File name: Pandora170s1_StGeorge_20240102_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20240427T224148.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20240102_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20240102 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240102T172741.3Z 8767.727562 426 1 50.07 2 66.59 181.55 100.58 284.19 0.00 1 0.00 1 0 25 2.762e-01 1.002e-02 7.980e-02 1.851e-03 3.978736e-01 9.172512e-04 4.706844e-03 -6.000000e+00 1.551160e-01 222.91 -2.00 3.57 -2.00 318.77 0.00e+00 9.041238e-04 2.013200e-04 3.984586e-04 -6.000000e+00 6.713586e-03 272.76 -2.00 20.00 -2.00 318.24 0.00e+00 2.498 0.000 302.00 328.00 3 3.5771e+00 2.4772e-03 3.1652e-02 -6.0000e+00 3.8245e-01 5.9815e-02 2.8500e-03 2.0149e-02 -6.0000e+00 4.1765e-01 3.9549e-02 2.1114e-03 1.0298e-02 -6.0000e+00 2.4831e-01 -2.7909e-02 1.1286e-03 3.2298e-03 -6.0000e+00 1.0501e-01 7.4478e-04 3.9397e-04 5.2750e-05 3.3047e-05 -6.0000e+00 7.5037e-03 -1.0226e-03 0.0000e+00 12 8 8 10 0 0 99.99 22.94 0.39 -0.00102 0.00194 177 35 1 5 0 282.790 26.83 20.00 22.94 6.19 7.4 996.99 32587 318147 13641 16641 5181 -261 15291 11885 -978 -2501 -1557 422 9871 4404 6536 4874 1810 2977 -1584 2736 3576 3161 5821 693 130 2793 2525 -5421 -1483 -2398 -1138 825 1378 -1048 -7557 -5439 -3650 -2552 -395 -388 -1695 -2446 -1241 -1104 -321 137 1031 -1568 -2677 -936 -400 704 468 1204 1086 2400 649 115 -643 -569 -138 747 1641 3123 902 -669 -1125 -2617 109 1206 1531 1411 1460 1111 596 -1139 -1486 -3336 -2121 -1587 -1366 -839 -2316 -1533 -992 272 907 1895 2132 1402 1182 -199 -1501 -1236 -982 -209 626 1565 1154 368 -279 -2253 -1527 -643 -1081 -1520 -307 -829 128 1117 1298 613 653 -306 -539 -923 -791 -616 386 448 243 832 845 371 456 -613 -1263 146 -195 -8 41 -918 -806 -273 104 -24 677 1143 525 133 187 -971 -602 752 632 440 511 163 -8 446 402 -41 -114 -72 20 502 278 476 407 168 290 -170 296 394 351 647 86 17 383 350 -779 -198 -325 -166 132 244 -198 -1465 -1012 -719 -578 -105 -119 -580 -893 -463 -419 -121 52 388 -603 -1045 -369 -167 315 224 604 566 1271 356 63 -349 -306 -76 437 1036 2087 625 -450 -723 -1694 73 898 1227 1172 1206 888 449 -798 -968 -2153 -1436 -1196 -1146 -764 -2262 -1552 -1049 301 1038 2201 2465 1581 1263 -201 -1448 -1184 -995 -230 751 2020 1571 500 -362 -2754 -1774 -755 -1347 -1983 -410 -1156 185 1708 2080 1004 1050 -474 -793 -1306 -1118 -899 584 704 384 1289 1278 548 650 -851 -1707 199 -282 -13 66 -1526 -1366 -477 188 -45 1286 2186 1009 252 341 -1727 -1054 SS 20240102T173240.9Z 8767.731029 429 1 50.18 2 66.62 182.80 101.44 285.05 0.00 1 0.00 1 0 25 4.280e-02 1.047e-02 1.285e-02 1.577e-03 3.977495e-01 7.809125e-04 4.735892e-03 -6.000000e+00 2.403629e-02 222.91 -2.00 3.57 -2.00 318.39 0.00e+00 1.383124e-03 1.543489e-04 3.643637e-04 -6.000000e+00 1.040329e-03 272.76 -2.00 20.00 -2.00 317.86 0.00e+00 2.501 0.000 302.00 328.00 3 3.5336e+00 2.0872e-03 3.1665e-02 -6.0000e+00 5.9263e-02 7.1363e-02 2.3828e-03 2.0124e-02 -6.0000e+00 6.4719e-02 1.9802e-02 1.6797e-03 1.0267e-02 -6.0000e+00 3.8477e-02 -1.8637e-02 8.9540e-04 3.3317e-03 -6.0000e+00 1.6271e-02 7.7463e-04 3.8577e-04 4.4384e-05 3.3240e-05 -6.0000e+00 1.1628e-03 -8.6571e-04 0.0000e+00 12 8 8 10 0 0 99.99 22.94 0.55 -0.00087 0.00203 72 14 1 5 0 696.770 26.83 20.00 22.94 6.20 7.4 997.20 10141 27788 12305 22467 6342 4204 12793 10063 5319 -2128 -1456 -11331 6638 2256 5657 -372 1212 164 -612 4020 1379 3700 3577 3998 -1579 4048 -956 -4424 -2614 -2503 -2420 -2971 2445 -2575 -5263 -6359 -5006 -2285 -151 -118 -1687 -1519 -1481 -359 -1087 551 -176 -97 -2971 -488 -393 279 1011 1498 1205 2054 1122 384 -66 -888 231 1220 1565 3296 954 163 -1286 -2037 180 1918 898 1913 1349 1339 854 -1860 -1424 -4150 -1792 -1697 -1173 -1232 -2334 -1578 -461 -5 937 1803 1812 1416 694 175 -1805 -1221 -934 -439 552 1564 1069 -24 -33 -2325 -1476 -504 -1073 -1607 -472 -846 -56 1171 1326 842 599 -66 -831 -652 -673 -625 534 137 433 535 921 374 1067 -457 -1224 546 143 -34 62 -815 -877 -123 134 -126 471 957 491 329 232 -1091 -784 335 887 476 771 232 150 445 404 250 -114 -79 -715 410 173 496 -39 136 20 -78 515 186 490 484 573 -255 650 -162 -744 -417 -402 -422 -584 507 -582 -1178 -1404 -1172 -604 -46 -42 -661 -627 -630 -154 -471 237 -76 -42 -1319 -217 -185 140 537 832 694 1204 674 232 -39 -527 139 777 1074 2376 711 118 -896 -1421 131 1518 766 1670 1177 1131 684 -1404 -1001 -2914 -1303 -1364 -1036 -1175 -2363 -1649 -499 -5 1091 2130 2134 1628 763 182 -1810 -1214 -977 -495 671 2028 1453 -32 -43 -2874 -1743 -601 -1349 -2104 -633 -1175 -81 1764 2082 1347 944 -100 -1211 -916 -946 -903 797 212 673 818 1375 546 1507 -632 -1653 740 205 -51 98 -1322 -1448 -209 235 -228 862 1762 907 597 408 -1880 -1334 SS 20240102T180059.4Z 8767.750687 441 1 49.53 2 67.19 189.86 106.26 290.08 0.00 1 0.00 1 0 25 3.401e-02 1.112e-02 1.260e-02 1.740e-03 4.087509e-01 8.616907e-04 4.865451e-03 -6.000000e+00 1.910144e-02 222.91 -2.00 3.57 -2.00 318.37 0.00e+00 1.707615e-03 1.688038e-04 4.347398e-04 -6.000000e+00 8.267026e-04 272.76 -2.00 20.00 -2.00 317.84 0.00e+00 2.559 0.000 302.00 328.00 3 3.6687e+00 2.3010e-03 3.2433e-02 -6.0000e+00 4.7096e-02 9.8437e-02 2.6256e-03 2.0640e-02 -6.0000e+00 5.1431e-02 -1.1248e-02 1.8306e-03 1.0570e-02 -6.0000e+00 3.0577e-02 -3.5014e-03 9.7240e-04 3.5388e-03 -6.0000e+00 1.2931e-02 6.2731e-04 4.6207e-04 4.8714e-05 3.4948e-05 -6.0000e+00 9.2399e-04 -1.3201e-03 0.0000e+00 12 8 8 10 0 0 99.99 22.95 0.29 -0.00132 0.00215 46 9 1 5 0 1076.550 26.83 20.00 22.95 6.51 7.5 996.56 -907 14589 8570 8223 -5928 -16346 1208 -1476 -6927 -3801 -10397 -16348 -981 -1150 -1221 165 -1535 -933 -2156 5538 242 5614 2047 3837 -14 2005 745 -8661 -2851 -1459 -1853 -1512 2814 -1875 -4904 -7155 -4614 -1746 1108 502 -1343 -1378 -374 119 37 955 375 -65 -2210 -1528 -213 562 1096 1489 1741 2488 1066 876 -695 -1137 386 1276 1758 3545 1365 189 -966 -2974 374 1560 1485 2220 1669 1219 558 -2360 -1757 -4367 -2329 -2086 -1352 -1080 -2318 -1570 -844 272 655 1716 1794 1637 442 -65 -2045 -1617 -1304 -467 437 1482 1086 96 -153 -2467 -1626 -422 -998 -1467 -483 -839 9 1218 1407 1046 448 -112 -543 -749 -731 -783 574 290 437 816 1179 503 1049 -192 -1171 501 177 15 49 -749 -728 -239 60 -112 541 1083 414 198 -38 -1049 -932 -35 547 357 334 -252 -729 48 -68 -373 -211 -628 -1102 -66 -93 -117 18 -181 -116 -287 718 34 745 286 560 -2 332 125 -1531 -461 -235 -327 -298 592 -428 -1111 -1615 -1092 -465 340 178 -528 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