File name: Pandora231s1_Suwon-USW_20250308_L2Fit_fout2c3d20231101p1-8.txt File generation date: 20250308T161218.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Hyeong-Ahn Kwon Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 231 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora231_OF_v2d20220713.txt Instrument calibration file used: Pandora231s1_CF_v3d20231101.txt Level 1 file used: Pandora231s1_Suwon-USW_20250308_L1_smca1c3d20231101p1-8.txt Full location name: University of Suwon Short location name: Suwon-USW Country of location: Korea, Republic of Location latitude [deg]: 37.2110 Location longitude [deg]: 126.9800 Location altitude [m]: 60 Local noon date: 20250308 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session after repairs and clearance, based on session 2 First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0495 305.1909 305.3323 305.4738 305.6151 305.7565 305.8979 306.0393 306.1806 306.3219 306.4633 306.6046 306.7459 306.8872 307.0285 307.1697 307.3110 307.4523 307.5935 307.7347 307.8759 308.0172 308.1584 308.2995 308.4407 308.5819 308.7230 308.8642 309.0053 309.1464 309.2875 309.4286 309.5697 309.7108 309.8519 309.9929 310.1339 310.2750 310.4160 310.5570 310.6980 310.8390 310.9800 311.1209 311.2619 311.4028 311.5438 311.6847 311.8256 311.9665 312.1074 312.2483 312.3891 312.5300 312.6708 312.8117 312.9525 313.0933 313.2341 313.3749 313.5157 313.6564 313.7972 313.9379 314.0787 314.2194 314.3601 314.5008 314.6415 314.7822 314.9228 315.0635 315.2041 315.3448 315.4854 315.6260 315.7666 315.9072 316.0477 316.1883 316.3289 316.4694 316.6099 316.7505 316.8910 317.0315 317.1720 317.3124 317.4529 317.5933 317.7338 317.8742 318.0146 318.1550 318.2954 318.4358 318.5762 318.7166 318.8569 318.9973 319.1376 319.2779 319.4182 319.5585 319.6988 319.8391 319.9793 320.1196 320.2598 320.4000 320.5403 320.6805 320.8207 320.9608 321.1010 321.2412 321.3813 321.5214 321.6616 321.8017 321.9418 322.0819 322.2220 322.3620 322.5021 322.6421 322.7822 322.9222 323.0622 323.2022 323.3422 323.4822 323.6221 323.7621 323.9020 324.0420 324.1819 324.3218 324.4617 324.6016 324.7414 324.8813 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250307T233537.5Z 9197.983073 148 1 49.07 2 71.14 111.85 114.04 11.73 0.00 1 0.00 1 0 49 2.365e-01 3.853e-02 1.754e-01 5.827e-03 3.525581e-01 2.884623e-03 7.825427e-03 -6.000000e+00 1.306179e-01 226.18 -2.00 3.43 -2.00 320.19 0.00e+00 3.795106e-03 9.751342e-04 8.862109e-03 -6.000000e+00 5.703075e-03 279.21 -2.00 20.00 -2.00 319.57 0.00e+00 3.057 0.000 302.00 328.00 3 4.6306e+00 8.5869e-03 4.9956e-02 -6.0000e+00 3.2413e-01 -2.2114e-01 1.0449e-02 5.0059e-02 -6.0000e+00 3.5261e-01 9.2053e-02 9.2534e-03 2.6230e-02 -6.0000e+00 2.0969e-01 -3.7240e-02 4.7867e-03 7.3594e-03 -6.0000e+00 9.0550e-02 1.8450e-04 7.3575e-03 1.6703e-04 1.3581e-04 -6.0000e+00 5.7815e-03 4.2902e-02 2.2915e-04 12 8 8 10 0 0 99.98 22.08 0.34 0.04290 0.09819 24 5 4 8 0 2044.110 20.04 22.08 14.66 25.07 25.39 0.0 905.53 212000 -2417 -4226 -54750 104711 -1375 63336 -62051 -18452 8567 -48371 -8662 -26069 22272 4258 -6507 1287 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388 3166 4136 2525 2544 1267 -1946 -4171 -7940 -6786 -4366 -2768 -2466 -2020 -2494 32 1393 4873 5222 7513 5219 1527 -1683 -7949 -6596 -6118 -2535 656 5171 5452 3103 -1869 -6403 -9597 -4606 -185 -2366 -2011 1169 479 6536 10086 9505 4780 -822 -7732 -8915 -7505 -4211 1262 5722 6839 5700 6560 3311 336 -4561 -9377 -6161 -2435 -2620 -1733 -6244 -6053 -4166 778 2720 5187 8815 8450 2927 1285 -5460 -7586 SS 20250307T234732.5Z 9197.991349 155 1 48.84 2 68.95 113.99 113.54 14.40 0.00 1 0.00 1 0 49 1.165e-01 4.065e-02 7.944e-02 4.964e-03 3.254880e-01 2.423826e-03 6.716383e-03 -6.000000e+00 6.422819e-02 226.18 -2.00 3.43 -2.00 319.76 0.00e+00 1.905693e-03 7.243253e-04 6.865419e-03 -6.000000e+00 2.808237e-03 279.21 -2.00 20.00 -2.00 319.14 0.00e+00 2.758 0.000 302.00 328.00 3 4.7719e+00 6.9656e-03 4.1802e-02 -6.0000e+00 1.5938e-01 -2.1477e-01 8.3071e-03 4.0012e-02 -6.0000e+00 1.7347e-01 1.0020e-01 6.9438e-03 1.8697e-02 -6.0000e+00 1.0315e-01 -4.3985e-02 3.6494e-03 4.1161e-03 -6.0000e+00 4.4486e-02 2.1967e-04 6.0419e-03 1.3938e-04 8.6678e-05 -6.0000e+00 2.8503e-03 4.5958e-02 -9.2885e-06 12 8 8 10 0 0 96.80 22.11 0.41 0.04596 0.09136 16 3 4 8 0 3052.040 20.15 22.11 15.44 25.07 25.39 0.0 911.30 9288 -26750 52188 -37680 577 -58629 1919 -37004 -26689 -31883 -5697 -19498 -22212 7128 9324 1008 1781 -7092 3167 5928 -3023 -2967 3203 15935 -3933 6372 -10064 -1541 -7931 -229 -4928 4184 -52 -15491 -20111 43129 -16757 -2364 3602 1604 2784 4621 5924 4384 5000 1056 -202 -6241 -623 -5093 4867 -1233 3816 1385 3714 1080 2091 -3230 -553 -4634 3579 5452 9251 6246 -1819 -5148 -9167 -4569 3064 5068 4985 5522 5134 3000 -4118 -9390 -13842 -12524 -7344 -4426 -3186 -3252 -3598 -347 1515 5507 6449 7919 6180 1596 -2377 -7819 -10983 -7549 -3726 -1363 5317 4742 2620 -1355 -4789 -9042 -3420 -1423 -1689 -1416 269 1202 4827 6523 6621 3200 165 -4864 -6119 -5765 -2360 1387 3610 3389 3998 4009 1497 -795 -3092 -6727 -4606 -1757 -1289 -1034 -2958 -3030 -2174 665 1069 2015 4549 3889 2018 39 -1960 -3684 142 -637 568 -897 9 -1655 33 -1189 -857 -1094 -150 -678 -958 273 410 52 97 -452 192 368 -205 -202 221 1038 -330 502 -903 -119 -639 -19 -470 407 -6 -1915 -2677 3319 -2725 -406 708 363 660 1129 1474 1112 1285 283 -54 -1776 -169 -1538 1465 -422 1332 520 1395 431 832 -1327 -219 -1967 1519 2518 4526 3262 -955 -2601 -4707 -2364 1711 3098 3211 3568 3215 1799 -2376 -5163 -7564 -7104 -4582 -3061 -2444 -2704 -3128 -315 1460 5403 6514 7968 6131 1532 -2179 -6944 -9771 -6996 -3741 -1502 6191 5997 3331 -1678 -5612 -10249 -3808 -1723 -2160 -1895 375 1754 7364 10503 10892 5267 263 -7455 -8938 -8465 -3523 2156 5879 5614 6449 6331 2323 -1201 -4592 -9788 -6710 -2738 -2165 -1843 -5545 -5815 -3942 1262 2127 4055 9196 7964 4067 77 -3802 -7135 SS 20250308T002018.6Z 9198.014104 171 1 50.60 2 63.14 120.26 111.63 21.54 0.00 1 0.00 1 0 49 6.135e-02 4.105e-02 3.245e-02 4.344e-03 2.770714e-01 2.097414e-03 4.505952e-03 -6.000000e+00 3.386518e-02 226.18 -2.00 3.43 -2.00 318.90 0.00e+00 2.553479e-03 4.777936e-04 3.533754e-03 -6.000000e+00 1.479304e-03 279.21 -2.00 20.00 -2.00 318.25 0.00e+00 2.201 0.000 302.00 328.00 3 5.1813e+00 5.7533e-03 2.8072e-02 -6.0000e+00 8.4035e-02 -1.1316e-01 6.6239e-03 2.0120e-02 -6.0000e+00 9.1435e-02 5.7197e-02 4.7866e-03 1.0531e-02 -6.0000e+00 5.4374e-02 -3.2551e-02 2.5545e-03 3.2758e-03 -6.0000e+00 2.3472e-02 2.5274e-04 5.7139e-03 1.1941e-04 3.9388e-05 -6.0000e+00 1.5005e-03 4.2513e-02 9.5545e-05 12 8 8 10 0 0 99.71 22.25 0.44 0.04251 0.08545 15 3 1 8 0 3372.910 19.95 22.25 17.57 25.17 25.47 0.0 927.39 6747 1888 -11356 -7190 -4481 -14480 -14724 3035 8343 -8110 -20143 -14042 13184 -148 2857 6793 5626 12499 4866 4715 626 -788 201 -1731 -2768 -816 -744 -3711 -3670 -5354 -3665 876 510 -13206 -16518 -18018 -12378 -5529 919 4814 792 3814 4469 2636 3509 2190 999 -1155 -4213 -3094 484 910 5345 3918 2336 2911 1874 -2450 -3875 -3710 837 5914 9150 6997 -367 -4355 -9278 -4314 1239 4936 5939 4758 5086 2741 -2547 -8090 -13281 -12098 -7705 -5455 -2683 -3251 -3070 -1581 1896 4054 6392 7392 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