File name: Pandora170s1_StGeorge_20230908_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20240422T021040.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20230908_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20230908 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230908T145347.1Z 8651.620684 357 1 5.04 2 49.11 130.32 32.97 253.59 0.00 1 0.00 1 0 17 1.336e-02 9.529e-03 1.016e-03 6.488e-04 1.966743e-01 3.335280e-04 2.395436e-03 -6.000000e+00 7.700729e-03 229.70 -2.00 3.57 -2.00 315.26 0.00e+00 5.124829e-04 3.049643e-05 6.055546e-05 -6.000000e+00 3.426169e-04 285.60 -2.00 20.00 -2.00 314.59 0.00e+00 1.525 0.000 302.00 328.00 3 9.5865e-01 8.5989e-04 1.8158e-02 -6.0000e+00 1.9203e-02 1.6751e-02 9.5680e-04 1.0259e-02 -6.0000e+00 2.0823e-02 -2.4027e-03 5.4747e-04 4.9879e-03 -6.0000e+00 1.2408e-02 -3.8746e-03 2.4245e-04 1.3923e-03 -6.0000e+00 5.2332e-03 3.6967e-02 1.1027e-04 1.8322e-05 1.7180e-05 -6.0000e+00 3.6385e-04 8.4582e-04 0.0000e+00 12 9 9 12 1 1 99.91 23.26 0.24 0.00085 0.00167 94 189 1 5 0 52.920 27.15 20.00 23.26 23.82 5.9 997.14 2278 1119 1113 -2494 -4006 -2678 -1618 1647 731 -709 -4156 -2982 -1203 -472 1359 543 -266 839 1073 1911 1449 -255 937 1278 1518 1818 507 -648 -764 -566 825 1273 2952 -527 -4525 -3992 -3976 -2144 -293 -296 -906 -505 -205 -666 356 374 -289 -112 -983 -617 883 847 944 1207 518 1422 1119 430 133 -145 478 1400 2059 2619 626 -498 -1125 -1970 742 1125 516 921 529 1156 585 -398 -1208 -2228 -963 -1097 -1290 -1385 -2656 -1976 -1041 -502 287 528 978 865 863 175 -1108 -210 -108 -281 341 1202 737 17 -503 -1682 -1033 -19 -952 -1437 -836 -1114 -164 587 849 697 630 284 -84 -55 84 -100 617 389 47 345 706 521 1091 163 -339 900 424 385 255 -714 -535 -55 52 -228 38 590 176 -24 -81 -959 -790 661 333 337 -736 -1149 -705 -435 480 222 -229 -1366 -968 -417 -184 546 239 -122 391 482 877 682 -121 442 626 782 965 270 -329 -361 -273 404 623 1520 -287 -2416 -2044 -2176 -1263 -192 -212 -678 -393 -163 -536 283 295 -225 -84 -757 -470 654 668 784 994 441 1221 978 377 114 -125 421 1245 1965 2507 606 -470 -1018 -1729 672 1090 526 936 541 1185 564 -364 -1049 -1926 -849 -1027 -1293 -1457 -2884 -2144 -1195 -592 342 648 1195 1060 1019 197 -1192 -216 -116 -316 405 1496 937 21 -619 -2005 -1172 -22 -1168 -1808 -1093 -1465 -224 811 1222 975 873 378 -106 -68 103 -124 816 532 64 481 954 701 1386 206 -408 1114 537 502 335 -962 -730 -78 75 -336 57 903 263 -37 -120 -1418 -1148 SS 20230908T150027.1Z 8651.625313 361 1 51.94 2 48.20 132.17 34.11 255.18 0.00 1 0.00 1 0 17 1.325e-02 9.495e-03 2.323e-04 1.427e-04 1.930350e-01 7.322522e-05 2.350169e-03 -6.000000e+00 7.633196e-03 229.70 -2.00 3.57 -2.00 315.41 0.00e+00 4.984136e-04 6.928424e-06 7.137360e-05 -6.000000e+00 3.396140e-04 285.60 -2.00 20.00 -2.00 314.73 0.00e+00 1.498 0.000 302.00 328.00 3 2.0592e-01 1.8907e-04 1.7832e-02 -6.0000e+00 1.9034e-02 1.4093e-02 2.1051e-04 1.0068e-02 -6.0000e+00 2.0641e-02 -2.2292e-03 1.2047e-04 4.8928e-03 -6.0000e+00 1.2300e-02 -4.1287e-03 5.3722e-05 1.3609e-03 -6.0000e+00 5.1873e-03 8.1202e-02 1.2801e-04 4.0505e-06 1.7023e-05 -6.0000e+00 3.6066e-04 8.8369e-04 0.0000e+00 12 8 8 10 0 0 99.91 23.27 0.22 0.00088 0.00185 3418 685 1 5 0 14.620 27.15 20.00 23.27 24.52 6.1 1003.93 2174 1018 934 -2421 -3752 -2811 -1598 1322 1386 -894 -3808 -2950 -1173 -243 1221 598 -166 889 751 1757 1127 -52 990 1240 1510 1791 568 -735 -727 -583 777 1163 2867 -845 -4410 -4021 -4151 -2164 -356 -468 -927 -488 -303 -594 190 459 -388 -177 -1084 -577 778 782 1072 1285 628 1325 1211 365 90 -4 412 1422 2043 2649 659 -637 -1163 -1970 648 1164 496 995 611 1280 555 -386 -1137 -2373 -962 -1152 -1341 -1321 -2728 -1979 -1013 -527 249 569 1053 830 801 111 -1014 -245 -113 -280 344 1254 738 3 -428 -1784 -1093 8 -965 -1411 -823 -1131 -193 685 973 773 659 251 -154 -100 1 -144 590 305 129 379 726 442 1032 132 -436 934 443 404 140 -724 -493 -9 83 -165 77 528 150 -19 -60 -994 -741 562 290 271 -683 -953 -713 -413 343 400 -276 -1190 -913 -387 -90 465 248 -72 390 341 813 535 -25 469 610 729 891 283 -350 -344 -264 357 570 1477 -430 -2191 -2056 -2121 -1263 -229 -328 -712 -369 -234 -463 147 351 -292 -136 -813 -427 590 596 859 1072 540 1153 1015 307 79 -3 348 1272 1959 2530 637 -604 -1008 -1746 561 1130 503 1049 617 1304 533 -354 -996 -1975 -814 -1031 -1345 -1379 -2925 -2207 -1140 -633 301 708 1303 994 929 123 -1081 -249 -120 -311 400 1519 949 4 -537 -2083 -1272 9 -1206 -1798 -1089 -1497 -265 945 1398 1117 912 335 -197 -125 1 -180 788 419 183 530 984 602 1324 169 -535 1131 570 531 193 -979 -674 -13 120 -250 115 803 230 -28 -91 -1467 -1074 SS 20230908T152055.3Z 8651.639529 376 1 51.74 2 45.59 138.17 37.64 259.68 0.00 1 0.00 1 0 17 1.311e-02 9.520e-03 2.742e-04 1.723e-04 1.842558e-01 8.847686e-05 2.248347e-03 -6.000000e+00 7.553860e-03 229.70 -2.00 3.57 -2.00 315.33 0.00e+00 5.225583e-04 8.192226e-06 6.149435e-05 -6.000000e+00 3.360773e-04 285.60 -2.00 20.00 -2.00 314.65 0.00e+00 1.427 0.000 302.00 328.00 3 6.3746e-01 2.2834e-04 1.7009e-02 -6.0000e+00 1.8836e-02 1.7289e-02 2.5421e-04 9.6268e-03 -6.0000e+00 2.0426e-02 -1.3800e-03 1.4539e-04 4.6853e-03 -6.0000e+00 1.2172e-02 -4.6678e-03 6.4380e-05 1.3132e-03 -6.0000e+00 5.1335e-03 5.7323e-02 1.4942e-04 4.8813e-06 1.6387e-05 -6.0000e+00 3.5691e-04 7.3131e-04 0.0000e+00 12 8 8 10 0 0 100.00 23.26 0.19 0.00073 0.00185 2804 562 1 5 0 17.820 27.15 20.00 23.26 25.52 5.9 1005.07 2291 662 1020 -2201 -3835 -2616 -1487 1458 1386 -729 -3734 -2731 -1026 -403 1299 516 -133 825 800 1809 1203 -20 1053 1247 1490 1836 488 -660 -783 -510 813 1246 2873 -777 -4408 -3948 -4016 -2198 -319 -518 -964 -589 -338 -637 155 421 -373 -152 -1086 -546 709 805 1016 1259 619 1268 1197 344 94 -49 415 1393 2042 2618 690 -669 -1181 -1905 680 1156 473 1002 596 1280 581 -380 -1150 -2368 -949 -1139 -1335 -1334 -2715 -1983 -1004 -528 255 589 1053 859 792 118 -1055 -235 -142 -268 322 1275 775 6 -454 -1799 -1074 -45 -961 -1421 -813 -1146 -188 710 985 787 697 255 -202 -147 -31 -174 566 319 134 360 691 418 1029 122 -463 869 406 391 124 -708 -497 26 94 -163 79 567 191 -20 -28 -976 -770 634 203 316 -661 -1039 -651 -377 401 424 -238 -1234 -891 -356 -146 518 224 -60 378 352 811 554 -9 483 594 745 944 252 -324 -382 -238 384 625 1412 -403 -2235 -1920 -2088 -1307 -209 -370 -711 -452 -265 -504 121 326 -284 -118 -822 -407 541 616 817 1053 534 1106 1059 305 82 -43 370 1246 1956 2493 664 -631 -1073 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