File name: Pandora170s1_StGeorge_20230508_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20240411T104119.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20230508_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20230508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20230508T185843.1Z 8528.790777 10 1 51.28 2 34.48 228.05 160.10 317.23 0.00 1 0.00 1 0 17 1.236e-02 9.239e-03 1.433e-04 1.008e-04 1.816820e-01 5.196365e-05 2.216761e-03 -6.000000e+00 7.130256e-03 230.28 -2.00 3.57 -2.00 314.83 0.00e+00 4.755178e-04 4.282107e-06 3.435667e-05 -6.000000e+00 3.096988e-04 280.19 -2.00 20.00 -2.00 314.28 0.00e+00 1.212 0.000 302.00 328.00 3 -1.3697e-01 1.3370e-04 1.5297e-02 -6.0000e+00 1.7837e-02 1.0090e-02 1.4848e-04 9.4727e-03 -6.0000e+00 1.9356e-02 -4.0426e-03 8.4790e-05 4.6114e-03 -6.0000e+00 1.1491e-02 -2.6458e-03 3.6774e-05 1.2884e-03 -6.0000e+00 4.8128e-03 1.5320e-01 5.8627e-05 2.8408e-06 1.6728e-05 -6.0000e+00 3.3644e-04 4.2618e-03 0.0000e+00 11 8 0 10 0 0 82.19 22.87 0.24 0.00426 0.00470 3240 650 1 5 0 15.230 26.73 20.00 22.87 28.64 5.4 1080.27 1944 675 913 -2395 -3687 -2406 -1118 1292 1303 -800 -3526 -2480 -864 -295 1197 614 -124 913 868 1864 1080 57 1259 1410 1384 1665 688 -658 -647 -303 1082 1100 2749 -844 -4278 -3490 -3632 -2093 -452 -446 -988 -622 -349 -649 93 343 -454 -206 -1020 -439 871 775 983 1299 660 1224 1139 366 148 91 506 1390 1905 2443 421 -707 -888 -1695 690 1045 408 931 548 1156 499 -311 -919 -2098 -796 -1107 -1364 -1344 -2720 -1944 -970 -611 60 476 976 666 655 182 -800 -75 1 -226 394 1212 521 -179 -316 -1507 -935 68 -961 -1468 -793 -1069 -220 573 836 618 572 256 -59 29 145 -93 633 279 62 362 778 405 993 225 -233 1117 417 306 147 -607 -414 -10 89 -243 37 538 73 -156 -13 -895 -766 639 244 333 -846 -1259 -755 -357 451 468 -306 -1360 -944 -350 -125 560 292 -61 457 447 977 581 31 672 782 760 940 388 -375 -342 -153 552 598 1566 -477 -2499 -1951 -2048 -1354 -307 -333 -768 -503 -288 -539 76 280 -363 -166 -801 -339 689 621 828 1134 567 1063 1004 323 129 79 449 1306 1836 2461 410 -667 -797 -1541 620 1006 414 979 579 1175 498 -294 -821 -1779 -687 -1017 -1343 -1387 -2899 -2153 -1093 -736 73 596 1215 802 759 199 -833 -78 1 -247 454 1463 667 -227 -389 -1728 -1065 80 -1188 -1861 -1005 -1412 -291 793 1162 862 788 338 -74 36 176 -114 831 379 83 483 1042 521 1251 281 -277 1312 522 393 190 -802 -553 -14 126 -349 55 780 107 -232 -19 -1296 -1091 SU 20230508T190140.0Z 8528.792824 13 1 50.31 2 34.88 229.07 160.44 318.75 0.00 1 0.00 1 0 17 1.236e-02 9.211e-03 2.009e-04 1.392e-04 1.831017e-01 7.192952e-05 2.234227e-03 -6.000000e+00 7.132592e-03 230.28 -2.00 3.57 -2.00 314.88 0.00e+00 4.911426e-04 5.965968e-06 3.341841e-05 -6.000000e+00 3.097719e-04 280.19 -2.00 20.00 -2.00 314.32 0.00e+00 1.218 0.000 302.00 328.00 3 5.0067e-01 1.8527e-04 1.5397e-02 -6.0000e+00 1.7843e-02 1.1232e-02 2.0585e-04 9.5549e-03 -6.0000e+00 1.9361e-02 -4.1559e-03 1.1752e-04 4.6534e-03 -6.0000e+00 1.1494e-02 -2.7055e-03 5.1091e-05 1.3057e-03 -6.0000e+00 4.8148e-03 8.0243e-02 1.6395e-04 3.9161e-06 1.6815e-05 -6.0000e+00 3.3651e-04 3.5522e-03 0.0000e+00 11 8 0 10 0 0 99.65 22.89 0.24 0.00355 0.00478 1817 364 1 5 0 27.310 26.83 20.00 22.89 28.87 5.3 1080.81 1946 660 942 -2335 -3662 -2321 -1131 1318 1265 -741 -3635 -2523 -872 -343 1124 579 -102 958 891 1852 1088 94 1289 1350 1334 1695 583 -652 -655 -286 1092 1083 2744 -828 -4259 -3605 -3573 -2096 -431 -441 -1011 -653 -391 -671 88 373 -461 -217 -1017 -443 882 768 1035 1325 661 1280 1135 390 149 83 539 1381 1912 2424 419 -708 -874 -1678 695 1057 454 917 566 1187 507 -318 -922 -2099 -790 -1115 -1347 -1312 -2709 -1933 -927 -613 81 478 970 664 670 186 -823 -86 -17 -205 419 1261 562 -173 -299 -1512 -950 75 -937 -1456 -770 -1048 -236 576 832 616 563 223 -64 37 149 -97 618 269 35 337 763 374 977 190 -237 1111 436 298 145 -605 -403 -30 107 -230 45 544 58 -145 -21 -922 -779 618 230 332 -796 -1209 -703 -349 444 440 -274 -1357 -929 -342 -141 510 285 -49 464 444 942 568 49 668 727 756 929 339 -361 -336 -149 577 573 1520 -483 -2419 -1962 -2081 -1319 -301 -337 -804 -539 -314 -543 74 311 -377 -170 -778 -351 680 630 848 1128 580 1135 1022 352 132 74 488 1266 1878 2382 415 -680 -801 -1488 638 1038 468 942 583 1228 494 -294 -804 -1824 -698 -1048 -1354 -1379 -2938 -2179 -1061 -721 101 584 1180 811 789 207 -874 -87 -18 -228 491 1544 703 -214 -360 -1763 -1101 86 -1132 -1804 -989 -1353 -315 779 1170 870 786 298 -81 44 184 -121 793 358 48 456 999 489 1249 232 -287 1328 535 389 191 -811 -546 -41 148 -336 65 797 86 -211 -31 -1307 -1086 SU 20230508T190426.4Z 8528.794750 16 1 50.63 2 35.26 230.01 160.75 320.23 0.00 1 0.00 1 0 17 1.232e-02 9.205e-03 1.798e-04 1.265e-04 1.833521e-01 6.541249e-05 2.234824e-03 -6.000000e+00 7.112682e-03 230.28 -2.00 3.57 -2.00 314.82 0.00e+00 4.657882e-04 5.348681e-06 3.330982e-05 -6.000000e+00 3.089082e-04 280.19 -2.00 20.00 -2.00 314.26 0.00e+00 1.224 0.000 302.00 328.00 3 3.1884e-01 1.6826e-04 1.5440e-02 -6.0000e+00 1.7793e-02 9.6148e-03 1.8689e-04 9.5567e-03 -6.0000e+00 1.9307e-02 -3.6971e-03 1.0677e-04 4.6553e-03 -6.0000e+00 1.1462e-02 -2.7511e-03 4.6230e-05 1.3020e-03 -6.0000e+00 4.8014e-03 9.5731e-02 1.4525e-04 3.5620e-06 1.6888e-05 -6.0000e+00 3.3557e-04 3.5759e-03 0.0000e+00 11 8 0 10 0 0 99.46 22.90 0.23 0.00358 0.00467 1846 370 1 5 0 26.880 26.83 20.00 22.90 28.88 5.3 1079.62 1880 657 826 -2324 -3726 -2318 -1127 1343 1223 -719 -3516 -2467 -811 -329 1200 539 -158 939 851 1845 1078 46 1235 1395 1364 1713 653 -659 -652 -240 1105 1107 2741 -845 -4292 -3545 -3584 -2125 -439 -455 -1022 -637 -379 -696 64 335 -487 -197 -1048 -453 849 739 988 1324 648 1226 1166 384 168 99 557 1393 1900 2456 410 -697 -876 -1664 697 1054 411 912 536 1181 519 -311 -912 -2098 -769 -1114 -1328 -1332 -2712 -1946 -975 -636 95 485 992 677 654 197 -813 -81 -8 -221 380 1217 556 -174 -298 -1507 -953 61 -934 -1450 -743 -1044 -206 577 842 609 567 252 -58 37 137 -100 637 273 38 346 780 382 999 223 -253 1112 442 307 131 -572 -406 -17 82 -260 37 539 74 -151 -11 -933 -747 624 240 305 -829 -1196 -735 -364 440 445 -278 -1373 -951 -333 -141 534 261 -79 477 445 983 555 24 671 741 762 984 375 -360 -351 -123 574 614 1500 -487 -2408 -1905 -2062 -1326 -305 -347 -812 -526 -305 -565 54 279 -398 -155 -802 -358 654 606 813 1130 570 1091 1053 347 150 88 507 1283 1799 2430 410 -674 -805 -1482 642 1042 428 946 559 1232 509 -288 -799 -1826 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