File name: Pandora170s1_StGeorge_20230801_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20240418T224803.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20230801_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20230801 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230801T112056.3Z 8613.472874 208 1 49.09 2 78.22 76.27 108.84 253.66 0.00 1 0.00 1 0 17 2.551e-01 7.798e-03 8.291e-02 1.128e-03 6.872952e-01 6.041637e-04 8.019903e-03 -6.000000e+00 1.484807e-01 232.43 -2.00 3.57 -2.00 320.79 0.00e+00 1.604966e-03 2.685485e-04 3.205132e-03 -6.000000e+00 6.691220e-03 287.30 -2.00 20.00 -2.00 320.13 0.00e+00 4.740 0.002 302.00 328.00 3 3.5693e-01 1.9669e-03 6.1286e-02 -6.0000e+00 3.7252e-01 -2.5782e-02 2.6502e-03 4.1653e-02 -6.0000e+00 4.0303e-01 2.1666e-02 2.6452e-03 2.0654e-02 -6.0000e+00 2.3997e-01 -2.0102e-02 1.2840e-03 5.5874e-03 -6.0000e+00 1.0100e-01 1.7246e-03 1.8536e-04 3.0037e-05 8.0980e-05 -6.0000e+00 7.0359e-03 3.1249e-03 0.0000e+00 11 8 0 10 0 0 98.93 23.22 0.24 0.00312 0.00452 324 65 1 5 0 151.470 27.15 20.00 23.22 23.11 5.5 1004.69 -49878 -69181 -108634 900000 -131382 -50585 -72509 -84286 -95708 -86697 -62062 -89047 -25206 -53539 -45 -15454 -16217 -1576 -31681 5813 -13315 -2626 -13873 -2633 -22452 7823 -15294 -24020 -13195 -19446 -14394 -11500 158 -9837 -6539 -10217 -5766 -5668 2367 720 707 -82 -566 589 -1928 2528 1039 -369 -3135 -1615 -404 1079 1810 1661 1898 2709 2080 1227 395 -1396 162 2248 2675 3683 1017 497 -1258 -1873 470 1923 1033 1705 898 317 -14 -1271 -1827 -3464 -1867 -1853 -822 -893 -2153 -1527 -645 -270 929 1659 1511 1087 730 157 -1309 -863 -644 -358 387 1442 1060 -26 -411 -2225 -1051 14 -798 -1368 -962 -1138 15 925 921 772 519 -153 -393 -297 108 23 780 304 77 368 887 499 665 -770 -1208 670 178 -71 -294 -1045 -801 -202 -138 -278 241 931 446 164 207 -724 10 -115 -214 -554 900000 -802 -150 -295 -454 -613 -564 -376 -739 -155 -525 0 -164 -201 -19 -573 78 -226 -41 -257 -48 -561 156 -395 -668 -330 -562 -475 -415 6 -449 -285 -461 -275 -327 158 59 67 -8 -58 61 -210 272 117 -44 -408 -225 -62 186 345 347 424 634 472 282 96 -341 40 564 766 1181 356 173 -440 -686 188 879 492 845 444 149 -7 -535 -726 -1429 -855 -945 -488 -570 -1530 -1150 -515 -229 773 1409 1278 944 595 120 -985 -673 -565 -343 403 1698 1290 -31 -500 -2467 -1124 15 -873 -1596 -1180 -1419 20 1331 1465 1237 836 -239 -612 -444 163 37 1237 500 125 602 1389 757 972 -1153 -1766 963 291 -126 -546 -2075 -1599 -429 -299 -635 537 2087 998 369 436 -1504 21 SS 20230801T112640.4Z 8613.476856 211 1 49.90 2 77.21 77.20 109.78 254.53 0.00 1 0.00 1 0 17 5.822e-01 9.888e-03 2.136e-01 3.143e-03 6.444446e-01 1.753774e-03 7.344833e-03 -6.000000e+00 3.496702e-01 232.43 -2.00 3.57 -2.00 320.75 0.00e+00 1.252004e-03 7.702524e-04 1.982557e-03 -6.000000e+00 1.831280e-02 287.30 -2.00 20.00 -2.00 320.10 0.00e+00 4.393 0.002 302.00 328.00 3 2.6876e+00 5.6938e-03 5.6116e-02 -6.0000e+00 8.8079e-01 -5.7539e-02 7.6811e-03 3.6519e-02 -6.0000e+00 9.5905e-01 8.8813e-02 7.7198e-03 1.8831e-02 -6.0000e+00 5.5504e-01 -4.5708e-02 3.7510e-03 5.5945e-03 -6.0000e+00 2.4141e-01 2.3890e-04 3.9824e-04 8.9669e-05 7.0470e-05 -6.0000e+00 1.6966e-02 2.4133e-03 0.0000e+00 12 8 8 10 0 0 99.93 23.22 0.66 0.00241 0.00541 45 9 1 5 0 1108.640 27.15 20.00 23.22 23.44 5.6 1006.87 900000 900000 900000 900000 -147048 900000 900000 900000 -180118 900000 900000 -17123 900000 900000 900000 230725 45919 -27193 -1838 89541 55152 900000 193504 47601 -16914 453877 -16500 -9495 -15502 212664 -31073 -10609 1228 12487 25182 -1687 -7227 1692 34710 -3816 -748 1927 -2923 3167 -4477 5990 5813 7108 -8842 -4978 -3844 -112 378 2329 -285 3696 -2338 2147 1573 -3208 2125 -707 55 4317 1782 -192 -1587 -2566 588 2289 2028 2929 607 919 2253 -1036 91 -3968 -2855 -2655 637 -1691 -1348 -2380 -1499 -2981 360 2727 1707 1845 -221 485 -571 -1274 -1124 883 1032 1359 907 129 258 -2515 -636 -504 -200 -1029 377 -1608 -252 837 774 268 -14 -501 -325 288 9 100 647 482 299 -96 961 -18 552 -1109 -1084 1132 835 -298 -316 -1383 -799 113 -325 -316 155 1023 581 218 417 -666 -432 900000 900000 900000 900000 -1069 900000 900000 900000 -2714 900000 900000 -73 900000 900000 900000 705 312 -418 -25 533 481 900000 592 540 -393 1387 -423 -226 -390 650 -1143 -388 47 463 820 -71 -352 91 1685 -317 -68 187 -313 331 -513 641 640 803 -1216 -710 -602 -19 70 463 -62 811 -562 498 360 -759 495 -185 16 1358 603 -65 -538 -908 223 975 946 1412 296 428 961 -415 34 -1561 -1232 -1328 356 -1077 -925 -1739 -1149 -2445 300 2286 1437 1503 -173 358 -412 -952 -921 801 1049 1522 1086 155 294 -2694 -633 -507 -212 -1150 435 -1979 -329 1178 1168 421 -21 -768 -477 409 12 149 998 764 472 -147 1428 -26 780 -1541 -1473 1570 1265 -495 -558 -2558 -1522 224 -673 -676 336 2226 1264 464 850 -1313 -839 SS 20230801T115945.7Z 8613.499835 227 1 49.01 2 71.32 82.63 115.27 259.57 0.00 1 0.00 1 0 17 3.902e-02 8.377e-03 6.152e-03 5.586e-04 4.602077e-01 2.868999e-04 5.401832e-03 -6.000000e+00 2.270562e-02 232.43 -2.00 3.57 -2.00 318.92 0.00e+00 1.175137e-03 6.799085e-05 7.486572e-04 -6.000000e+00 1.007625e-03 287.30 -2.00 20.00 -2.00 318.12 0.00e+00 3.083 0.001 302.00 328.00 3 9.4446e-01 7.9869e-04 3.9227e-02 -6.0000e+00 5.6966e-02 6.5755e-03 9.2242e-04 2.4640e-02 -6.0000e+00 6.1632e-02 -5.3009e-03 6.6644e-04 1.2049e-02 -6.0000e+00 3.6680e-02 -6.4341e-03 3.5029e-04 3.4008e-03 -6.0000e+00 1.5403e-02 5.6638e-03 1.2549e-04 1.5602e-05 3.4991e-05 -6.0000e+00 1.0632e-03 2.7483e-03 0.0000e+00 11 8 0 10 0 0 99.69 23.21 0.21 0.00275 0.00369 358 72 1 5 0 136.850 27.15 20.00 23.21 24.98 5.5 1013.25 -5378 3829 -5995 -7291 -17843 -13206 -14218 -10674 -18727 -10372 -14343 -11007 -7304 -4536 -809 -977 -647 111 -468 668 563 -809 -68 750 -148 1042 -1485 -3761 -4147 -3373 -1245 447 2226 -1312 -5844 -5859 -4891 -3547 -772 -573 -724 -519 -29 -611 317 415 114 -36 -1376 -707 821 1081 1121 1549 810 1720 1236 539 57 -457 585 1511 2541 3117 1178 -342 -822 -1808 823 1420 1048 1489 860 1179 172 -796 -1560 -2862 -1440 -1381 -1259 -1107 -2496 -1880 -878 -392 651 970 1388 1022 881 127 -1163 -399 -384 -426 257 1268 753 -108 -578 -1987 -1161 8 -1009 -1480 -884 -1195 -92 697 849 632 550 -16 -294 -173 60 84 698 238 104 418 921 532 895 -300 -758 832 442 173 -12 -850 -583 -107 23 -215 101 636 266 88 29 -803 -388 -120 90 -166 -199 -497 -338 -392 -326 -706 -387 -575 -460 -348 -258 -49 -69 -50 9 -42 62 54 -79 -7 81 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