File name: Pandora170s1_StGeorge_20230610_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20240414T140951.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20230610_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20230610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230610T112045.3Z 8561.472747 192 1 50.24 2 73.70 73.51 53.99 182.20 0.00 1 0.00 1 0 17 3.788e-01 9.228e-03 1.486e-01 2.544e-03 5.437541e-01 1.389274e-03 6.180513e-03 -6.000000e+00 2.281935e-01 232.57 -2.00 3.57 -2.00 320.17 0.00e+00 1.215629e-03 4.949647e-04 6.539908e-04 -6.000000e+00 1.190267e-02 283.66 -2.00 20.00 -2.00 319.51 0.00e+00 3.504 0.001 302.00 328.00 3 3.2624e+00 4.1636e-03 4.5405e-02 -6.0000e+00 5.7989e-01 -8.2571e-02 5.2259e-03 2.9423e-02 -6.0000e+00 6.3351e-01 1.1032e-01 4.9555e-03 1.4986e-02 -6.0000e+00 3.6178e-01 -5.7041e-02 2.5161e-03 4.7981e-03 -6.0000e+00 1.5755e-01 3.4484e-04 2.2499e-04 7.4414e-05 4.8800e-05 -6.0000e+00 1.1198e-02 1.1043e-03 0.0000e+00 11 8 0 10 0 0 99.96 23.06 0.69 0.00110 0.00279 56 11 1 5 0 896.990 26.94 20.00 23.06 21.07 5.0 988.87 900000 900000 900000 900000 900000 228240 900000 900000 900000 900000 900000 43755 900000 900000 210314 135431 83022 94996 7165 126781 51041 110803 80935 46086 31275 27824 40013 -3818 30460 3749 18768 -9276 11754 397 -2956 2348 -1288 6528 -22768 5388 -5139 -299 -2891 515 -3229 1401 4536 -942 -3955 -3744 21 -1696 1513 224 2977 483 -1078 2648 -1787 -1782 -1148 2309 -277 3330 63 -115 -1163 -2209 15 1198 1395 1640 1084 172 2273 -995 -2294 -2736 -1084 -639 -664 -1220 -2451 -1417 -1473 -1228 298 1799 2336 804 1776 165 -337 -225 -393 112 1120 1260 806 181 -227 -1750 -766 293 -439 -1219 -727 -1220 -111 782 710 75 219 -706 250 -356 -29 148 877 82 194 39 224 309 306 -516 -1216 1033 424 10 -222 -1147 -598 -315 143 -689 309 912 621 229 338 -611 -355 900000 900000 900000 900000 900000 565 900000 900000 900000 900000 900000 257 900000 900000 521 749 860 967 182 1113 963 1212 1233 1067 913 898 1179 -166 951 157 782 -588 703 28 -213 160 -99 556 -3101 671 -793 -48 -494 88 -580 247 789 -176 -785 -783 5 -421 398 64 878 152 -354 846 -584 -578 -382 810 -110 1410 29 -51 -504 -983 7 636 805 982 650 100 1211 -499 -1091 -1302 -553 -371 -437 -891 -1937 -1167 -1279 -1124 281 1718 2217 750 1560 138 -272 -184 -347 110 1205 1481 1007 227 -271 -1960 -809 311 -495 -1446 -892 -1570 -150 1130 1088 119 345 -1079 363 -503 -41 216 1331 129 306 60 336 452 435 -716 -1652 1419 630 15 -376 -2021 -1079 -590 278 -1393 631 1876 1277 462 658 -1155 -661 SS 20230610T112606.8Z 8561.476467 196 1 40.11 2 72.77 74.35 54.01 183.79 0.00 1 0.00 1 0 17 9.061e-02 8.203e-03 4.660e-02 1.528e-03 5.156730e-01 7.910920e-04 5.974002e-03 -6.000000e+00 5.275399e-02 232.57 -2.00 3.57 -2.00 319.63 0.00e+00 1.378623e-03 2.328553e-04 8.646107e-04 -6.000000e+00 2.304285e-03 283.66 -2.00 20.00 -2.00 318.93 0.00e+00 3.326 0.001 302.00 328.00 3 2.3393e+00 2.2714e-03 4.3062e-02 -6.0000e+00 1.3256e-01 -2.5876e-02 2.7079e-03 2.7781e-02 -6.0000e+00 1.4349e-01 2.2441e-02 2.2667e-03 1.3922e-02 -6.0000e+00 8.5201e-02 -1.9990e-02 1.1825e-03 4.2105e-03 -6.0000e+00 3.5649e-02 1.0568e-03 2.5010e-04 4.2462e-05 4.3796e-05 -6.0000e+00 2.4686e-03 1.3892e-03 0.0000e+00 12 9 1 12 1 1 99.98 23.06 0.42 0.00139 0.00327 78 20 1 5 0 505.410 26.94 20.01 23.06 21.32 5.0 990.86 65286 -48226 5071 9973 17976 -26062 7977 38346 -14948 3496 -6795 -11206 21201 12981 9939 4182 9450 1771 -7749 9590 4709 6739 6741 4248 2049 2703 1249 -5413 -3605 -5796 -3670 -1339 2003 -2963 -5763 -4677 -5349 -4113 -7711 -1756 -1970 -1707 -684 -146 8 907 -45 -574 -1880 -1282 -4 259 270 1560 1119 1549 653 838 -696 -786 295 1772 1777 3690 1325 -860 -1146 -2004 955 1699 1175 1680 761 1235 549 -841 -1588 -2739 -1499 -1137 -801 -919 -2272 -1928 -768 -708 997 1329 1530 1057 1097 299 -1104 -233 -604 -75 418 1566 862 107 -535 -1969 -1052 -56 -819 -1572 -903 -1320 -162 794 696 490 339 -76 -385 -104 138 -64 641 122 19 359 774 534 684 -451 -806 757 603 14 -137 -926 -623 -158 -87 -322 106 870 430 210 127 -755 -289 310 -836 56 103 158 -346 81 332 -253 54 -121 -228 376 313 304 146 351 78 -404 447 239 339 352 247 133 186 88 -398 -254 -433 -305 -128 211 -350 -680 -538 -677 -567 -1357 -347 -440 -409 -170 -37 2 234 -12 -155 -527 -376 -1 84 96 590 449 644 282 362 -299 -334 128 828 868 1952 745 -477 -611 -1091 554 1052 807 1201 546 840 346 -516 -905 -1564 -925 -763 -620 -756 -2058 -1845 -733 -722 1056 1443 1652 1104 1068 287 -1015 -214 -580 -82 489 1939 1156 144 -676 -2399 -1185 -64 -1013 -1972 -1184 -1840 -230 1172 1115 782 557 -119 -566 -152 203 -95 998 200 31 571 1182 824 1011 -644 -1113 1065 939 24 -235 -1672 -1117 -298 -168 -654 212 1749 866 427 244 -1447 -541 SS 20230610T113201.2Z 8561.480569 199 1 10.11 2 71.74 75.28 54.07 185.55 0.00 1 0.00 1 0 17 1.776e-01 1.002e-02 1.381e-01 5.230e-03 4.997323e-01 2.773125e-03 5.782378e-03 -6.000000e+00 1.053989e-01 232.57 -2.00 3.57 -2.00 319.66 0.00e+00 -1.546373e-04 8.264898e-04 7.746867e-04 -6.000000e+00 5.114292e-03 283.66 -2.00 20.00 -2.00 318.96 0.00e+00 3.150 0.001 302.00 328.00 3 2.2640e+00 7.9894e-03 4.1268e-02 -6.0000e+00 2.6501e-01 -6.3359e-02 9.5700e-03 2.7134e-02 -6.0000e+00 2.8775e-01 6.8854e-02 8.1799e-03 1.3247e-02 -6.0000e+00 1.6864e-01 -3.9718e-02 4.2625e-03 3.6264e-03 -6.0000e+00 7.1557e-02 1.3808e-03 2.0251e-04 1.5093e-04 3.8178e-05 -6.0000e+00 5.1520e-03 2.8742e-03 0.0000e+00 12 9 9 12 1 1 99.31 23.06 0.49 0.00287 0.00440 6 7 2 5 0 1418.060 26.94 20.00 23.06 21.78 5.0 993.29 900000 -32165 900000 900000 900000 -5363 900000 900000 -2684 80201 900000 -4348 135174 72539 26280 41044 -12789 -3711 -10659 46507 17931 42418 14042 30228 8421 15137 5369 -14511 12192 1627 10304 -10152 8370 -2628 -401 -2235 -8841 4260 -15346 -2612 -4561 -2844 -6462 6165 1521 899 -524 -1712 -5240 -3154 -1036 -930 970 1735 1566 1099 927 1329 -2268 -64 -1555 2575 133 2884 728 523 98 -960 -375 1769 1094 1041 1017 1524 2334 -108 469 -2282 -1256 -49 -20 -1150 -2651 -1425 129 -1621 286 2293 2076 587 608 1052 -931 -820 -980 -602 -65 1034 887 -74 -788 -1976 -1012 -356 -1385 -1245 -582 -811 -237 694 1263 165 548 -401 -99 237 -343 182 849 22 -14 -549 752 254 939 -800 -1179 1237 1219 502 -158 -813 -755 -124 -289 -147 178 883 423 150 446 -973 -602 900000 -418 900000 900000 900000 -53 900000 900000 -37 555 900000 -77 757 911 620 979 -560 -162 -536 1457 763 1462 659 1332 498 897 354 -1121 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