File name: Pandora170s1_StGeorge_20231002_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20240423T220205.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20231002_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20231002 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231002T122532.0Z 8675.517731 259 1 49.80 2 78.51 106.40 63.20 272.02 0.00 1 0.00 1 0 33 1.831e-01 7.738e-03 1.515e-01 1.754e-03 5.348948e-01 9.080272e-04 6.189334e-03 -6.000000e+00 1.044654e-01 227.03 -2.00 3.57 -2.00 320.35 0.00e+00 1.336015e-03 3.409432e-04 1.174844e-03 -6.000000e+00 4.663332e-03 282.89 -2.00 20.00 -2.00 319.70 0.00e+00 4.854 0.002 302.00 328.00 3 1.3609e+00 2.7608e-03 5.5215e-02 -6.0000e+00 2.5907e-01 -6.6402e-02 3.4935e-03 2.8908e-02 -6.0000e+00 2.8180e-01 5.1440e-02 3.3032e-03 1.4845e-02 -6.0000e+00 1.6792e-01 -3.1386e-02 1.6657e-03 4.5678e-03 -6.0000e+00 7.1445e-02 7.1383e-04 -1.2269e-05 4.9985e-05 5.4561e-05 -6.0000e+00 5.0215e-03 4.4569e-03 0.0000e+00 11 8 0 10 0 0 73.03 23.15 0.38 0.00446 0.00436 126 25 1 5 0 395.140 27.05 20.00 23.15 26.02 6.2 1032.38 900000 4310 136238 8539 34603 89498 36373 92188 -36715 -21471 -42368 -14676 14685 32234 24669 3001 6419 2062 -6467 15842 13692 5656 19225 9340 -5221 16489 8316 -9931 -6402 2933 -9022 -1845 4508 -348 -3953 -5568 -3696 -4560 2438 -3133 -668 -2831 -1888 -2170 -1530 -1318 1653 611 -4562 -3310 -767 2185 -504 901 739 1363 51 994 -282 -2177 10 1093 1254 3067 1659 -701 -155 -2397 1058 1772 1132 1977 1126 1312 143 -1564 -1250 -2822 -2234 -2048 -794 -1143 -2079 -1862 -829 -72 1069 1492 1642 1400 893 339 -819 -286 -960 55 465 1668 1046 37 -638 -1850 -1005 -93 -899 -1585 -749 -1133 69 631 909 492 426 -249 -413 -50 -435 -34 565 197 -22 264 723 379 594 -429 -1016 718 344 12 30 -987 -687 -137 -180 -335 90 909 484 217 136 -599 -291 900000 21 233 42 124 181 136 229 -382 -210 -540 -157 144 336 345 62 145 54 -199 416 383 174 541 318 -208 615 315 -442 -270 118 -472 -106 281 -24 -281 -399 -285 -427 263 -396 -93 -437 -304 -361 -257 -226 280 107 -873 -664 -165 510 -133 253 221 424 16 322 -90 -706 3 391 469 1252 717 -301 -64 -1034 487 932 662 1121 641 761 77 -776 -574 -1315 -1142 -1225 -509 -833 -1668 -1486 -701 -65 1004 1439 1578 1301 779 277 -685 -243 -851 56 503 2013 1295 46 -792 -2100 -1057 -99 -1042 -1965 -916 -1481 97 924 1449 780 704 -395 -615 -71 -625 -51 902 330 -38 429 1129 575 864 -638 -1471 1064 540 21 55 -1800 -1305 -275 -368 -720 198 2017 1077 470 278 -1229 -584 SS 20231002T123118.3Z 8675.521740 262 1 13.59 2 77.51 107.47 64.20 272.97 0.00 1 0.00 1 0 17 9.277e-02 8.236e-03 9.104e-02 2.983e-03 4.976960e-01 1.518904e-03 5.775901e-03 -6.000000e+00 5.291093e-02 227.02 -2.00 3.57 -2.00 319.96 0.00e+00 1.038322e-03 5.034834e-04 9.031256e-04 -6.000000e+00 2.351669e-03 282.89 -2.00 20.00 -2.00 319.29 0.00e+00 4.494 0.002 302.00 328.00 3 1.5071e+00 4.4449e-03 5.1074e-02 -6.0000e+00 1.3122e-01 -4.6823e-02 5.4262e-03 2.6530e-02 -6.0000e+00 1.4267e-01 3.4668e-02 4.7966e-03 1.3429e-02 -6.0000e+00 8.5057e-02 -2.5041e-02 2.4752e-03 4.0363e-03 -6.0000e+00 3.5964e-02 8.8886e-04 1.3153e-04 8.4676e-05 4.4859e-05 -6.0000e+00 2.5244e-03 3.6118e-03 0.0000e+00 12 9 1 12 1 1 99.39 23.15 0.34 0.00361 0.00460 33 25 1 5 0 399.500 27.05 20.00 23.15 26.69 6.2 1035.68 -36687 -23175 -22695 38592 -22544 -12274 -37450 39023 13610 10351 8498 -53713 -2704 1575 5007 7398 -1818 1569 5470 7710 13415 5576 10870 2948 -5010 6362 489 -6704 -5675 888 -664 -90 7832 -2425 -4022 -5657 -5182 -183 644 1525 -524 -1512 -3441 -1666 -2674 1077 -482 -1358 -3519 -2535 -1942 820 1674 1473 961 1452 187 464 211 -2057 406 1399 822 3064 1460 -762 -486 -2162 1510 2458 1632 1236 1474 1532 637 -1306 -2077 -3848 -1444 -1491 -726 -785 -2657 -1607 -145 -594 842 1266 1885 1157 1387 -14 -999 -377 -620 -265 349 1339 1054 68 -643 -1777 -1234 221 -828 -1767 -1033 -1320 139 1008 723 717 484 125 -424 -478 -295 -105 248 278 -146 155 547 510 767 -76 -712 950 399 -222 -96 -763 -518 -150 57 -467 236 620 496 151 160 -734 -260 -398 -257 -270 245 -244 -117 -495 279 144 123 108 -1276 -51 35 134 208 -63 57 207 303 517 235 453 145 -293 353 29 -419 -343 52 -45 -7 651 -238 -390 -551 -550 -22 88 246 -97 -306 -745 -363 -598 236 -109 -314 -855 -642 -534 244 501 476 330 518 69 173 77 -762 152 568 377 1517 711 -392 -239 -1099 760 1406 1038 827 979 971 376 -708 -1123 -2104 -788 -949 -531 -607 -2279 -1448 -130 -571 845 1304 1925 1148 1281 -13 -879 -335 -571 -278 391 1675 1348 87 -821 -2077 -1344 243 -994 -2274 -1316 -1790 202 1514 1125 1158 773 200 -638 -688 -426 -159 399 446 -237 243 870 784 1128 -114 -1034 1407 625 -370 -171 -1377 -971 -285 115 -954 491 1307 1048 309 325 -1431 -518 SS 20231002T123640.9Z 8675.525473 265 1 49.99 2 76.59 108.47 65.13 273.86 0.00 1 0.00 1 0 17 6.074e-02 8.132e-03 2.210e-02 1.078e-03 4.705102e-01 5.474765e-04 5.520966e-03 -6.000000e+00 3.464254e-02 227.02 -2.00 3.57 -2.00 319.70 0.00e+00 1.334972e-03 1.643529e-04 8.979993e-04 -6.000000e+00 1.539808e-03 282.89 -2.00 20.00 -2.00 319.00 0.00e+00 4.206 0.001 302.00 328.00 3 1.1535e+00 1.5699e-03 4.7922e-02 -6.0000e+00 8.5915e-02 -4.0436e-02 1.8838e-03 2.5022e-02 -6.0000e+00 9.3411e-02 2.0007e-02 1.5717e-03 1.2659e-02 -6.0000e+00 5.5691e-02 -1.6847e-02 8.1774e-04 3.8511e-03 -6.0000e+00 2.3545e-02 1.7019e-03 1.0298e-04 3.0830e-05 4.2510e-05 -6.0000e+00 1.6529e-03 4.0983e-03 0.0000e+00 11 8 0 10 0 0 40.80 23.15 0.37 0.00410 0.00487 218 44 1 5 0 229.280 27.05 20.00 23.15 27.34 6.2 1039.90 -4285 -44390 11013 -7533 -9204 -28754 590 -18703 -2550 -18110 -16937 -20701 -4336 2447 -5638 3291 -4270 3599 -5998 8332 -183 358 4321 1849 -188 962 984 -7137 -3934 -5193 -1290 -736 2350 -1226 -5960 -5346 -5760 -540 -73 299 -1128 -1202 -794 -835 162 -38 479 -1220 -1073 -1390 815 850 134 1041 524 1298 537 900 -1104 -878 -292 1467 1773 3060 855 -91 -732 -1881 1115 1588 1544 1572 1046 1166 537 -964 -1398 -2899 -1899 -1288 -1119 -1110 -2599 -1618 -841 -116 751 1233 1804 1338 1071 115 -971 -633 -560 -463 437 1220 970 119 -732 -2039 -1152 69 -973 -1620 -896 -1250 -18 912 1039 553 488 -88 -381 -160 -122 -208 655 179 -52 327 708 424 700 -356 -966 944 450 123 -20 -1031 -593 -236 -3 -278 140 719 437 197 219 -721 -411 -47 -848 129 -104 -132 -440 8 -320 -42 -381 -366 -504 -107 70 -214 133 -207 175 -346 440 -11 21 258 122 -14 74 77 -587 -304 -420 -113 -68 240 -138 -680 -597 -706 -75 -12 60 -258 -296 -188 -203 39 -9 119 -313 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