File name: Pandora170s1_StGeorge_20231010_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20240424T102505.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20231010_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20231010 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231010T134130.9Z 8683.570496 237 1 49.96 2 68.04 123.93 30.09 161.05 0.00 1 0.00 1 0 17 2.517e-02 9.115e-03 1.194e-02 1.710e-03 3.821832e-01 8.586777e-04 4.546530e-03 -6.000000e+00 1.430468e-02 226.06 -2.00 3.57 -2.00 318.38 0.00e+00 1.058004e-03 1.720899e-04 3.454173e-04 -6.000000e+00 6.406022e-04 281.89 -2.00 20.00 -2.00 317.67 0.00e+00 2.651 0.000 302.00 328.00 3 3.6444e+00 2.3165e-03 3.2641e-02 -6.0000e+00 3.5410e-02 1.8985e-02 2.6487e-03 1.9735e-02 -6.0000e+00 3.8529e-02 1.9205e-02 1.8089e-03 9.8337e-03 -6.0000e+00 2.2991e-02 -1.7218e-02 9.5155e-04 2.9395e-03 -6.0000e+00 9.7877e-03 6.3277e-04 1.9597e-04 4.8578e-05 2.9987e-05 -6.0000e+00 6.8501e-04 1.9687e-03 0.0000e+00 11 8 0 10 0 0 99.93 22.52 0.49 0.00197 0.00344 35 7 1 5 0 1427.050 26.41 19.99 22.52 14.91 6.1 987.65 6284 900000 4175 3641 -3717 -12766 9456 126 196 -2732 -7978 -10441 -419 731 285 2253 -3426 1146 -5084 4280 2087 4632 3781 1025 -815 2509 850 -2619 -1650 -545 -726 -1524 3407 478 -5206 -5681 -4731 -1533 -413 -809 -2355 -522 -1726 -416 -867 33 2077 -29 -1771 -1500 552 523 958 876 1098 1150 828 692 -201 -779 -249 1808 1298 3067 1060 -407 -988 -1852 588 1587 1541 1992 1277 1132 1213 -788 -733 -2600 -1770 -1575 -1229 -887 -2367 -1895 -1170 -346 418 916 1202 703 968 100 -680 -226 -263 -363 733 1095 1180 -362 -803 -1898 -1157 311 -899 -1524 -619 -1388 -282 621 887 432 500 -307 9 -100 -319 -256 683 371 55 361 523 678 838 11 -951 1273 599 330 161 -1062 -611 -114 68 -487 419 742 418 179 267 -1119 -764 224 900000 181 154 -155 -555 353 6 10 -155 -486 -686 -29 59 27 239 -413 140 -697 563 288 627 528 156 -135 424 146 -449 -270 -89 -128 -302 714 107 -1184 -1271 -1129 -411 -130 -293 -941 -216 -745 -181 -379 14 892 -13 -785 -678 260 264 511 489 633 679 499 417 -120 -465 -152 1152 894 2213 786 -294 -685 -1285 425 1250 1298 1723 1108 955 969 -593 -516 -1814 -1290 -1263 -1080 -837 -2373 -1964 -1260 -388 483 1078 1409 806 1057 103 -675 -223 -272 -406 881 1406 1580 -486 -1036 -2321 -1358 369 -1126 -1989 -827 -1925 -404 931 1381 685 780 -463 13 -139 -444 -367 1014 570 85 552 783 991 1189 16 -1291 1727 859 501 253 -1721 -1005 -192 118 -879 764 1364 770 325 471 -1938 -1309 SS 20231010T140731.2Z 8683.588556 251 1 24.48 2 64.28 129.67 29.15 173.43 0.00 1 0.00 1 0 17 2.602e-02 9.837e-03 1.373e-02 2.899e-03 3.352687e-01 1.451152e-03 4.001715e-03 -6.000000e+00 1.479405e-02 226.06 -2.00 3.57 -2.00 317.77 0.00e+00 9.742084e-04 2.433269e-04 2.018237e-04 -6.000000e+00 6.569155e-04 281.88 -2.00 20.00 -2.00 317.06 0.00e+00 2.290 0.000 302.00 328.00 3 4.2774e+00 3.8552e-03 2.8327e-02 -6.0000e+00 3.6621e-02 2.7984e-02 4.3686e-03 1.7228e-02 -6.0000e+00 3.9845e-02 1.8747e-02 2.7661e-03 8.5402e-03 -6.0000e+00 2.3759e-02 -1.5724e-02 1.4183e-03 2.5454e-03 -6.0000e+00 1.0061e-02 5.0206e-04 4.8708e-04 8.2507e-05 2.6105e-05 -6.0000e+00 7.0791e-04 8.2689e-04 0.0000e+00 12 9 9 12 1 1 99.79 22.51 0.65 0.00083 0.00449 8 4 1 5 0 2718.720 26.41 20.00 22.51 15.35 6.1 986.75 11113 -2988 -95 1146 5655 -7163 -1166 12176 -2088 3635 -5411 -11054 3460 -3839 356 2400 -222 -1557 -4800 1363 4195 3109 6676 2128 16 1593 -922 -3929 -2914 1138 -301 28 1686 -287 -7434 -4573 -4182 789 360 -1558 -1298 18 -770 -1492 -578 354 1106 -818 -2929 -262 1557 1258 -319 1345 1009 1151 1306 1533 -638 -582 280 2064 477 2909 938 -25 -504 -1547 180 1655 986 2064 1187 990 881 -900 -842 -2890 -2193 -1650 -1010 -1253 -2448 -2005 -1040 -121 898 951 1842 657 556 -305 -765 -684 -326 -1102 521 1686 496 -95 -488 -1331 -1329 96 -548 -1220 -1506 -915 -166 638 769 368 479 -73 27 -179 -392 -155 881 -16 -150 609 391 764 757 -221 -443 1465 975 531 90 -1207 -407 5 7 -685 135 1065 251 465 -379 -847 -796 627 -216 -7 80 346 -472 -76 794 -174 305 -500 -1121 348 -483 50 369 -37 -278 -925 259 796 597 1265 444 4 370 -219 -922 -648 243 -70 7 460 -82 -2182 -1281 -1251 260 139 -695 -626 9 -397 -784 -303 185 571 -425 -1540 -137 842 726 -196 851 659 766 882 1032 -430 -390 191 1470 367 2318 763 -19 -378 -1159 140 1397 890 1904 1099 893 756 -727 -636 -2159 -1701 -1394 -927 -1234 -2545 -2151 -1157 -140 1068 1153 2217 778 629 -328 -782 -693 -345 -1255 632 2165 667 -127 -629 -1626 -1571 115 -690 -1599 -2034 -1268 -238 950 1187 575 735 -108 38 -244 -535 -217 1279 -25 -229 915 576 1098 1058 -302 -588 1944 1361 782 138 -1888 -643 8 11 -1186 237 1874 445 809 -647 -1411 -1314 SS 20231010T141618.3Z 8683.594657 257 1 6.66 2 63.08 131.70 29.06 177.73 0.00 1 0.00 1 0 17 4.562e-02 1.266e-02 3.156e-02 7.704e-03 3.127453e-01 3.852561e-03 3.722696e-03 -6.000000e+00 2.593129e-02 226.05 -2.00 3.57 -2.00 317.60 0.00e+00 1.825027e-03 6.128449e-04 1.577878e-04 -6.000000e+00 1.151706e-03 281.88 -2.00 20.00 -2.00 316.89 0.00e+00 2.196 0.000 302.00 328.00 3 4.4865e+00 1.0200e-02 2.6857e-02 -6.0000e+00 6.4189e-02 9.3469e-03 1.1534e-02 1.6086e-02 -6.0000e+00 6.9845e-02 1.2424e-02 7.1438e-03 7.9642e-03 -6.0000e+00 4.1648e-02 -8.7483e-03 3.6159e-03 2.6533e-03 -6.0000e+00 1.7632e-02 4.6495e-04 3.5075e-04 2.2001e-04 2.5812e-05 -6.0000e+00 1.2412e-03 2.5096e-03 0.0000e+00 12 9 9 12 33 1 999.00 22.51 0.76 0.00251 0.00515 1 3 1 5 0 3327.500 26.41 20.00 22.51 15.55 6.1 987.66 -15126 -5892 -1609 -12873 3090 -7927 28878 -8572 14917 14664 -11277 -9111 8064 -4482 -1619 10077 -8370 5771 2284 5024 -2053 5049 5540 2650 -676 -1397 -134 -5649 1593 -2031 -1478 -470 3224 300 -9821 -1211 -1721 -1177 1903 368 -3951 1530 907 -910 -569 657 -68 -981 -2743 -2932 50 1277 889 3798 1654 2026 2366 64 -748 -102 323 2534 -1302 4628 1176 2070 -1339 -3706 546 1077 1293 789 1355 1286 -69 -3631 -1290 -3877 -808 -1308 -2111 -1848 -2409 -1524 -1247 61 180 908 1776 1358 1664 581 55 -2274 -1145 343 535 1688 117 -194 -815 -734 -1422 638 -519 -1711 -588 -1335 363 727 1023 -370 958 74 58 -334 -169 -174 1395 124 -17 706 341 782 -8 -333 -1451 2042 492 -402 928 -1321 -314 -445 363 -330 -409 558 103 655 280 -545 -910 -1314 -526 -143 -1225 231 -623 1680 -794 1235 1282 -1264 -1038 886 -644 -262 1630 -1697 1079 461 1029 -458 1058 1172 604 -167 -362 -34 -1459 370 -484 -373 -129 930 92 -3134 -351 -536 -417 766 170 -2035 789 483 -498 -311 358 -37 -532 -1499 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