File name: Pandora170s1_StGeorge_20230609_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20240414T123532.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20230609_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20230609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230609T142925.9Z 8560.603772 315 1 48.33 2 40.07 107.31 80.65 237.89 0.00 1 0.00 1 0 17 1.345e-02 9.511e-03 6.303e-04 3.486e-04 2.171086e-01 1.799928e-04 2.604297e-03 -6.000000e+00 7.830162e-03 232.51 -2.00 3.57 -2.00 315.80 0.00e+00 6.032724e-04 1.804613e-05 8.463154e-05 -6.000000e+00 3.419142e-04 283.57 -2.00 20.00 -2.00 315.11 0.00e+00 1.305 0.000 302.00 328.00 3 2.0681e+00 4.6998e-04 1.7319e-02 -6.0000e+00 1.9674e-02 7.4842e-04 5.2317e-04 1.1372e-02 -6.0000e+00 2.1296e-02 -6.4477e-03 2.9937e-04 5.5051e-03 -6.0000e+00 1.2645e-02 -3.9465e-03 1.3438e-04 1.5274e-03 -6.0000e+00 5.2919e-03 1.4405e-02 3.1141e-04 9.9392e-06 1.8009e-05 -6.0000e+00 3.6642e-04 3.5852e-04 0.0000e+00 12 8 8 10 0 0 99.99 23.00 0.23 0.00036 0.00270 587 118 1 5 0 82.310 26.94 20.00 23.00 19.35 5.1 996.47 2161 1136 875 -1959 -3881 -2685 -1505 1335 1326 -1093 -3752 -3183 -1129 -546 1339 568 -11 1019 608 1957 1128 131 1105 1372 1292 1839 374 -940 -1093 -1040 638 1003 2944 -908 -4323 -4250 -4138 -2252 -459 -446 -945 -412 -386 -553 126 440 -369 -137 -1095 -570 724 810 1037 1203 658 1267 1111 361 68 -71 429 1452 2075 2739 737 -532 -1197 -1940 607 1295 654 1036 711 1237 648 -366 -1197 -2537 -1058 -1270 -1335 -1392 -2734 -2002 -1011 -459 351 729 1140 946 785 121 -1067 -373 -256 -340 316 1214 814 39 -418 -1857 -1169 -47 -928 -1392 -847 -1124 -255 689 930 732 618 145 -217 -159 -23 -108 697 400 197 407 757 423 1008 90 -585 887 442 398 93 -704 -552 -7 124 -162 96 569 191 1 -18 -983 -740 462 269 212 -460 -896 -572 -328 316 323 -286 -995 -844 -320 -176 478 207 -4 395 245 803 476 55 467 603 600 878 168 -432 -468 -430 268 453 1399 -428 -2131 -2022 -1966 -1225 -276 -292 -679 -309 -280 -405 91 336 -277 -100 -780 -402 525 627 799 967 546 1065 950 309 58 -60 369 1254 1927 2537 693 -492 -1017 -1690 519 1238 654 1078 743 1241 611 -330 -1032 -2089 -889 -1132 -1268 -1452 -2931 -2235 -1139 -551 424 905 1408 1129 909 134 -1140 -382 -275 -382 373 1494 1063 50 -509 -2203 -1379 -55 -1122 -1793 -1133 -1505 -355 967 1363 1081 875 199 -285 -197 -29 -138 917 563 274 582 1048 564 1323 114 -735 1102 560 540 126 -985 -785 -10 186 -246 149 898 303 1 -27 -1500 -1108 SS 20230609T143500.6Z 8560.607646 318 1 6.41 2 39.11 108.65 81.47 238.92 0.00 1 0.00 1 0 17 1.633e-02 1.041e-02 7.561e-03 4.215e-03 2.192815e-01 2.177684e-03 2.623872e-03 -6.000000e+00 9.508777e-03 232.51 -2.00 3.57 -2.00 315.74 0.00e+00 5.266475e-04 2.160879e-04 5.456208e-05 -6.000000e+00 4.151656e-04 283.57 -2.00 20.00 -2.00 315.06 0.00e+00 1.288 0.000 302.00 328.00 3 4.5890e+00 5.6794e-03 1.7276e-02 -6.0000e+00 2.3892e-02 1.9557e-02 6.3191e-03 1.1485e-02 -6.0000e+00 2.5860e-02 -5.3860e-03 3.6140e-03 5.5610e-03 -6.0000e+00 1.5355e-02 -3.0270e-03 1.6225e-03 1.5409e-03 -6.0000e+00 6.4270e-03 1.1612e-03 2.8133e-04 1.1953e-04 1.8278e-05 -6.0000e+00 4.4491e-04 -4.8166e-04 0.0000e+00 12 9 9 12 1 1 999.00 23.00 0.48 -0.00048 0.00163 2 5 1 5 0 2077.510 26.94 19.99 23.00 19.98 5.1 999.25 3984 -2480 2 892 -3482 -1052 1102 3173 2697 -1889 -6806 -4484 3000 458 2277 844 -796 -1901 -430 2791 347 1816 3064 597 1713 1760 1684 394 -833 -988 -103 661 4699 -1002 -3700 -4647 -3565 -2319 -2111 -1792 -282 -653 -1703 136 -216 214 -375 -298 -1933 -1382 1476 1084 1351 857 1459 833 1566 334 73 -677 237 1642 1330 2786 892 -247 -2642 -1555 544 1132 657 1015 1498 846 702 0 -1310 -1870 -1183 -1750 -649 -1026 -2199 -2250 -452 -545 500 1195 823 897 879 6 -862 -324 -244 -30 246 1082 1334 -88 -136 -1785 -1567 -205 -250 -1045 -1037 -1624 -229 880 359 842 539 225 -443 -138 -706 22 1090 235 -50 123 802 133 1396 390 -1183 682 769 -139 134 -572 -893 -345 434 146 114 208 501 325 -177 -879 -552 874 -622 0 212 -782 -219 232 725 678 -513 -1910 -1242 843 146 790 317 -312 -768 -177 1149 148 763 1284 264 782 825 786 178 -361 -418 -44 300 2185 -493 -1787 -2203 -1766 -1269 -1307 -1223 -202 -484 -1292 103 -163 161 -279 -218 -1400 -995 1073 825 1063 696 1203 698 1320 283 62 -569 202 1448 1233 2651 856 -228 -2339 -1339 480 1072 659 1043 1536 854 681 0 -1132 -1561 -1007 -1600 -632 -1060 -2375 -2502 -517 -650 612 1485 1025 1094 1027 6 -909 -334 -258 -34 292 1349 1716 -113 -169 -2127 -1819 -241 -308 -1338 -1361 -2188 -314 1243 522 1223 767 307 -578 -174 -888 29 1453 327 -71 173 1104 179 1818 497 -1474 843 983 -185 184 -793 -1252 -493 638 221 176 324 781 501 -269 -1312 -815 SS 20230609T160237.2Z 8560.668486 371 1 49.94 2 25.75 137.56 95.22 254.13 0.00 1 0.00 1 0 17 1.416e-02 9.947e-03 2.962e-03 1.619e-03 1.920375e-01 8.349553e-04 2.305123e-03 -6.000000e+00 8.247496e-03 232.51 -2.00 3.57 -2.00 315.83 0.00e+00 4.112149e-04 8.432320e-05 9.113562e-05 -6.000000e+00 3.600813e-04 283.58 -2.00 20.00 -2.00 315.14 0.00e+00 1.110 0.000 302.00 328.00 3 5.1160e+00 2.1810e-03 1.5010e-02 -6.0000e+00 2.0723e-02 2.9889e-02 2.4269e-03 1.0053e-02 -6.0000e+00 2.2430e-02 -2.4900e-03 1.3888e-03 4.8715e-03 -6.0000e+00 1.3318e-02 -5.4891e-03 6.2506e-04 1.3340e-03 -6.0000e+00 5.5748e-03 8.5434e-04 2.0123e-04 4.6175e-05 1.6067e-05 -6.0000e+00 3.8586e-04 -8.7386e-04 0.0000e+00 12 8 8 10 0 0 100.00 22.99 0.68 -0.00087 0.00064 73 15 1 5 0 684.020 26.94 20.00 22.99 21.59 5.0 998.62 3766 27 1091 -584 -1922 -2858 646 3110 1226 1257 -2875 -3524 68 -102 1094 499 -526 635 -1030 2827 1248 506 1181 1776 1161 1677 985 -1483 -544 -1250 1235 907 2604 -1718 -4752 -4160 -4516 -2171 -2417 -684 -1197 -791 -995 -370 -391 -5 -224 -670 -1763 -474 471 748 1174 1643 1075 1494 1274 1087 -167 80 253 1558 1579 2976 871 -523 -1055 -1874 648 1161 698 1458 877 1329 802 -139 -1177 -2714 -1549 -1435 -937 -1437 -2486 -1885 -862 -915 288 1039 1587 1050 889 -149 -1255 -484 -400 -294 509 1220 913 24 -474 -1774 -1303 -149 -1042 -1322 -718 -1148 -6 840 832 410 517 -259 -170 125 -321 -196 777 424 149 456 426 263 633 -31 -693 980 564 161 36 -724 -443 -45 145 -208 272 666 269 182 69 -943 -797 816 7 269 -141 -416 -594 133 685 306 328 -770 -947 19 -31 377 183 -202 246 -418 1138 520 211 490 763 517 768 450 -667 -225 -508 502 387 1166 -819 -2199 -1842 -2142 -1147 -1470 -463 -857 -589 -760 -283 -297 -4 -165 -486 -1249 -334 335 564 912 1323 876 1233 1069 909 -139 66 214 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