File name: Pandora123s1_StonyPlain_20190602_L2Fit_fwvt1c1d20190501p1-8.txt File generation date: 20250129T002326.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 123 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora123_OF_v3d20161109.txt Instrument calibration file used: Pandora123s1_CF_v1d20190501.txt Level 1 file used: Pandora123s1_StonyPlain_20190602_L1_smca1c1d20190501p1-8.txt Full location name: Stony Plain Upper Air Station (CWSE) Short location name: StonyPlain Country of location: Canada Location latitude [deg]: 53.5500 Location longitude [deg]: -114.1100 Location altitude [m]: 766 Local noon date: 20190602 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial fieldcal based on session 3 First and last pixel inside fitting window: 1635 1784 Nominal wavelengths inside fitting window [nm]: 492.0766 492.1981 492.3195 492.4409 492.5623 492.6837 492.8051 492.9264 493.0477 493.1691 493.2903 493.4116 493.5329 493.6541 493.7754 493.8966 494.0178 494.1390 494.2601 494.3813 494.5024 494.6235 494.7446 494.8657 494.9867 495.1078 495.2288 495.3498 495.4708 495.5918 495.7128 495.8337 495.9547 496.0756 496.1965 496.3173 496.4382 496.5591 496.6799 496.8007 496.9215 497.0423 497.1630 497.2838 497.4045 497.5252 497.6459 497.7666 497.8873 498.0079 498.1285 498.2492 498.3697 498.4903 498.6109 498.7314 498.8520 498.9725 499.0930 499.2135 499.3339 499.4544 499.5748 499.6952 499.8156 499.9360 500.0563 500.1767 500.2970 500.4173 500.5376 500.6579 500.7782 500.8984 501.0186 501.1388 501.2590 501.3792 501.4994 501.6195 501.7396 501.8598 501.9799 502.0999 502.2200 502.3400 502.4601 502.5801 502.7001 502.8200 502.9400 503.0599 503.1799 503.2998 503.4197 503.5395 503.6594 503.7792 503.8991 504.0189 504.1387 504.2584 504.3782 504.4979 504.6177 504.7374 504.8571 504.9767 505.0964 505.2160 505.3357 505.4553 505.5749 505.6944 505.8140 505.9335 506.0530 506.1725 506.2920 506.4115 506.5310 506.6504 506.7698 506.8892 507.0086 507.1280 507.2473 507.3667 507.4860 507.6053 507.7246 507.8438 507.9631 508.0823 508.2016 508.3208 508.4399 508.5591 508.6783 508.7974 508.9165 509.0356 509.1547 509.2738 509.3928 509.5118 509.6308 509.7498 509.8688 509.9878 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190602T112144.0Z 7092.473426 298 1 32.01 2 89.85 50.81 89.93 63.33 0.00 1 0.00 1 0 22 7.484e-02 7.235e-02 1.524e-02 1.503e-02 1.194754e+04 1.115232e+03 8.601716e+02 -6.000000e+00 4.219103e+03 274.42 -2.00 20.00 -2.00 505.25 0.00e+00 2.295793e-03 4.160261e-04 1.583696e-04 -6.000000e+00 2.104695e-03 274.42 -2.00 20.00 -2.00 500.23 0.00e+00 2.027229e+00 3.121212e-01 4.651066e-02 -6.000000e+00 1.553242e+00 232.19 -2.00 3.88 -2.00 501.82 0.00e+00 20.412 0.192 489.00 513.00 1 9.2957e+00 2.3876e-02 3.6897e-02 -6.0000e+00 1.1868e-01 7.8960e-02 5.9771e-03 2.4443e-03 -6.0000e+00 3.1033e-02 1.0365e-05 2.5548e-02 1.6240e-03 1.2306e-04 -6.0000e+00 8.8438e-03 1.8008e-01 -1.9809e-03 12 8 8 10 0 0 -172.12 21.41 1.16 0.18008 0.35728 8 2 1 4 0 4000.000 26.83 20.00 21.41 900000 -5454 5491 -10128 -1836 14693 11596 -4651 10996 9865 -8355 -9969 -2404 -1638 2034 10782 -7806 -3240 -419 4979 7530 -11795 -3753 4148 -3195 4361 -7446 3159 7940 837 1368 -12358 8233 -1545 -1840 1375 5037 8362 15654 3076 -2245 17393 810 -12311 -7006 7831 1819 -2484 -591 1571 830 -4206 7163 9576 -549 -4757 4975 -2867 -3249 -1030 -1054 2816 2111 7227 6147 -13599 -2328 -2227 -282 -926 14838 14844 576 -689 9573 -2344 12397 -11455 -8627 2721 3200 -6818 -6577 9105 7391 -3966 -7792 -1202 5841 -12197 1060 -8673 -3792 -980 12514 1629 8056 -3755 108 1341 -6082 9656 5732 -4157 -5025 -8930 4957 1657 24318 5921 7623 -5911 2270 10381 3451 475 -1384 -1152 15515 -8328 23 -2013 883 -3673 -10664 17682 8448 -10531 6422 -8989 -9331 -1978 -2769 13701 -171 9205 846 -6007 12661 7549 -5831 -3778 -6716 -5457 -4290 2304 5636 4413 123 1825 900000 -5318 5349 -10976 -1882 14131 10781 -5119 10323 9273 -9291 -11109 -2452 -1644 1962 9597 -8503 -3445 -441 5024 7444 -14185 -4177 4283 -3563 4504 -8593 3230 7571 838 1348 -14064 7794 -1657 -2017 1469 5162 8219 14181 3149 -2430 15599 867 -15182 -8251 7954 1948 -2740 -627 1592 827 -4330 6554 8654 -562 -5204 5026 -3159 -3602 -1118 -1146 2953 2231 7226 6153 -16355 -2462 -2320 -285 -932 12686 12725 574 -701 8792 -2402 10796 -12479 -9046 2536 2972 -7033 -6822 8146 6780 -4092 -8347 -1202 5431 -13605 1042 -9468 -3946 -981 10699 1507 6778 -3461 94 1142 -5620 7818 5011 -4161 -5201 -9005 4676 1608 18808 5545 7096 -5911 2270 9628 3451 458 -1371 -1143 13951 -8713 22 -1922 815 -3557 -11124 15018 7883 -11029 5666 -9206 -9498 -1849 -2589 11699 -157 7831 797 -6165 10944 6954 -6199 -3960 -7281 -5842 -4516 2246 5233 4088 118 1729 SO 20190602T112551.0Z 7092.476285 302 1 32.01 2 89.37 51.64 89.40 64.12 0.00 1 0.00 1 0 22 5.248e-02 5.188e-02 1.139e-02 1.126e-02 1.222650e+04 8.568098e+02 8.074952e+02 -6.000000e+00 2.959537e+03 274.42 -2.00 20.00 -2.00 505.40 0.00e+00 2.387220e-03 3.129339e-04 1.608334e-04 -6.000000e+00 1.472656e-03 274.42 -2.00 20.00 -2.00 500.34 0.00e+00 1.269131e+00 2.350942e-01 8.811601e-02 -6.000000e+00 1.083169e+00 232.19 -2.00 3.88 -2.00 501.99 0.00e+00 19.618 0.170 489.00 513.00 1 9.1303e+00 1.7993e-02 3.4837e-02 -6.0000e+00 8.2883e-02 8.2349e-02 4.4213e-03 2.8108e-03 -6.0000e+00 2.1467e-02 1.4369e-05 1.3701e-02 1.2197e-03 8.5923e-05 -6.0000e+00 6.2141e-03 6.3898e-02 -8.9004e-04 12 8 8 10 0 0 -3.23 21.41 1.64 0.06390 0.15894 8 2 1 4 0 4000.000 26.83 20.00 21.41 900000 -6605 3223 -8007 -6608 6268 8051 -1702 8109 7355 -7050 -9008 -1368 -2882 3737 6939 -3189 -1220 -3481 2715 5490 -8293 -3696 3549 -1965 5783 -5548 563 6817 1031 -879 -8084 6689 -2297 -1677 2477 1958 7753 9526 1506 -1637 10582 2094 -8608 -3409 5225 1816 -2287 -2282 3352 1448 -2037 3767 6128 -642 -5019 2077 -1317 -3898 172 -595 1466 464 6647 2170 -8171 -3159 -1084 1593 -2196 9897 8781 2674 -5364 6762 -644 7994 -7396 -7306 4638 525 -955 -789 3343 5535 -3068 -2078 -1395 4173 -11789 4199 -5790 -3487 -131 7333 1635 2797 -747 -1257 506 -1871 8900 7312 -2838 -7034 -7045 2566 1454 13251 7055 1384 -344 2554 2387 1218 778 -433 -241 11118 -4395 -1478 -2955 136 -356 -8362 11829 4816 -7138 3993 -7427 -7406 376 -2437 9622 2402 6456 -814 -3885 7627 8069 -3175 -3887 -5191 -3643 -1840 -5148 7597 -462 -454 1057 900000 -6698 3047 -8731 -7302 6224 7973 -1871 8059 7291 -7958 -10221 -1420 -3009 3641 6589 -3404 -1305 -3879 2875 5684 -9175 -4218 3783 -2221 6041 -5986 606 6746 1057 -908 -9042 6596 -2546 -1748 2684 2123 7869 9419 1608 -1679 10435 2110 -9761 -3696 5200 1857 -2404 -2352 3433 1476 -1961 3673 5908 -630 -5272 2068 -1369 -4168 176 -617 1495 478 6416 2170 -8938 -3236 -1073 1517 -2151 9214 7702 2514 -5508 6155 -625 7011 -7460 -7295 4093 483 -897 -747 3064 5003 -3034 -2034 -1352 3818 -12681 3875 -5950 -3503 -125 6385 1462 2398 -647 -1073 421 -1608 7056 6120 -2727 -7217 -7290 2406 1373 11121 6349 1333 -341 2474 2329 1209 782 -444 -247 10128 -4614 -1483 -2971 132 -348 -8896 10320 4513 -7532 3760 -7796 -7692 357 -2363 8272 2241 5881 -812 -4063 7212 7688 -3415 -4236 -5751 -3970 -1957 -5594 7154 -464 -454 1046 SO 20190602T112953.0Z 7092.479086 306 1 32.01 2 88.90 52.44 88.87 64.89 0.00 1 0.00 1 0 15 3.360e-02 3.316e-02 7.709e-03 7.669e-03 9.576315e+03 5.415966e+02 5.306383e+02 -6.000000e+00 1.895582e+03 274.42 -2.00 20.00 -2.00 505.33 0.00e+00 2.943506e-03 2.119443e-04 1.777203e-04 -6.000000e+00 9.414904e-04 274.42 -2.00 20.00 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