File name: Pandora81s1_StocktonIL_20250627_L2Fit_fout2c2d20240325p1-8.txt
File generation date: 20250628T060905.3Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c2p1-8
Local principal investigator: Kevin Mishoe
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 81
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora81_OF_v5d20230613.txt
Instrument calibration file used: Pandora81s1_CF_v2d20240325.txt
Level 1 file used: Pandora81s1_StocktonIL_20250627_L1_smca1c2d20240325p1-8.txt
Full location name: CASTNET Site STK138
Short location name: StocktonIL
Country of location: United States
Location latitude [deg]: 42.2872
Location longitude [deg]: -90.0000
Location altitude [m]: 281
Local noon date: 20250627
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based off of session 1 lab analysis
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1283 305.2686 305.4090 305.5494 305.6897 305.8300 305.9703 306.1106 306.2509 306.3912 306.5315 306.6717 306.8120 306.9522 307.0924 307.2327 307.3729 307.5131 307.6532 307.7934 307.9336 308.0737 308.2139 308.3540 308.4941 308.6342 308.7743 308.9144 309.0544 309.1945 309.3345 309.4746 309.6146 309.7546 309.8946 310.0346 310.1746 310.3146 310.4545 310.5945 310.7344 310.8743 311.0142 311.1541 311.2940 311.4339 311.5738 311.7136 311.8535 311.9933 312.1331 312.2729 312.4128 312.5525 312.6923 312.8321 312.9718 313.1116 313.2513 313.3910 313.5307 313.6704 313.8101 313.9498 314.0895 314.2291 314.3688 314.5084 314.6480 314.7876 314.9272 315.0668 315.2064 315.3460 315.4855 315.6250 315.7646 315.9041 316.0436 316.1831 316.3226 316.4621 316.6015 316.7410 316.8804 317.0198 317.1592 317.2986 317.4380 317.5774 317.7168 317.8561 317.9955 318.1348 318.2742 318.4135 318.5528 318.6921 318.8313 318.9706 319.1099 319.2491 319.3883 319.5276 319.6668 319.8060 319.9452 320.0843 320.2235 320.3626 320.5018 320.6409 320.7800 320.9191 321.0582 321.1973 321.3364 321.4755 321.6145 321.7535 321.8926 322.0316 322.1706 322.3096 322.4486 322.5875 322.7265 322.8654 323.0044 323.1433 323.2822 323.4211 323.5600 323.6989 323.8377 323.9766 324.1154 324.2542 324.3931 324.5319 324.6707 324.8094 324.9482
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250627T142726.9Z 9309.602394 170 1 22.34 2 48.24 95.48 72.59 75.75 0.00 1 0.00 1 0 17 9.401e-03 6.082e-03 2.322e-03 1.411e-03 2.061018e-01 7.316499e-04 2.484831e-03 -6.000000e+00 5.447069e-03 232.81 -2.00 3.53 -2.00 315.50 0.00e+00 2.311386e-04 6.922686e-05 3.121641e-05 -6.000000e+00 2.393888e-04 285.62 -2.00 20.00 -2.00 314.81 0.00e+00 1.499 0.000 302.00 328.00 3 4.7548e+00 1.9039e-03 1.8224e-02 -6.0000e+00 1.3687e-02 1.3170e-02 2.1144e-03 1.0826e-02 -6.0000e+00 1.4806e-02 2.4705e-03 1.2078e-03 5.2307e-03 -6.0000e+00 8.7962e-03 -2.7063e-03 5.3889e-04 1.4290e-03 -6.0000e+00 3.7135e-03 8.4708e-04 3.3002e-04 3.9733e-05 1.8142e-05 -6.0000e+00 2.5385e-04 6.1311e-03 1.0800e-04 12 1 1 12 1 1 99.99 26.79 0.28 0.00613 0.00861 36 9 1 5 0 603.520 34.75 20.07 26.79 31.06 0.9 991.58 -1826 -2655 -1170 -3208 -3173 -1794 -620 2717 178 -2231 -1500 8 560 2196 179 36 597 617 986 243 353 1326 1592 1047 108 -412 10 -792 -553 759 721 2296 1138 -832 -2347 -1817 -1368 -478 -189 -506 -552 -7 -524 -981 -278 -734 310 -379 -941 282 430 940 607 642 1039 1318 613 233 109 360 936 1363 1455 978 2 -226 -469 -245 548 642 387 -102 162 -78 -208 -304 -643 -913 -732 -681 -1100 -1355 -1754 -1208 -808 -798 -650 37 50 190 537 258 622 657 505 402 895 573 96 -156 -252 -313 -588 91 -742 -962 -547 -564 -148 -21 390 238 345 -41 88 -23 116 11 242 362 -24 343 392 321 293 563 761 772 663 502 67 -78 -302 -7 -250 -367 82 -33 -85 -154 -291 -296 -512 -489 -750 -318 -863 -770 -432 -161 766 51 -663 -431 2 187 815 70 15 250 267 438 112 163 601 746 519 52 -205 5 -379 -247 337 339 1131 562 -410 -1170 -922 -720 -274 -129 -369 -403 -5 -403 -757 -212 -557 240 -286 -694 208 336 728 496 547 900 1093 518 195 95 314 802 1253 1362 958 2 -207 -400 -218 495 620 404 -105 164 -80 -198 -273 -556 -758 -644 -635 -1085 -1391 -1907 -1371 -936 -943 -806 47 64 228 618 284 656 675 524 437 1072 723 121 -201 -303 -365 -658 106 -909 -1240 -702 -757 -198 -29 574 350 483 -56 114 -28 142 14 318 507 -33 466 542 424 383 698 936 954 831 669 90 -107 -420 -10 -366 -543 124 -51 -132 -234 -430 -441 -748
SS 20250627T144604.8Z 9309.615334 176 1 54.83 2 44.82 99.03 69.37 78.55 0.00 1 0.00 1 0 17 7.214e-03 5.606e-03 1.821e-04 1.313e-04 1.930547e-01 6.835139e-05 2.339362e-03 -6.000000e+00 4.179682e-03 232.81 -2.00 3.53 -2.00 314.77 0.00e+00 2.028009e-04 5.574491e-06 1.795144e-05 -6.000000e+00 1.837019e-04 285.62 -2.00 20.00 -2.00 314.13 0.00e+00 1.408 0.000 302.00 328.00 3 1.1811e+00 1.7660e-04 1.7095e-02 -6.0000e+00 1.0503e-02 -7.3046e-03 1.9554e-04 1.0134e-02 -6.0000e+00 1.1362e-02 2.9581e-03 1.1164e-04 4.8994e-03 -6.0000e+00 6.7499e-03 -2.7119e-03 4.8496e-05 1.3386e-03 -6.0000e+00 2.8493e-03 3.4050e-02 1.5524e-04 3.6645e-06 1.7971e-05 -6.0000e+00 1.9482e-04 6.4332e-03 8.2568e-05 10 0 0 10 0 0 99.95 26.83 0.38 0.00643 0.00760 2037 192 1 5 0 26.910 34.75 19.96 26.83 31.70 0.9 997.92 -755 -567 -1613 -2561 -2188 -1180 22 948 521 -532 -808 -477 -63 460 447 -26 292 682 959 1131 699 1129 955 453 90 184 115 -131 181 936 1128 1515 777 -1213 -1714 -1561 -1151 -405 -168 -561 -797 -702 -763 -683 -463 -540 -589 -590 -412 360 612 834 853 824 801 798 581 572 493 639 935 1102 1309 840 8 -146 -368 -118 524 420 353 -38 -28 16 -144 -285 -547 -571 -382 -715 -892 -1340 -1837 -1366 -1031 -795 -512 -86 154 206 414 376 495 723 550 461 561 492 -12 -149 -223 -436 -191 -58 -584 -675 -642 -467 -44 118 326 145 177 38 45 298 158 273 228 50 -90 50 270 364 474 423 684 799 562 379 97 84 -130 30 -82 -223 -37 -39 -186 -301 -289 -327 -436 -272 -213 -597 -898 -730 -392 8 356 202 -209 -310 -192 -27 209 215 -13 151 347 502 609 377 603 529 254 52 106 67 -73 94 483 612 833 459 -713 -978 -871 -689 -262 -120 -429 -629 -571 -634 -566 -381 -441 -480 -464 -325 285 495 690 717 723 696 704 520 506 429 558 850 1046 1260 845 8 -137 -330 -104 483 413 365 -39 -29 16 -139 -261 -483 -497 -341 -677 -890 -1392 -1972 -1493 -1180 -950 -626 -105 188 245 472 408 516 731 575 504 646 596 -15 -183 -269 -500 -214 -67 -703 -837 -814 -603 -59 160 452 201 243 50 56 362 193 340 294 67 -122 66 360 473 594 517 829 971 692 484 128 113 -173 41 -115 -322 -54 -58 -274 -441 -419 -469 -613
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