 62 -169 -48 -67 -127 -47 -187 -29 -118 -67 -177 -181 -111 -260 -202 -95 -286 -160 -114 -144 -47 -317 -132 -197 -290 -278 -234 -124 -171 -309 -252 -150 8 -234 -90 -29 33 -224 40 163 10 33 -73 -10 -28 67 65 138 168 238 224 41 56 420 282 226 462 380