File name: Pandora170s1_StGeorge_20240222_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20240430T045415.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20240222_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20240222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240222T141526.3Z 8818.594054 314 1 9.00 2 69.82 127.78 110.18 330.68 0.00 1 0.00 1 0 17 1.924e-01 1.534e-02 1.667e-01 9.254e-03 5.232906e-01 4.777197e-03 6.071571e-03 -6.000000e+00 1.102760e-01 224.93 -2.00 3.57 -2.00 319.81 0.00e+00 2.473430e-03 1.447169e-03 1.094336e-03 -6.000000e+00 5.197574e-03 272.52 -2.00 20.00 -2.00 319.32 0.00e+00 2.868 0.000 302.00 328.00 3 4.4468e+00 1.3488e-02 3.9006e-02 -6.0000e+00 2.7411e-01 -8.4405e-03 1.6237e-02 2.6964e-02 -6.0000e+00 2.9937e-01 9.7148e-03 1.4700e-02 1.4932e-02 -6.0000e+00 1.7611e-01 -1.0903e-02 7.7091e-03 5.8938e-03 -6.0000e+00 7.4936e-02 1.9387e-04 1.2496e-03 2.6305e-04 6.0300e-05 -6.0000e+00 5.3514e-03 -7.9505e-03 0.0000e+00 12 9 9 12 9 1 99.76 23.47 0.58 -0.00795 0.00144 3 4 1 5 0 2248.020 27.35 20.00 23.47 14.97 8.2 987.93 -38252 900000 900000 -10417 -42718 -95424 900000 -1361 900000 -79696 900000 -93149 900000 -3772 19720 -25992 -12282 43457 -53534 30032 -20106 85965 8561 26700 -5443 -8260 25275 -38934 9105 -6384 -5829 -10794 35331 -13986 -5561 -4301 -3900 3045 828 14752 -8688 12719 -5509 4293 -6570 3942 3974 5549 -507 -2038 1597 1795 3753 2664 6288 10734 -586 1364 -3913 -2074 -3471 573 -533 8256 -1508 977 -53 699 2761 -1486 3162 906 3220 1189 4399 -2321 2401 -3114 -4704 -2904 -2237 -1844 -2776 -3001 -1478 31 -1295 1693 826 361 1130 27 -953 -1630 -1815 1918 308 543 1669 -66 -244 -2006 -1900 1537 -479 -2248 -137 -1253 307 706 1345 -526 520 -771 -115 275 261 -935 1735 650 55 115 490 1230 726 -56 -1521 1641 518 -650 -65 -62 -251 -852 732 -1841 514 1380 629 -735 183 -651 -365 -454 900000 900000 -119 -614 -2172 900000 -16 900000 -2305 900000 -3486 900000 -92 474 -1119 -519 1189 -3888 1059 -1167 1877 396 1123 -334 -550 1249 -3418 502 -423 -435 -984 2386 -1587 -569 -427 -418 359 121 2220 -1809 2332 -1247 912 -1560 867 884 1239 -123 -524 431 532 1182 905 2169 3683 -228 521 -1533 -791 -1379 238 -248 3881 -797 493 -26 345 1448 -907 2012 608 2108 760 2552 -1304 1211 -1637 -2711 -1874 -1621 -1467 -2376 -2694 -1377 31 -1321 1727 846 360 1061 24 -820 -1425 -1710 1945 350 672 2164 -87 -304 -2345 -2104 1681 -560 -2781 -173 -1666 427 1049 2109 -859 836 -1207 -170 393 376 -1398 2657 1033 88 180 744 1812 1042 -78 -2094 2264 775 -1053 -111 -108 -452 -1598 1415 -3734 1042 2808 1283 -1479 354 -1218 -672 SS 20240222T145809.3Z 8818.623719 335 1 51.26 2 64.12 137.38 113.38 340.41 0.00 1 0.00 1 0 17 1.366e-01 1.011e-02 3.726e-02 2.344e-03 4.206075e-01 1.169530e-03 4.986870e-03 -6.000000e+00 7.728700e-02 224.93 -2.00 3.57 -2.00 318.80 0.00e+00 1.786571e-03 2.596417e-04 1.895165e-04 -6.000000e+00 3.316471e-03 272.52 -2.00 20.00 -2.00 318.27 0.00e+00 2.277 0.000 302.00 328.00 3 4.5642e+00 3.1707e-03 3.1175e-02 -6.0000e+00 1.9143e-01 -3.2770e-02 3.6413e-03 2.1671e-02 -6.0000e+00 2.0876e-01 4.5487e-02 2.7631e-03 1.0984e-02 -6.0000e+00 1.2391e-01 -2.6179e-02 1.4840e-03 3.7267e-03 -6.0000e+00 5.2172e-02 3.4255e-04 7.9199e-05 6.6310e-05 3.6314e-05 -6.0000e+00 3.7119e-03 -1.5516e-03 0.0000e+00 12 8 8 10 0 0 98.05 23.47 0.78 -0.00155 -0.00096 19 4 1 5 0 2696.900 27.35 19.99 23.47 15.92 8.3 987.28 39536 -18353 72276 103404 17762 -3766 60701 10205 2555 29797 10627 -14905 27717 12542 6537 5470 -3282 3203 -9701 -8385 3357 18608 8943 6525 499 5773 2570 -6397 -6282 8677 -3937 -8342 1333 -988 -4130 -5099 -5152 -1382 2103 604 -3036 -2304 -2559 -1395 -2643 -1509 1909 1020 -3149 -473 -95 116 437 1383 2165 3640 -500 1748 -1137 -1768 -607 1179 988 2995 1444 -293 -25 -2157 181 987 1643 2269 1423 1583 1585 -1684 -73 -2156 -1964 -1246 -796 -1072 -2591 -2451 -876 -881 -137 1475 1574 1112 743 -70 54 -578 -96 -166 535 1499 1089 -167 -279 -1539 -1039 -14 -799 -1610 -282 -1273 -986 898 798 169 365 -95 -512 356 -414 -446 933 336 188 -486 462 784 849 -400 -1167 1553 1324 24 18 -675 -504 -109 22 -791 156 893 196 148 90 -629 -451 626 -581 1028 1071 385 -96 884 273 83 803 354 -673 979 619 409 397 -283 278 -1013 -909 337 1629 879 700 61 706 327 -858 -815 995 -557 -1393 228 -181 -756 -921 -1002 -302 531 179 -1023 -818 -943 -519 -1003 -574 707 382 -1233 -186 -40 52 209 693 1120 1911 -277 950 -623 -965 -337 688 627 2004 998 -198 -16 -1415 124 742 1320 1874 1179 1269 1200 -1208 -48 -1423 -1369 -958 -676 -988 -2547 -2503 -924 -975 -157 1702 1812 1252 800 -72 52 -563 -98 -185 643 1929 1472 -227 -363 -1889 -1219 -17 -998 -2101 -377 -1769 -1428 1357 1261 274 582 -146 -754 505 -588 -654 1410 526 297 -759 702 1161 1220 -562 -1605 2131 1924 37 29 -1124 -854 -190 41 -1479 294 1695 374 278 164 -1116 -789 SS 20240222T150409.4Z 8818.627886 338 1 50.35 2 63.39 138.82 113.73 341.82 0.00 1 0.00 1 0 17 1.025e-01 1.009e-02 3.006e-02 2.354e-03 4.141649e-01 1.173434e-03 4.909707e-03 -6.000000e+00 5.801650e-02 224.93 -2.00 3.57 -2.00 318.68 0.00e+00 6.295693e-04 2.515421e-04 1.922149e-04 -6.000000e+00 2.489106e-03 272.52 -2.00 20.00 -2.00 318.16 0.00e+00 2.220 0.000 302.00 328.00 3 4.6194e+00 3.1742e-03 3.0521e-02 -6.0000e+00 1.4370e-01 -2.3132e-02 3.6348e-03 2.1237e-02 -6.0000e+00 1.5669e-01 4.4289e-02 2.7153e-03 1.0710e-02 -6.0000e+00 9.3009e-02 -2.8171e-02 1.4586e-03 3.2254e-03 -6.0000e+00 3.9173e-02 3.4456e-04 2.3672e-04 6.6550e-05 3.3108e-05 -6.0000e+00 2.7856e-03 -3.4642e-03 0.0000e+00 12 8 8 10 0 0 99.97 23.47 0.72 -0.00346 -0.00169 18 4 1 5 0 2796.660 27.35 19.99 23.47 16.09 8.3 987.32 24563 5479 34728 51709 20586 -12396 42054 52388 19220 39538 11642 -9151 31072 18011 5099 9710 -1779 -2192 -8652 9215 1902 12296 14761 7299 2743 7460 4614 -8674 -1389 7286 -3746 -5096 3493 -774 -6548 -5544 -2164 603 2072 -372 -3044 -948 -1765 685 -1861 21 -4373 -180 -4705 -2197 181 -140 -23 1387 1766 -2188 1016 -1890 34 -1960 -556 1858 757 2826 936 295 -13 -1716 833 1589 1381 2173 1863 1709 1798 -1407 666 -2578 -491 -1619 -206 -1216 -2263 -1733 -960 -404 87 1263 1730 1121 725 6 -630 -477 106 18 660 1190 1348 -30 -203 -1382 -1219 -219 -524 -1569 -854 -1405 -500 765 707 168 284 -466 -622 552 -424 -365 765 -506 45 301 285 919 486 -43 -1295 1588 886 -68 123 -725 -389 -83 -168 -822 238 1104 362 353 49 -468 -733 497 153 778 967 477 -377 808 1042 595 1086 429 -436 1174 924 352 733 -163 -215 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