File name: Pandora170s1_StGeorge_20240912_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20240913T051841.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora170_OF_v11d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20240912_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20240912 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240912T121550.9Z 9021.511006 79 1 51.22 2 76.12 98.03 165.19 2.00 0.00 1 0.00 1 0 17 3.634e-01 1.868e-02 1.753e-01 4.997e-03 5.357519e-01 2.618288e-03 6.352974e-03 -6.000000e+00 2.091293e-01 229.25 -2.00 3.57 -2.00 320.35 0.00e+00 2.895371e-03 9.677330e-04 2.023185e-03 -6.000000e+00 9.822561e-03 285.19 -2.00 20.00 -2.00 319.67 0.00e+00 4.074 0.001 302.00 328.00 3 3.9065e+00 7.9603e-03 4.9513e-02 -6.0000e+00 5.2194e-01 3.6495e-02 9.9150e-03 2.9910e-02 -6.0000e+00 5.6668e-01 -7.9767e-02 8.6877e-03 1.5652e-02 -6.0000e+00 3.3722e-01 3.3139e-02 4.3782e-03 4.9832e-03 -6.0000e+00 1.4351e-01 1.0844e-04 -2.3894e-05 1.4321e-04 6.5869e-05 -6.0000e+00 1.0019e-02 4.4319e-03 0.0000e+00 12 9 8 11 32 0 94.11 23.04 0.68 0.00443 0.00425 15 3 1 5 0 3414.080 26.94 20.00 23.04 25.13 11.6 1009.21 61937 900000 -84865 900000 -105108 -148009 111596 -113483 -80711 900000 -104328 -130215 139720 -17279 -7615 16124 288 -30663 -43083 -2550 21330 163119 78066 25715 -5420 33121 35495 -50713 -26343 69129 -32517 -23276 -4854 3629 -1224 -10666 9481 4445 25042 14485 427 5415 -10974 11520 -7522 3635 16495 6514 -10420 57 -1617 4165 619 6748 14509 17695 2060 8869 1978 -9314 9421 2804 -276 6900 5206 5607 582 -4121 31 1089 4191 -2262 5488 1954 1751 -3795 2548 -4967 -4872 -6529 320 -3248 -2125 -3029 148 -4543 -470 4133 2572 1430 -216 -1484 -935 -1046 -3169 -667 337 719 1409 -393 -367 -2428 -1252 -678 -808 -1098 -856 -963 -550 1722 742 -32 -207 -865 -221 1585 -93 -195 1803 613 228 337 -352 1188 1267 -789 -711 2575 1530 -33 513 -1275 -785 -114 -399 -654 174 1289 349 -160 262 -785 -1102 302 900000 -1607 900000 -2199 -4488 544 -2989 -1754 900000 -3168 -5525 680 -380 -188 371 9 -1332 -2265 -97 665 1318 1473 857 -262 1172 1242 -3897 -1581 1761 -2461 -1886 -377 276 -95 -887 709 411 2308 1735 65 845 -2085 1822 -1441 640 2610 1154 -2223 12 -364 981 164 1805 3798 4665 643 2602 606 -3135 2761 951 -107 2759 2191 2288 240 -1805 14 562 2290 -1359 3062 1078 899 -1866 1107 -2304 -2465 -3849 202 -2354 -1638 -2477 125 -4209 -440 3825 2406 1309 -190 -1237 -743 -845 -2830 -653 365 855 1772 -499 -443 -2745 -1330 -729 -922 -1317 -1067 -1262 -765 2542 1176 -53 -338 -1369 -333 2272 -136 -295 2822 1001 373 539 -552 1794 1856 -1136 -998 3629 2353 -56 909 -2371 -1498 -226 -828 -1405 378 2809 763 -344 541 -1568 -2179 SS 20240912T123617.8Z 9021.525206 85 1 50.14 2 72.48 101.75 164.57 18.15 0.00 1 0.00 1 0 17 3.905e-02 8.293e-03 2.157e-02 1.388e-03 4.476803e-01 7.056863e-04 5.257032e-03 -6.000000e+00 2.245823e-02 229.25 -2.00 3.57 -2.00 319.23 0.00e+00 1.271179e-03 1.841258e-04 6.764791e-04 -6.000000e+00 9.996278e-04 285.19 -2.00 20.00 -2.00 318.48 0.00e+00 3.275 0.001 302.00 328.00 3 2.5309e+00 1.9844e-03 3.9932e-02 -6.0000e+00 5.5948e-02 -2.8071e-02 2.3233e-03 2.3709e-02 -6.0000e+00 6.0706e-02 2.1740e-02 1.7876e-03 1.1783e-02 -6.0000e+00 3.6177e-02 -1.7194e-02 9.4193e-04 3.4777e-03 -6.0000e+00 1.5257e-02 1.0122e-03 7.6082e-05 3.9314e-05 3.6030e-05 -6.0000e+00 1.0634e-03 4.5418e-03 0.0000e+00 11 8 0 10 0 0 93.53 23.04 0.39 0.00454 0.00511 94 19 1 5 0 533.250 26.94 19.99 23.04 26.16 11.6 1014.14 3531 14272 9819 13108 9548 -19564 11209 6972 1993 -5756 -8629 -18189 6077 6019 2947 2361 -2551 2980 -3734 2703 -230 780 2685 3318 -701 1392 1366 -7720 -1791 -2145 -62 -2790 3524 -3119 -7418 -5956 -5137 -2762 -214 -2812 -1988 -723 -1686 -513 -1234 125 1936 -886 -2023 -849 495 173 1697 1021 1120 2243 513 598 -490 -641 525 1721 1561 3738 917 -206 -685 -2195 1009 1447 929 1571 1134 1577 560 -751 -941 -2698 -1413 -1440 -1652 -856 -2552 -1831 -966 -558 607 1165 1477 1100 922 88 -583 -307 -199 -187 501 1247 711 -6 -293 -2069 -1152 51 -1123 -1638 -616 -1039 -59 643 904 435 370 -163 -177 -101 148 -76 752 226 -191 358 586 488 650 -400 -784 1125 450 0 67 -914 -520 -188 -73 -258 203 692 322 111 232 -831 -378 56 236 181 228 171 -418 204 140 48 -161 -257 -642 199 243 148 138 -173 206 -275 197 -18 60 211 279 -67 137 136 -811 -171 -211 -7 -355 475 -474 -1137 -884 -824 -515 -48 -710 -557 -214 -526 -161 -396 40 612 -290 -680 -294 183 66 694 450 517 1063 254 296 -240 -311 260 920 876 2244 582 -127 -401 -1310 637 981 696 1223 882 1167 387 -501 -577 -1655 -927 -1032 -1363 -744 -2442 -1747 -977 -601 651 1280 1612 1161 953 85 -556 -293 -196 -209 601 1586 932 -8 -375 -2562 -1329 60 -1369 -2127 -832 -1424 -86 976 1414 705 587 -256 -258 -146 214 -111 1164 354 -302 573 906 728 967 -574 -1085 1573 667 0 112 -1552 -912 -347 -137 -494 397 1367 639 214 441 -1517 -701 SS 20240912T124323.2Z 9021.530130 89 1 50.03 2 71.23 103.06 164.13 23.37 0.00 1 0.00 1 0 17 2.417e-02 8.189e-03 1.099e-02 1.035e-03 4.215940e-01 5.245768e-04 4.973888e-03 -6.000000e+00 1.390088e-02 229.25 -2.00 3.57 -2.00 318.91 0.00e+00 9.322413e-04 1.229613e-04 5.670181e-04 -6.000000e+00 6.187398e-04 285.19 -2.00 20.00 -2.00 318.15 0.00e+00 3.070 0.001 302.00 328.00 3 2.2378e+00 1.4487e-03 3.7458e-02 -6.0000e+00 3.4630e-02 -2.5045e-02 1.6758e-03 2.2244e-02 -6.0000e+00 3.7575e-02 1.2135e-02 1.2116e-03 1.0950e-02 -6.0000e+00 2.2392e-02 -1.3314e-02 6.3833e-04 3.1174e-03 -6.0000e+00 9.4435e-03 1.7037e-03 1.2618e-05 2.9419e-05 3.2549e-05 -6.0000e+00 6.5822e-04 4.5872e-03 0.0000e+00 11 8 0 10 0 0 -14.39 23.04 0.38 0.00459 0.00468 127 25 1 5 0 393.810 26.94 20.00 23.04 26.63 11.7 1017.37 11727 -1041 1200 1692 -2579 -10600 2386 7818 -4492 -4441 -5769 -9086 2832 792 3249 1551 -884 1128 -1771 2541 816 214 1929 2473 -812 1111 -269 -5395 -2338 -2237 -353 -247 1896 -1035 -5954 -6452 -5007 -3063 -273 -2182 -1485 -801 -1264 -757 -360 -82 419 -254 -1772 -768 782 738 833 1497 1112 1919 1116 821 -281 -481 674 1788 2040 3171 1001 -211 -736 -1756 855 1235 1014 1381 850 1211 592 -436 -1092 -2728 -1065 -1058 -1305 -1049 -2642 -1706 -949 -582 526 1133 1404 993 926 240 -867 -350 -255 -321 386 1231 677 -171 -525 -2001 -1296 59 -1059 -1578 -758 -1177 -170 706 857 524 538 35 -308 -20 140 -93 694 97 -52 381 650 291 802 -158 -650 998 409 208 84 -856 -483 -188 84 -328 167 657 233 27 204 -783 -449 257 -30 36 48 -70 -301 63 226 -167 -177 -240 -417 135 47 206 115 -74 99 -170 246 83 22 201 275 -101 143 -35 -720 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