File name: Pandora123s1_StonyPlain_20190624_L2Fit_fwvt1c1d20190501p1-8.txt File generation date: 20250129T003757.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 123 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora123_OF_v3d20161109.txt Instrument calibration file used: Pandora123s1_CF_v1d20190501.txt Level 1 file used: Pandora123s1_StonyPlain_20190624_L1_smca1c1d20190501p1-8.txt Full location name: Stony Plain Upper Air Station (CWSE) Short location name: StonyPlain Country of location: Canada Location latitude [deg]: 53.5500 Location longitude [deg]: -114.1100 Location altitude [m]: 766 Local noon date: 20190624 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial fieldcal based on session 3 First and last pixel inside fitting window: 1635 1784 Nominal wavelengths inside fitting window [nm]: 492.0766 492.1981 492.3195 492.4409 492.5623 492.6837 492.8051 492.9264 493.0477 493.1691 493.2903 493.4116 493.5329 493.6541 493.7754 493.8966 494.0178 494.1390 494.2601 494.3813 494.5024 494.6235 494.7446 494.8657 494.9867 495.1078 495.2288 495.3498 495.4708 495.5918 495.7128 495.8337 495.9547 496.0756 496.1965 496.3173 496.4382 496.5591 496.6799 496.8007 496.9215 497.0423 497.1630 497.2838 497.4045 497.5252 497.6459 497.7666 497.8873 498.0079 498.1285 498.2492 498.3697 498.4903 498.6109 498.7314 498.8520 498.9725 499.0930 499.2135 499.3339 499.4544 499.5748 499.6952 499.8156 499.9360 500.0563 500.1767 500.2970 500.4173 500.5376 500.6579 500.7782 500.8984 501.0186 501.1388 501.2590 501.3792 501.4994 501.6195 501.7396 501.8598 501.9799 502.0999 502.2200 502.3400 502.4601 502.5801 502.7001 502.8200 502.9400 503.0599 503.1799 503.2998 503.4197 503.5395 503.6594 503.7792 503.8991 504.0189 504.1387 504.2584 504.3782 504.4979 504.6177 504.7374 504.8571 504.9767 505.0964 505.2160 505.3357 505.4553 505.5749 505.6944 505.8140 505.9335 506.0530 506.1725 506.2920 506.4115 506.5310 506.6504 506.7698 506.8892 507.0086 507.1280 507.2473 507.3667 507.4860 507.6053 507.7246 507.8438 507.9631 508.0823 508.2016 508.3208 508.4399 508.5591 508.6783 508.7974 508.9165 509.0356 509.1547 509.2738 509.3928 509.5118 509.6308 509.7498 509.8688 509.9878 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190624T111641.0Z 7114.469919 222 1 32.01 2 89.85 48.31 66.05 149.72 0.00 1 0.00 1 0 36 8.090e-01 3.782e-01 2.325e-01 1.057e-01 3.457436e+04 1.098379e+04 3.313312e+03 -6.000000e+00 4.736490e+04 277.07 -2.00 20.00 -2.00 504.99 0.00e+00 1.417979e-02 3.325871e-03 9.794230e-04 -6.000000e+00 2.512715e-02 277.07 -2.00 20.00 -2.00 498.72 0.00e+00 -3.578325e+00 2.957689e+00 2.171217e-01 -6.000000e+00 2.133952e+01 233.40 -2.00 3.88 -2.00 500.34 0.00e+00 20.332 0.190 489.00 513.00 1 1.1430e+01 2.1725e-01 4.2820e-02 -6.0000e+00 1.5945e+00 3.0041e-01 6.7447e-02 3.3433e-03 -6.0000e+00 5.0648e-01 1.0681e-06 4.0722e-03 1.0921e-02 4.1801e-04 -6.0000e+00 1.0484e-01 5.8405e-01 -1.2148e-02 12 9 8 11 256 0 -61.39 21.36 17.87 0.58405 0.61230 8 2 1 4 0 4000.000 26.73 20.00 21.36 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 64286 125146 213306 3873 37561 28296 180220 98162 -44926 -10346 73991 -15338 66296 -19812 -1914 95216 59738 14914 -42542 247279 -2481 38235 86308 86806 203180 190564 41854 -6635 900000 56393 -38652 27085 49466 5545 1108 -5847 72791 38061 71406 76549 145308 -10985 -4737 78437 39354 11409 11425 -15228 64156 22341 68035 33553 -43325 4144 -38621 59248 -10408 900000 102724 54894 -1029 124999 52205 900000 -3040 -27100 143740 43363 18445 41356 93511 65738 -26298 1791 28340 96343 -34873 67512 -19733 5444 83866 206220 99736 131790 49931 105963 77092 127843 900000 900000 53472 -15021 -12696 76587 222405 900000 94916 42474 -16994 9726 91123 14537 17969 128980 -218 900000 -27547 7480 7740 132723 57784 -18327 900000 65753 -16908 165607 -48110 10908 19419 37705 900000 24679 188566 15811 -28139 150730 80306 -31831 9038 5519 -4879 10594 -4387 76789 65156 -19112 3824 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 43389 50596 36697 5135 36386 30557 46508 53002 -100242 -16019 48176 -23871 44745 -31149 -2493 46875 42217 16698 -85462 29780 -3349 34307 47972 48249 38451 40981 36557 -9272 900000 39852 -69363 25163 37314 6649 1416 -8078 45661 33546 44792 45587 43844 -16049 -6620 48580 36561 14132 14152 -24425 45848 23771 44839 30639 -84627 5068 -68628 43752 -15784 900000 51387 44460 -1462 50620 43940 900000 -4417 -45957 46795 37875 20358 35794 47521 43847 -40912 2275 27679 47430 -58368 42886 -27353 6225 43285 31112 43557 41858 36079 43752 42238 41620 900000 900000 35241 -18274 -15164 40136 26490 900000 36930 26643 -17292 7955 32560 11196 13697 33797 -203 900000 -35747 6894 7134 37939 35330 -22567 900000 38114 -20819 35504 -81942 10456 17325 28079 900000 20198 31443 13523 -37138 35906 38897 -44123 8330 5249 -5108 9373 -4431 33971 32187 -21983 3524 SO 20190624T112100.0Z 7114.472917 226 1 32.01 2 89.37 49.17 65.72 150.81 0.00 1 0.00 1 0 73 8.959e-01 3.567e-01 2.624e-01 9.729e-02 1.124025e+05 1.464198e+04 4.564117e+02 -6.000000e+00 5.320267e+04 277.07 -2.00 20.00 -2.00 505.18 0.00e+00 -4.781694e-03 2.909005e-03 1.097111e-03 -6.000000e+00 2.658374e-02 277.07 -2.00 20.00 -2.00 499.16 0.00e+00 -8.707648e+00 2.403782e+00 1.504611e-01 -6.000000e+00 1.986765e+01 233.40 -2.00 3.88 -2.00 500.86 0.00e+00 19.538 0.168 489.00 513.00 1 1.1997e+01 1.8301e-01 4.3752e-02 -6.0000e+00 1.4929e+00 2.4766e-01 4.2194e-02 2.1800e-03 -6.0000e+00 4.2720e-01 1.2088e-06 1.0396e-01 5.6619e-03 5.3656e-04 -6.0000e+00 1.1074e-01 4.3477e-01 -6.3814e-03 12 12 8 10 0 0 28.13 21.36 0.13 0.43477 1.15590 8 2 1 4 0 4000.000 26.73 20.00 21.36 900000 900000 900000 900000 900000 900000 232117 -1346 191959 82432 -17255 -27960 23314 70412 55137 150094 -9064 31489 10059 121048 102083 -46918 -5708 62599 -10234 65961 -8409 15140 79058 59890 21194 -42220 174933 1704 12876 86490 95278 126869 359957 28917 1812 900000 38923 -26391 24472 82624 10738 7531 -258 46287 42827 17493 67333 112627 7647 -25608 57826 20256 -8724 24832 -12800 69371 28054 63214 67780 -32234 9079 -41657 58521 -10361 900000 67053 44862 -4154 86584 61538 352659 -18966 -47445 90190 58276 -6758 8277 128552 34488 -11572 -657 24147 60920 -48049 23850 -11043 -11905 21268 108640 36101 78210 -18619 20317 9216 30217 900000 290864 23416 -598 -24615 78320 97480 900000 48196 109751 54633 22758 71018 57138 16737 46225 18528 900000 -9732 16965 -1780 80153 40470 -41899 330652 51926 -27329 63649 -35326 -209 -1140 21436 900000 27668 286702 5954 -20856 251265 79269 -21608 -5322 7472 15358 -3313 -13884 71695 91187 -9572 -2142 900000 900000 900000 900000 900000 900000 33128 -1843 41095 52288 -27026 -48091 23718 44320 40355 46414 -12936 30653 12368 53748 55040 -103705 -8356 46275 -15655 46829 -12432 17397 46869 42081 21717 -82197 42998 2244 15456 50009 50209 52309 34249 28784 2360 900000 35326 -46357 25972 48983 12967 9260 -336 36927 34480 17797 41397 44513 8843 -42359 42324 21794 -12578 25626 -19299 46203 28336 44879 45640 -54111 10698 -74743 41119 -14409 900000 43188 36447 -5564 46895 42338 33555 -27762 -83514 42247 37108 -8261 8845 42340 29785 -14864 -807 22622 38346 -81312 20773 -13336 -13854 16345 31011 18760 24042 -14172 10260 5261 14596 900000 27675 17138 -585 -33458 42992 44948 900000 36334 44180 37187 19025 37944 34292 14105 32479 16748 900000 -11972 15335 -1827 36959 26955 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