File name: Pandora170s1_StGeorge_20241130_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20241201T051305.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora170_OF_v11d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20241130_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20241130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241130T151146.8Z 9100.633181 137 1 1.03 2 70.54 151.79 71.64 160.64 0.00 1 0.00 1 0 17 7.698e-02 1.080e-02 8.668e-02 6.805e-03 4.732406e-01 3.373121e-03 5.643761e-03 -6.000000e+00 4.314904e-02 222.39 -2.00 3.57 -2.00 318.90 0.00e+00 2.238277e-03 7.881871e-04 2.816160e-04 -6.000000e+00 1.892413e-03 275.49 -2.00 20.00 -2.00 318.33 0.00e+00 2.968 0.000 302.00 328.00 3 1.8441e+00 9.1676e-03 3.7719e-02 -6.0000e+00 1.0617e-01 7.2075e-03 1.0593e-02 2.4159e-02 -6.0000e+00 1.1594e-01 -1.2207e-02 8.0800e-03 1.2318e-02 -6.0000e+00 6.9065e-02 -1.9422e-03 4.3344e-03 4.2378e-03 -6.0000e+00 2.9299e-02 2.5640e-03 -3.5211e-04 1.8769e-04 4.2358e-05 -6.0000e+00 2.0918e-03 1.1095e-03 0.0000e+00 12 9 9 12 1 1 999.00 22.71 0.29 0.00111 -0.00154 2 29 1 5 0 341.790 26.62 19.99 22.71 5.47 12.6 992.91 2706 -15146 5703 12736 1700 -21632 48265 -43278 14776 -10767 119 -15163 17858 -8313 -1072 15927 -9644 18710 -6476 9006 -17482 9405 2114 -5701 2191 2444 10195 -6287 1770 -14274 -1575 -2573 4599 -2826 -10379 -2607 -6068 3141 -4019 147 -3744 -630 -1786 92 -1426 399 2751 148 1293 -1191 2273 -437 3825 1076 663 1192 2508 804 -1329 1360 280 3036 857 2107 321 -436 867 -1662 1104 1450 1720 642 1853 -593 532 -2016 -1471 -3719 -1798 -714 -1635 -772 -2165 -1806 -1411 -379 1395 1156 1262 607 1312 781 784 -1150 51 -796 -206 5 944 382 -512 -1991 -1421 474 -1492 -1010 -241 -1147 -782 134 1670 356 1001 -84 -384 -965 658 -229 1144 47 -855 302 232 657 1333 -229 -1125 1856 12 1012 533 -812 -840 -60 440 -794 295 365 486 -218 563 -521 -1144 55 -416 138 284 39 -588 725 -1707 384 -379 4 -619 635 -459 -67 980 -825 1329 -618 784 -1989 843 208 -641 247 289 1135 -790 202 -1924 -210 -396 744 -514 -1964 -452 -1161 641 -1032 42 -1214 -211 -626 32 -513 143 976 54 476 -462 914 -194 1748 529 339 624 1324 430 -710 706 150 1697 528 1375 218 -290 551 -1080 746 1072 1355 524 1496 -472 398 -1428 -980 -2487 -1257 -548 -1389 -704 -2097 -1811 -1468 -409 1538 1302 1418 669 1380 784 757 -1127 52 -889 -248 6 1266 513 -665 -2451 -1673 558 -1857 -1299 -318 -1572 -1117 201 2598 570 1581 -130 -569 -1394 943 -338 1740 75 -1355 468 353 977 1924 -326 -1569 2588 18 1589 875 -1374 -1451 -106 805 -1501 562 701 933 -412 1031 -932 -2030 SS 20241130T152208.0Z 9100.640371 144 1 3.10 2 69.69 154.18 71.10 162.98 0.00 1 0.00 1 0 17 1.785e-01 1.526e-02 1.355e-01 9.792e-03 4.578013e-01 4.856210e-03 5.429588e-03 -6.000000e+00 1.000783e-01 222.39 -2.00 3.57 -2.00 318.93 0.00e+00 3.749445e-03 1.145837e-03 2.588529e-04 -6.000000e+00 4.389252e-03 275.49 -2.00 20.00 -2.00 318.37 0.00e+00 2.852 0.000 302.00 328.00 3 3.4055e+00 1.3216e-02 3.6424e-02 -6.0000e+00 2.4624e-01 3.1932e-02 1.5289e-02 2.3907e-02 -6.0000e+00 2.6891e-01 -6.6552e-03 1.1589e-02 1.1994e-02 -6.0000e+00 1.6019e-01 -7.1509e-03 6.1804e-03 5.2426e-03 -6.0000e+00 6.7953e-02 5.9841e-04 1.2520e-04 2.7175e-04 4.6476e-05 -6.0000e+00 4.8518e-03 1.2352e-03 0.0000e+00 12 9 9 12 1 1 999.00 22.71 0.38 0.00124 0.00218 1 6 1 5 0 1542.540 26.62 20.00 22.71 5.85 12.6 992.99 -50266 -104291 -26645 -6933 -56854 124695 3339 56653 -26469 -17082 -17106 -41270 7479 -13092 -3134 -2782 1306 39364 -677 -275 9649 36738 -2898 8636 -5361 8412 -1110 -12240 7514 9900 1960 -9817 5033 350 -2899 -4187 -1304 -3515 -1075 -1829 1317 1812 853 -981 -130 -125 -150 946 -2057 -4666 1676 1135 4306 -1068 2579 3580 2249 1217 -838 -2505 697 4365 3673 5719 1865 234 -106 -1405 387 113 -670 3114 1470 -289 -39 -1334 2 -4606 -1320 -3511 -1030 -486 -3787 -2388 -2461 -341 -654 2579 790 1633 484 3 -1062 740 -1531 -956 1621 1952 1794 -296 170 -3020 -824 -98 -751 -1002 -1030 -326 -1183 -420 530 352 677 -109 -135 -1355 74 -1025 1020 -312 -493 1287 698 843 1298 1248 -1276 1370 2101 492 820 -916 -151 -400 -66 -228 84 989 1233 -574 328 -1571 -1770 -1681 -6667 -881 -187 -2256 1191 76 877 -993 -625 -644 -2095 286 -746 -197 -202 100 2287 -61 -26 851 2527 -293 834 -628 909 -132 -1570 787 1045 248 -1581 795 61 -502 -717 -234 -744 -264 -522 402 583 287 -343 -46 -44 -54 340 -768 -1838 669 491 1938 -528 1285 1814 1171 637 -438 -1319 368 2397 2207 3629 1246 154 -67 -901 260 84 -535 2496 1186 -229 -29 -928 1 -3051 -907 -2725 -868 -441 -3708 -2406 -2585 -370 -734 2893 895 1794 511 3 -1029 711 -1581 -1067 1935 2500 2407 -400 220 -3734 -964 -115 -932 -1291 -1369 -447 -1704 -637 837 566 1076 -168 -200 -1956 106 -1522 1554 -492 -782 1986 1059 1251 1869 1749 -1772 1907 3085 775 1343 -1550 -260 -711 -121 -430 161 1899 2363 -1090 602 -2828 -3156 SS 20241130T153010.1Z 9100.645950 150 1 31.43 2 69.08 156.07 70.72 164.81 0.00 1 0.00 1 0 17 1.833e-01 1.269e-02 9.328e-02 4.185e-03 4.379883e-01 2.078065e-03 5.191714e-03 -6.000000e+00 1.027385e-01 222.39 -2.00 3.57 -2.00 319.15 0.00e+00 1.322735e-03 5.222020e-04 5.248606e-04 -6.000000e+00 4.505680e-03 275.49 -2.00 20.00 -2.00 318.58 0.00e+00 2.774 0.000 302.00 328.00 3 4.5454e+00 5.7086e-03 3.5097e-02 -6.0000e+00 2.5279e-01 -1.2216e-02 6.6566e-03 2.2316e-02 -6.0000e+00 2.7605e-01 2.4891e-02 5.2875e-03 1.1520e-02 -6.0000e+00 1.6444e-01 -1.6042e-02 2.8270e-03 3.7421e-03 -6.0000e+00 6.9762e-02 2.1589e-04 2.2181e-04 1.1845e-04 3.8709e-05 -6.0000e+00 4.9805e-03 8.3592e-04 0.0000e+00 12 9 9 12 33 1 99.91 22.71 0.50 0.00084 0.00250 8 3 1 5 0 3488.010 26.62 20.00 22.71 6.04 12.6 992.91 15978 80867 18536 142176 -17095 -46549 12826 37243 26663 89808 -2860 -20157 38492 -4749 -9490 17500 -17557 -9533 -5967 11787 3379 30056 16618 6841 -666 13073 5035 -5741 -13604 14406 -9300 -9156 3819 -642 -1427 -7909 -3393 -680 7534 -12819 -2468 -861 -2183 2811 -5716 857 4868 -746 -4016 -572 -329 2427 -537 105 3856 5204 -783 360 -180 -2520 15 2394 -351 3159 1823 1720 797 -2619 -816 1925 1765 3163 2076 1533 2554 -1955 63 -4174 -4198 -2806 -790 -1404 -1739 -2287 -695 -111 136 2070 1658 1215 110 -432 -1375 -1028 -1353 -57 1458 891 386 -471 14 -2606 -1520 683 -1129 -905 233 -1363 -393 959 1226 445 151 -103 -490 567 -902 -362 1250 -572 20 349 944 329 648 -166 -1458 1449 603 553 495 -1519 153 -445 -295 -173 -45 1527 92 403 115 -911 -959 256 809 354 825 -412 -1424 238 627 560 1119 -88 -779 1006 -226 -566 930 -1420 -766 -495 870 278 1937 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