File name: Pandora170s1_StGeorge_20241206_L2Fit_fwvt1c8d20220508p1-8.txt File generation date: 20241207T051535.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora170_OF_v11d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20241206_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20241206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1633 1782 Nominal wavelengths inside fitting window [nm]: 492.0081 492.1294 492.2507 492.3720 492.4932 492.6145 492.7357 492.8569 492.9781 493.0993 493.2204 493.3416 493.4627 493.5838 493.7049 493.8260 493.9470 494.0681 494.1891 494.3101 494.4311 494.5521 494.6730 494.7940 494.9149 495.0358 495.1567 495.2776 495.3984 495.5193 495.6401 495.7609 495.8817 496.0025 496.1232 496.2440 496.3647 496.4854 496.6061 496.7268 496.8474 496.9681 497.0887 497.2093 497.3299 497.4505 497.5710 497.6915 497.8121 497.9326 498.0531 498.1735 498.2940 498.4144 498.5348 498.6552 498.7756 498.8960 499.0164 499.1367 499.2570 499.3773 499.4976 499.6179 499.7381 499.8584 499.9786 500.0988 500.2190 500.3391 500.4593 500.5794 500.6995 500.8196 500.9397 501.0598 501.1798 501.2999 501.4199 501.5399 501.6598 501.7798 501.8998 502.0197 502.1396 502.2595 502.3794 502.4992 502.6191 502.7389 502.8587 502.9785 503.0983 503.2180 503.3378 503.4575 503.5772 503.6969 503.8166 503.9362 504.0559 504.1755 504.2951 504.4147 504.5343 504.6538 504.7733 504.8929 505.0124 505.1319 505.2513 505.3708 505.4902 505.6096 505.7290 505.8484 505.9678 506.0871 506.2064 506.3258 506.4451 506.5643 506.6836 506.8028 506.9221 507.0413 507.1605 507.2796 507.3988 507.5179 507.6371 507.7562 507.8753 507.9943 508.1134 508.2324 508.3514 508.4705 508.5894 508.7084 508.8274 508.9463 509.0652 509.1841 509.3030 509.4219 509.5407 509.6595 509.7783 509.8971 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241206T131258.0Z 9106.550671 70 1 51.56 2 85.46 127.46 130.28 77.72 0.00 1 0.00 1 0 15 4.518e-03 4.477e-03 1.002e-03 1.001e-03 2.729815e+03 5.542500e+01 2.107244e+02 -6.000000e+00 2.312414e+02 274.82 -2.00 20.00 -2.00 505.30 0.00e+00 3.183485e-03 2.655556e-05 1.691607e-04 -6.000000e+00 1.223265e-04 274.82 -2.00 20.00 -2.00 500.65 0.00e+00 9.117441e-01 1.921998e-02 3.211957e-02 -6.000000e+00 8.797943e-02 222.31 -2.00 3.57 -2.00 502.21 0.00e+00 10.555 0.023 489.00 513.00 1 6.1301e+00 1.4625e-03 1.5875e-02 -6.0000e+00 6.6993e-03 7.7184e-03 3.8619e-04 9.9821e-04 -6.0000e+00 1.7893e-03 8.7303e-04 2.3007e-03 8.2521e-05 5.7773e-05 -6.0000e+00 3.8147e-04 1.8991e-02 -2.7875e-04 11 8 0 10 0 0 98.53 22.57 1.36 0.01899 0.03495 14 3 1 4 0 3682.250 26.51 20.00 22.57 -0.28 12.3 1001.93 900000 -919 -428 -381 -222 314 1015 729 623 198 331 -122 -152 -284 -230 -724 -770 329 135 189 413 -41 -65 634 265 -8 609 478 350 -505 -424 -804 -439 238 531 429 384 203 -293 -42 -431 -350 -196 29 215 438 261 77 1006 183 -392 -456 -868 -962 -550 -158 145 330 194 -17 401 129 422 601 311 -43 182 23 -201 -475 -328 -535 -464 -144 69 9 -387 -348 -481 -906 -588 -350 -434 -183 -308 5 -92 -384 55 20 -28 2 621 370 446 406 451 -114 -367 -609 -1121 -1132 -522 130 -289 -144 -108 -473 -49 -189 -116 -249 301 393 456 904 888 703 640 693 366 16 401 201 -15 226 18 142 568 386 -98 158 243 -499 -794 -277 143 -72 281 204 275 219 -228 83 482 487 -443 -458 -825 -679 900000 -849 -406 -365 -220 316 1037 737 632 199 328 -123 -152 -278 -223 -705 -758 327 135 193 421 -42 -66 647 274 -9 630 492 354 -496 -416 -788 -435 236 533 439 390 204 -300 -42 -438 -359 -198 30 222 456 271 80 1014 182 -392 -442 -829 -920 -539 -160 147 339 200 -17 409 133 437 624 322 -44 183 23 -197 -462 -323 -528 -462 -141 68 9 -379 -343 -468 -883 -572 -343 -429 -176 -301 5 -91 -379 54 19 -27 2 616 372 446 410 446 -110 -357 -580 -1059 -1080 -495 128 -288 -144 -106 -472 -48 -187 -114 -250 306 405 460 912 904 722 654 697 373 16 398 202 -16 230 18 145 576 383 -98 158 239 -486 -772 -271 144 -72 284 209 284 226 -238 85 491 494 -458 -459 -808 -679 SQ 20241206T132405.8Z 9106.558401 73 1 12.44 2 83.89 129.50 128.37 79.84 0.00 1 0.00 1 0 15 4.707e-03 4.661e-03 4.277e-04 4.273e-04 2.005200e+03 2.312765e+01 1.489542e+02 -6.000000e+00 2.409585e+02 274.82 -2.00 20.00 -2.00 505.30 0.00e+00 2.458257e-03 1.134553e-05 1.331022e-04 -6.000000e+00 1.274095e-04 274.82 -2.00 20.00 -2.00 500.68 0.00e+00 7.071304e-01 8.177433e-03 2.591317e-02 -6.000000e+00 9.156089e-02 222.31 -2.00 3.57 -2.00 502.23 0.00e+00 8.429 0.012 489.00 513.00 1 3.3953e+00 6.2226e-04 1.2512e-02 -6.0000e+00 6.9738e-03 -6.8614e-03 1.6469e-04 7.8700e-04 -6.0000e+00 1.8593e-03 1.8586e-02 3.2992e-04 3.5250e-05 4.4033e-05 -6.0000e+00 3.9697e-04 3.2930e-03 -9.0445e-05 12 9 9 12 1 1 99.95 22.57 1.14 0.00329 0.00558 41 34 1 4 0 296.050 26.41 20.00 22.57 -0.11 12.1 1001.82 900000 -1188 -650 -188 14 430 720 769 691 527 394 222 -136 -272 -407 -530 -451 -80 267 202 268 225 70 262 328 448 505 522 -30 -438 -763 -918 -796 46 416 457 453 235 -19 -313 -180 -282 17 201 390 435 447 464 362 -61 -438 -860 -1172 -1130 -633 -236 112 310 222 304 183 411 401 574 591 268 167 62 -175 -441 -519 -529 -439 6 152 13 -185 -326 -606 -727 -643 -578 -642 -304 -228 -126 -236 -129 -267 -274 -255 146 498 443 508 441 278 -67 -378 -749 -1023 -1043 -531 38 94 54 -35 -463 -466 -210 -224 16 411 465 623 818 921 915 698 573 184 -74 69 249 168 305 361 67 299 470 175 42 -111 -588 -676 -356 -150 -110 197 171 78 250 348 359 441 289 -59 -562 -749 -854 900000 -1124 -619 -183 13 430 720 782 706 535 392 223 -135 -266 -402 -523 -441 -80 268 204 271 228 71 267 336 461 519 533 -30 -434 -749 -898 -775 47 427 469 461 237 -20 -315 -181 -286 18 205 403 445 457 477 367 -61 -432 -841 -1128 -1088 -623 -236 113 318 224 311 187 415 408 585 598 273 167 61 -175 -436 -506 -516 -433 6 151 13 -181 -318 -585 -700 -621 -564 -631 -300 -224 -125 -235 -128 -265 -273 -255 145 504 447 517 442 274 -66 -368 -714 -966 -995 -511 38 94 54 -36 -460 -456 -206 -225 16 419 472 637 838 950 934 722 583 185 -75 68 251 168 306 362 67 299 471 176 42 -109 -573 -667 -348 -148 -112 198 174 80 257 359 367 453 296 -60 -570 -742 -842 SQ 20241206T134625.9Z 9106.573911 80 1 7.47 2 80.87 133.72 124.50 83.89 0.00 1 0.00 1 0 15 4.043e-03 4.011e-03 1.078e-04 1.077e-04 1.440635e+03 5.716438e+00 1.107571e+02 -6.000000e+00 2.069639e+02 274.81 -2.00 20.00 -2.00 505.28 0.00e+00 1.655330e-03 2.853650e-06 9.012655e-05 -6.000000e+00 1.094336e-04 274.81 -2.00 20.00 -2.00 500.61 0.00e+00 4.886581e-01 2.065143e-03 1.755991e-02 -6.000000e+00 7.863642e-02 222.31 -2.00 3.57 -2.00 502.17 0.00e+00 5.985 0.004 489.00 513.00 1 2.8985e-01 1.5717e-04 8.7906e-03 -6.0000e+00 5.9895e-03 -2.8988e-03 4.1736e-05 5.5240e-04 -6.0000e+00 1.5967e-03 5.9986e-01 2.1882e-04 8.8933e-06 3.0801e-05 -6.0000e+00 3.4096e-04 1.2103e-03 -6.9594e-05 11 8 0 10 0 0 84.42 22.56 1.06 0.00121 0.00273 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