File name: Pandora77s1_Singapore-NUS_20250502_L2Fit_fout2c3d20230113p1-8.txt File generation date: 20250509T125730.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Santo V. Salinas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 77 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora77_OF_v2d20220405.txt Instrument calibration file used: Pandora77s1_CF_v3d20230113.txt Level 1 file used: Pandora77s1_Singapore-NUS_20250502_L1_smca1c3d20230113p1-8.txt Full location name: Centre for Remote Imaging Sensing and Processing (CRISP), National University of Short location name: Singapore-NUS Country of location: Singapore Location latitude [deg]: 1.2990 Location longitude [deg]: 103.7710 Location altitude [m]: 77 Local noon date: 20250502 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0008 305.1420 305.2832 305.4244 305.5656 305.7068 305.8480 305.9891 306.1303 306.2714 306.4126 306.5537 306.6948 306.8359 306.9770 307.1181 307.2591 307.4002 307.5412 307.6822 307.8233 307.9643 308.1053 308.2463 308.3872 308.5282 308.6691 308.8101 308.9510 309.0919 309.2328 309.3737 309.5146 309.6555 309.7964 309.9372 310.0780 310.2189 310.3597 310.5005 310.6413 310.7821 310.9228 311.0636 311.2043 311.3451 311.4858 311.6265 311.7672 311.9079 312.0486 312.1893 312.3299 312.4706 312.6112 312.7518 312.8924 313.0331 313.1736 313.3142 313.4548 313.5953 313.7359 313.8764 314.0169 314.1574 314.2979 314.4384 314.5789 314.7194 314.8598 315.0003 315.1407 315.2811 315.4215 315.5619 315.7023 315.8427 315.9830 316.1234 316.2637 316.4040 316.5444 316.6847 316.8250 316.9652 317.1055 317.2458 317.3860 317.5262 317.6665 317.8067 317.9469 318.0871 318.2272 318.3674 318.5076 318.6477 318.7878 318.9279 319.0680 319.2081 319.3482 319.4883 319.6284 319.7684 319.9084 320.0485 320.1885 320.3285 320.4685 320.6085 320.7484 320.8884 321.0283 321.1683 321.3082 321.4481 321.5880 321.7279 321.8678 322.0076 322.1475 322.2873 322.4271 322.5670 322.7068 322.8466 322.9863 323.1261 323.2659 323.4056 323.5454 323.6851 323.8248 323.9645 324.1042 324.2439 324.3835 324.5232 324.6628 324.8025 324.9421 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250501T233613.1Z 9252.983485 44 1 51.45 2 81.40 74.63 134.52 47.56 0.00 1 0.00 1 0 17 3.540e-01 1.940e-02 2.725e-01 1.204e-02 6.215100e-01 6.585366e-03 7.147475e-03 -6.000000e+00 2.044363e-01 227.53 -2.00 3.05 -2.00 321.52 0.00e+00 3.732778e-03 3.309917e-03 7.924946e-03 -6.000000e+00 9.482434e-03 294.35 -2.00 20.00 -2.00 320.83 0.00e+00 6.299 0.000 302.00 328.00 3 2.5253e+00 2.4429e-02 8.0326e-02 -6.0000e+00 5.0545e-01 4.6388e-01 3.2081e-02 6.4651e-02 -6.0000e+00 5.4747e-01 -6.3438e-01 2.5242e-02 2.2360e-02 -6.0000e+00 3.2852e-01 2.5428e-01 1.2049e-02 4.9642e-03 -6.0000e+00 1.4158e-01 4.7434e-05 -1.0372e-03 3.6257e-04 9.6062e-05 -6.0000e+00 9.8557e-03 -7.2568e-03 4.0997e-05 12 9 8 11 16 0 92.15 25.17 0.43 -0.00726 -0.01505 25 5 1 5 0 2057.910 27.45 20.00 25.17 33.24 13.3 1001.27 900000 -24715 -116832 -92636 -145905 -122364 -35638 -58155 -115784 25538 -123409 -111481 -68906 -55278 -60554 28869 34522 26364 27679 -28914 -35144 12614 -3076 881 46645 -16697 -40672 -53906 -32493 133858 88935 -4902 21433 24969 -3944 16897 -12579 -9063 37848 36779 9477 11604 13391 20393 32256 -11436 32153 14596 17091 23515 1347 28326 24566 8080 18972 27672 5724 10715 12340 14095 5245 -763 2912 6915 13458 966 15169 3180 3624 3676 6904 2342 3015 6632 3320 -3490 1126 -8307 -9053 -4511 -2694 -3682 -1512 830 2720 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-2460 945 SS 20250501T234817.7Z 9252.991871 49 1 50.33 2 78.49 74.56 132.38 49.41 0.00 1 0.00 1 0 17 2.194e-01 7.864e-03 9.004e-02 1.799e-03 5.135230e-01 9.459911e-04 5.335828e-03 -6.000000e+00 1.267253e-01 227.53 -2.00 3.05 -2.00 320.18 0.00e+00 1.801089e-03 3.458278e-04 1.590758e-03 -6.000000e+00 5.982104e-03 294.35 -2.00 20.00 -2.00 319.35 0.00e+00 4.843 0.000 302.00 328.00 3 1.9831e+00 2.8942e-03 5.3102e-02 -6.0000e+00 3.1321e-01 -1.6898e-02 3.6246e-03 2.4978e-02 -6.0000e+00 3.3929e-01 -1.9937e-02 3.0915e-03 1.2208e-02 -6.0000e+00 2.0359e-01 -7.3350e-04 1.5819e-03 3.3447e-03 -6.0000e+00 8.7860e-02 3.8402e-04 -4.6896e-04 5.2265e-05 4.6483e-05 -6.0000e+00 6.2066e-03 -7.0369e-03 1.6349e-07 11 8 0 10 0 0 45.34 25.17 0.47 -0.00704 -0.01056 103 19 1 5 0 488.630 27.45 19.99 25.17 34.29 13.3 1008.73 900000 -57913 -23560 -82731 900000 -80080 -67190 127936 -35953 -85833 -48131 -71424 -55887 -69216 30416 5675 6884 -18157 196 1273 12834 9215 -750 -8770 -6353 -12228 -1921 -11072 -4945 518 -3170 2652 -4469 670 -10912 -2136 -9794 -4104 -2736 -2309 5443 -824 540 -215 -242 486 3215 -1036 -793 -1416 -2084 -244 2553 2808 2474 3339 501 58 609 -394 540 315 2610 2620 3722 374 -418 -1202 1225 1309 2062 1109 2098 141 -554 -309 -2159 -4028 -1952 -2141 -1409 -1742 -2697 -1676 -310 -57 615 982 1095 1451 1017 320 -577 -639 -47 -508 442 702 277 -100 -815 -1265 -1202 -1062 -1214 -1116 -617 -572 84 1049 955 864 262 487 -257 15 -601 95 -109 237 26 247 583 353 249 -55 -44 255 69 -201 -252 -344 -270 -94 -160 213 330 435 261 -144 -236 -212 -352 900000 -609 -195 -1266 900000 -1047 -803 245 -407 -1779 -721 -1435 -1131 -1997 443 127 174 -646 6 43 407 307 -28 -386 -297 -650 -96 -596 -241 24 -172 159 -331 52 -947 -164 -862 -397 -318 -325 816 -143 98 -41 -47 95 618 -211 -165 -310 -498 -64 710 844 797 1012 162 19 196 -126 191 110 996 1117 1669 170 -185 -535 568 693 1216 703 1330 88 -324 -163 -1061 -1961 -993 -1261 -960 -1244 -2145 -1406 -274 -50 566 936 1054 1357 971 286 -490 -538 -42 -484 477 800 347 -128 -997 -1531 -1339 -1176 -1443 -1313 -761 -751 118 1500 1496 1429 436 778 -388 21 -861 141 -171 394 43 407 928 545 368 -78 -66 382 106 -343 -439 -637 -521 -180 -326 432 688 926 561 -302 -499 -426 -691 SS 20250501T235401.6Z 9252.995852 52 1 50.34 2 77.11 74.51 131.34 50.22 0.00 1 0.00 1 0 17 1.226e-01 7.169e-03 2.078e-02 1.214e-03 4.682276e-01 6.258438e-04 4.826222e-03 -6.000000e+00 7.078577e-02 227.53 -2.00 3.05 -2.00 319.66 0.00e+00 1.560359e-03 1.919317e-04 1.069021e-03 -6.000000e+00 3.283964e-03 294.35 -2.00 20.00 -2.00 318.78 0.00e+00 4.362 0.000 302.00 328.00 3 1.7789e+00 1.8264e-03 4.7744e-02 -6.0000e+00 1.7501e-01 -1.4339e-02 2.2098e-03 2.1945e-02 -6.0000e+00 1.8957e-01 -2.7679e-02 1.7402e-03 1.0788e-02 -6.0000e+00 1.1375e-01 4.9123e-03 9.1035e-04 3.0347e-03 -6.0000e+00 4.9019e-02 7.7439e-04 -4.3048e-04 3.5297e-05 3.6509e-05 -6.0000e+00 3.4135e-03 -7.1954e-03 1.1143e-06 11 8 0 10 0 0 78.66 25.16 0.36 -0.00720 -0.01043 158 30 1 5 0 318.580 27.45 20.00 25.16 34.99 13.3 1012.56 900000 -40837 -15471 -57624 -2208 -62436 -51929 -10078 -33770 -46561 -29396 -40267 -33124 -30498 -8029 -6492 118 -8729 -4774 -1091 3183 4127 -2812 -5014 -1136 -3882 -3967 -2774 -1397 -3499 -3949 -417 -119 -880 -4640 -3212 -7432 -3183 -2539 -688 1570 424 492 489 1046 678 703 -986 -208 -968 63 901 1100 1648 1843 1606 702 430 40 173 801 1399 2346 2249 2966 869 -3 -390 985 1187 1406 1402 1195 483 141 -868 -1804 -2995 -2519 -2237 -1656 -1849 -2450 -1469 -742 -355 328 779 1076 1035 844 213 -445 -371 -296 -349 276 628 219 -333 -683 -1062 -826 -679 -1085 -994 -777 -315 113 1072 822 770 416 233 -290 8 -252 254 1 -28 -40 300 522 420 274 -230 24 416 112 -220 -142 -77 -267 42 -126 131 278 341 151 -69 -279 -390 -346 900000 -690 -223 -1284 -26 -1263 -978 -154 -680 -1295 -720 -1154 -1024 -1127 -290 -274 5 -461 -262 -61 178 231 -172 -336 -79 -297 -314 -213 -101 -260 -324 -38 -12 -101 -546 -359 -916 -435 -419 -135 345 102 125 128 276 182 191 -274 -58 -257 18 279 371 596 707 642 293 182 17 71 333 621 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