File name: Pandora170s1_StGeorge_20231027_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20240425T075036.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20231027_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20231027 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231027T130837.3Z 8700.547654 253 1 49.98 2 77.38 121.84 118.65 311.12 0.00 1 0.00 1 0 17 7.078e-02 8.042e-03 1.901e-02 9.986e-04 4.725634e-01 5.016917e-04 5.562305e-03 -6.000000e+00 3.996752e-02 224.34 -2.00 3.57 -2.00 319.76 0.00e+00 1.928958e-03 1.546363e-04 9.632187e-04 -6.000000e+00 1.770680e-03 279.73 -2.00 20.00 -2.00 319.14 0.00e+00 4.452 0.002 302.00 328.00 3 7.7648e-01 1.4346e-03 4.9777e-02 -6.0000e+00 9.8622e-02 -2.9622e-02 1.7160e-03 2.4790e-02 -6.0000e+00 1.0748e-01 9.8545e-03 1.4627e-03 1.2813e-02 -6.0000e+00 6.4093e-02 -1.3622e-02 7.6506e-04 4.2161e-03 -6.0000e+00 2.7178e-02 1.9861e-03 -4.1555e-05 2.8384e-05 4.6672e-05 -6.0000e+00 1.9245e-03 2.1826e-03 0.0000e+00 11 8 0 10 0 0 66.12 23.58 0.26 0.00218 0.00187 280 56 1 5 0 178.460 27.45 20.00 23.58 23.32 6.4 1010.93 -17860 -27818 -21362 -15907 -28087 -26577 -29777 -6961 -18897 -24078 -22299 -24175 -3856 -9905 -4012 -2658 -78 -3646 -5824 1042 2834 346 1621 1846 -1625 2574 -1500 -6413 -4637 -6376 -2393 642 3358 -2013 -5395 -6756 -3857 -4861 555 -428 -1274 131 -805 -265 -327 785 347 984 -1906 -530 1073 1096 947 748 921 1331 923 205 -697 -1278 -46 1171 2363 3391 1229 -279 -884 -1639 630 1807 1052 1595 842 1119 441 -832 -1122 -3353 -1803 -1392 -1032 -1254 -2223 -1834 -881 -82 717 1218 1528 1335 1026 338 -1025 -565 -483 -304 354 1307 889 92 -604 -2060 -1147 -49 -816 -1657 -879 -1142 -72 878 950 614 445 -49 -394 -368 -68 6 537 184 61 405 843 487 714 -334 -955 657 284 234 -81 -963 -683 -104 49 -249 128 784 413 187 196 -794 -404 -223 -448 -346 -239 -440 -395 -488 -115 -363 -527 -497 -597 -93 -317 -148 -113 -4 -190 -334 59 163 21 98 121 -110 176 -109 -474 -327 -473 -192 58 338 -227 -610 -762 -460 -697 92 -79 -266 29 -189 -63 -79 192 86 246 -501 -144 312 353 332 283 340 508 364 82 -274 -501 -19 507 1133 1773 680 -151 -460 -865 356 1079 698 1103 584 740 271 -500 -624 -1883 -1087 -907 -774 -996 -1935 -1686 -808 -79 733 1278 1597 1349 971 317 -916 -508 -475 -320 397 1637 1140 118 -773 -2424 -1327 -54 -983 -2139 -1123 -1551 -105 1319 1470 989 707 -79 -587 -523 -97 8 853 294 98 662 1329 745 1046 -498 -1381 966 440 383 -143 -1710 -1257 -201 97 -517 261 1615 854 377 391 -1523 -793 SS 20231027T131941.6Z 8700.555343 256 1 50.03 2 75.70 124.02 120.02 313.71 0.00 1 0.00 1 0 17 3.848e-02 8.219e-03 7.850e-03 6.705e-04 4.239031e-01 3.341424e-04 5.021186e-03 -6.000000e+00 2.173223e-02 224.34 -2.00 3.57 -2.00 319.20 0.00e+00 1.750467e-03 8.519518e-05 6.082544e-04 -6.000000e+00 9.627791e-04 279.73 -2.00 20.00 -2.00 318.55 0.00e+00 3.962 0.001 302.00 328.00 3 5.5815e-01 9.2838e-04 4.4310e-02 -6.0000e+00 5.3625e-02 -1.9615e-02 1.0809e-03 2.1984e-02 -6.0000e+00 5.8442e-02 -1.3496e-03 8.2574e-04 1.1169e-02 -6.0000e+00 3.4850e-02 -7.7039e-03 4.3753e-04 3.6334e-03 -6.0000e+00 1.4778e-02 4.0997e-03 2.6911e-05 1.9136e-05 3.8642e-05 -6.0000e+00 1.0464e-03 2.0093e-03 0.0000e+00 11 8 0 10 0 0 67.37 23.59 0.25 0.00201 0.00221 436 87 1 5 0 114.730 27.45 20.00 23.59 24.04 6.4 1015.84 -9778 -7154 -9003 -10636 -14677 -15489 -11410 -8445 -9842 -13152 -12102 -16816 -5077 -4069 -456 -495 -117 -82 -1608 3157 942 187 686 1955 -1097 574 -1015 -4165 -2675 -5401 -385 -203 3489 -758 -4907 -5497 -4700 -2407 -351 -219 -1051 -636 -1039 -249 -102 542 -19 -278 -1130 -626 708 667 1342 1165 1044 1462 1141 341 -310 -524 65 1348 2122 3127 1154 -172 -1006 -1795 820 1559 993 1476 899 1196 353 -725 -1427 -3005 -1540 -1533 -1324 -1087 -2581 -1877 -950 -227 737 1169 1504 1123 911 225 -1070 -533 -412 -376 321 1377 951 -19 -541 -1996 -1156 52 -1001 -1428 -918 -1107 -145 730 970 669 505 0 -394 -301 -41 -178 622 213 35 321 824 523 775 -266 -796 880 303 235 5 -889 -631 -108 41 -246 160 702 331 124 81 -826 -395 -216 -177 -241 -282 -371 -378 -283 -232 -311 -460 -431 -672 -212 -206 -27 -34 -9 -7 -140 275 87 17 65 197 -113 61 -111 -455 -278 -587 -44 -27 497 -119 -774 -854 -786 -466 -81 -55 -299 -193 -330 -80 -33 178 -6 -93 -384 -220 265 274 551 512 481 696 558 168 -151 -254 32 720 1253 1865 721 -104 -582 -1046 507 1093 722 1118 683 867 255 -477 -867 -1817 -991 -1138 -1057 -971 -2383 -1821 -976 -234 798 1299 1665 1203 913 221 -998 -495 -416 -405 369 1754 1240 -24 -701 -2382 -1359 62 -1235 -1879 -1201 -1532 -204 1110 1510 1078 798 1 -578 -441 -60 -261 968 334 55 497 1290 793 1122 -390 -1130 1263 457 373 9 -1518 -1111 -200 78 -470 311 1387 658 240 155 -1529 -716 SS 20231027T133016.0Z 8700.562686 259 1 50.06 2 74.14 126.14 121.27 316.25 0.00 1 0.00 1 0 17 2.771e-02 8.412e-03 4.648e-03 5.719e-04 3.888202e-01 2.842733e-04 4.636415e-03 -6.000000e+00 1.564777e-02 224.34 -2.00 3.57 -2.00 318.76 0.00e+00 1.242333e-03 6.323465e-05 4.876413e-04 -6.000000e+00 6.932121e-04 279.73 -2.00 20.00 -2.00 318.09 0.00e+00 3.595 0.001 302.00 328.00 3 6.7165e-01 7.7362e-04 4.0295e-02 -6.0000e+00 3.8612e-02 -1.8124e-02 8.8975e-04 2.0105e-02 -6.0000e+00 4.2080e-02 -3.1366e-03 6.3452e-04 1.0083e-02 -6.0000e+00 2.5093e-02 -6.3356e-03 3.3541e-04 3.0893e-03 -6.0000e+00 1.0641e-02 5.3760e-03 1.6530e-05 1.6354e-05 3.2609e-05 -6.0000e+00 7.5342e-04 1.8661e-03 0.0000e+00 11 8 0 10 0 0 94.71 23.58 0.26 0.00187 0.00199 460 92 1 5 0 108.740 27.45 20.00 23.58 24.78 6.4 1020.71 -6033 -486 -7316 -5403 -12874 -9204 -9743 -2369 -6114 -7248 -8917 -12019 -2773 -3201 1839 218 1210 996 331 1812 724 462 541 2340 99 1664 -726 -3108 -2967 -3368 -527 799 3738 -994 -4445 -5089 -4357 -2932 -491 -600 -1202 -581 -645 -458 -56 827 -210 46 -1251 -677 682 859 1064 1333 981 1407 1460 211 -50 -645 288 1587 2242 3172 1011 -393 -956 -1708 639 1572 986 1360 753 1312 435 -817 -1196 -2736 -1287 -1434 -1477 -1210 -2582 -1920 -999 -206 578 1055 1352 1107 943 144 -1127 -462 -427 -305 341 1309 822 5 -522 -2004 -1176 43 -874 -1490 -945 -1122 -187 816 916 573 461 46 -356 -222 -28 -100 650 225 26 408 836 505 921 -164 -852 846 343 285 11 -831 -542 -94 -3 -202 93 685 311 29 82 -852 -434 -202 -18 -299 -210 -491 -322 -363 -93 -283 -363 -464 -683 -167 -233 152 19 115 101 36 203 84 54 65 295 14 240 -108 -454 -415 -477 -79 135 684 -200 -891 -1003 -923 -724 -133 -192 -431 -220 -237 -171 -21 310 -80 19 -481 -267 284 391 521 694 535 738 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