File name: Pandora231s1_Suwon-USW_20250607_L2Fit_fwvt1c3d20231101p1-8.txt File generation date: 20250607T154843.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Hyeong-Ahn Kwon Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 231 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora231_OF_v3d20220713.txt Instrument calibration file used: Pandora231s1_CF_v3d20231101.txt Level 1 file used: Pandora231s1_Suwon-USW_20250607_L1_smca1c3d20231101p1-8.txt Full location name: University of Suwon Short location name: Suwon-USW Country of location: Korea, Republic of Location latitude [deg]: 37.2110 Location longitude [deg]: 126.9800 Location altitude [m]: 60 Local noon date: 20250607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session after repairs and clearance, based on session 2 First and last pixel inside fitting window: 1612 1760 Nominal wavelengths inside fitting window [nm]: 492.0504 492.1723 492.2941 492.4160 492.5378 492.6596 492.7814 492.9031 493.0249 493.1466 493.2684 493.3901 493.5118 493.6334 493.7551 493.8767 493.9983 494.1199 494.2415 494.3631 494.4846 494.6062 494.7277 494.8492 494.9707 495.0922 495.2136 495.3350 495.4565 495.5779 495.6993 495.8206 495.9420 496.0633 496.1846 496.3059 496.4272 496.5485 496.6697 496.7910 496.9122 497.0334 497.1546 497.2757 497.3969 497.5180 497.6391 497.7602 497.8813 498.0024 498.1234 498.2444 498.3655 498.4865 498.6074 498.7284 498.8493 498.9703 499.0912 499.2121 499.3330 499.4538 499.5747 499.6955 499.8163 499.9371 500.0579 500.1786 500.2994 500.4201 500.5408 500.6615 500.7822 500.9028 501.0235 501.1441 501.2647 501.3853 501.5059 501.6264 501.7470 501.8675 501.9880 502.1085 502.2289 502.3494 502.4698 502.5903 502.7107 502.8310 502.9514 503.0718 503.1921 503.3124 503.4327 503.5530 503.6733 503.7935 503.9137 504.0340 504.1542 504.2743 504.3945 504.5146 504.6348 504.7549 504.8750 504.9951 505.1151 505.2352 505.3552 505.4752 505.5952 505.7152 505.8351 505.9551 506.0750 506.1949 506.3148 506.4347 506.5545 506.6743 506.7942 506.9140 507.0338 507.1535 507.2733 507.3930 507.5127 507.6324 507.7521 507.8718 507.9914 508.1111 508.2307 508.3503 508.4698 508.5894 508.7089 508.8285 508.9480 509.0675 509.1870 509.3064 509.4259 509.5453 509.6647 509.7841 509.9034 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250606T213401.4Z 9288.898627 121 1 4.71 2 75.90 71.96 138.71 294.60 0.00 1 0.00 1 0 36 1.565e-02 1.553e-02 1.300e-03 1.296e-03 3.271048e+03 7.755621e+01 2.533780e+02 -6.000000e+00 8.432085e+02 287.73 -2.00 20.00 -2.00 505.34 0.00e+00 9.316239e-04 3.559870e-05 3.643586e-05 -6.000000e+00 4.372696e-04 287.73 -2.00 20.00 -2.00 500.52 0.00e+00 5.841288e-01 2.498260e-02 1.886304e-02 -6.000000e+00 3.047942e-01 232.36 -2.00 3.43 -2.00 502.13 0.00e+00 4.012 0.001 489.00 513.00 1 2.5557e+00 1.9051e-03 6.0260e-03 -6.0000e+00 2.3322e-02 -3.2689e-02 5.0312e-04 5.8372e-04 -6.0000e+00 6.1645e-03 8.1079e-02 2.7863e-03 1.0437e-04 2.9831e-05 -6.0000e+00 1.2975e-03 6.7559e-02 -2.7675e-04 12 8 8 10 0 0 6.45 25.53 0.85 0.06756 0.08689 1947 2995 3 2 0 2.400 20.00 25.53 29.43 28.21 28.62 0.0 1000.78 -4491 -3151 -1313 -300 720 1545 2095 2262 1468 1035 139 -601 -1545 -2063 -2096 -1739 -1067 99 711 588 1035 960 1299 1607 1816 1666 1373 298 -1707 -2557 -2590 -2002 -266 1137 1523 802 197 -473 -866 -609 -159 684 1203 2135 2206 2369 1804 1237 -117 -1719 -2627 -3708 -3436 -2026 -939 132 400 661 711 689 1374 1816 2013 1647 1082 311 9 -533 -1069 -1115 -602 -370 276 579 408 -556 -1353 -1923 -2147 -1611 -1227 -1481 -1243 -773 -484 -473 -541 -251 145 720 2062 2866 2795 2263 1705 941 -480 -1994 -2930 -2929 -2345 -806 825 758 215 -811 -1974 -2017 -1678 -585 -181 663 1068 1287 2072 2135 2829 2000 608 224 -397 76 603 693 1083 1018 732 811 608 -154 -1143 -1802 -2812 -2755 -1708 -1051 -254 319 760 814 1168 1370 1566 1705 635 -710 -1796 -2133 -1794 -4153 -2945 -1258 -296 717 1560 2145 2329 1511 1052 141 -606 -1540 -2041 -2078 -1734 -1077 102 747 621 1089 1012 1365 1695 1924 1763 1451 314 -1755 -2568 -2601 -2021 -273 1205 1643 864 210 -503 -912 -637 -167 720 1278 2277 2368 2531 1917 1303 -122 -1763 -2635 -3695 -3416 -2040 -908 130 399 658 703 681 1358 1801 1995 1629 1060 301 9 -510 -1011 -1041 -562 -349 262 558 393 -529 -1271 -1797 -1999 -1499 -1154 -1406 -1184 -745 -471 -461 -526 -243 141 698 2004 2824 2770 2220 1651 899 -453 -1852 -2693 -2687 -2176 -765 809 766 218 -820 -1979 -1998 -1674 -589 -185 681 1104 1332 2140 2226 2941 2073 628 229 -400 76 608 703 1093 1030 740 819 618 -156 -1142 -1789 -2794 -2728 -1713 -1013 -247 313 750 807 1158 1367 1568 1706 635 -702 -1740 -2042 -1720 SQ 20250606T213406.2Z 9288.898683 121 2 4.74 2 75.88 71.97 138.73 294.62 0.00 1 0.00 1 0 43 1.547e-02 1.535e-02 1.339e-03 1.334e-03 3.205831e+03 7.978801e+01 2.470603e+02 -6.000000e+00 8.335953e+02 287.73 -2.00 20.00 -2.00 505.35 0.00e+00 9.170839e-04 3.663407e-05 3.508543e-05 -6.000000e+00 4.322888e-04 287.73 -2.00 20.00 -2.00 500.53 0.00e+00 5.963560e-01 2.570215e-02 1.901373e-02 -6.000000e+00 3.013057e-01 232.36 -2.00 3.43 -2.00 502.14 0.00e+00 4.008 0.001 489.00 513.00 1 2.5873e+00 1.9588e-03 6.0179e-03 -6.0000e+00 2.3056e-02 -3.2999e-02 5.1713e-04 5.8340e-04 -6.0000e+00 6.0936e-03 7.8552e-02 3.0185e-03 1.0726e-04 2.8658e-05 -6.0000e+00 1.2827e-03 6.6204e-02 -2.6448e-04 12 8 8 10 0 0 8.55 25.53 0.91 0.06620 0.08714 1947 2995 3 2 0 2.400 20.00 25.53 29.43 28.21 28.62 0.0 1000.78 -4370 -3082 -1345 -265 596 1463 2004 2158 1588 874 175 -690 -1481 -2121 -2010 -1978 -963 239 740 649 848 1100 1190 1611 1785 1673 1404 200 -1669 -2539 -2488 -2012 12 1155 1466 810 128 -333 -916 -727 -69 696 1351 2114 2427 2210 1767 1000 -154 -1813 -2819 -3650 -3424 -2069 -878 250 526 613 617 757 1548 1837 1882 1658 1089 390 -85 -563 -1057 -1234 -695 -306 470 740 463 -474 -1286 -1722 -2194 -1722 -1377 -1409 -1138 -749 -431 -626 -576 -245 257 875 2051 2852 2884 2106 1600 708 -307 -2016 -2914 -2720 -2077 -908 691 886 222 -981 -1881 -2083 -1475 -778 -298 497 1013 1382 1804 2215 2887 2049 667 112 -334 44 517 825 1014 1204 710 781 680 -323 -1296 -1599 -2705 -2631 -1642 -936 -305 417 614 720 1071 1308 1535 1602 718 -820 -1763 -2194 -1555 -4031 -2876 -1288 -261 594 1477 2051 2221 1630 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