File name: Pandora231s1_Suwon-USW_20250623_L2Fit_fwvt1c3d20231101p1-8.txt File generation date: 20250623T160042.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Hyeong-Ahn Kwon Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 231 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora231_OF_v3d20220713.txt Instrument calibration file used: Pandora231s1_CF_v3d20231101.txt Level 1 file used: Pandora231s1_Suwon-USW_20250623_L1_smca1c3d20231101p1-8.txt Full location name: University of Suwon Short location name: Suwon-USW Country of location: Korea, Republic of Location latitude [deg]: 37.2110 Location longitude [deg]: 126.9800 Location altitude [m]: 60 Local noon date: 20250623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session after repairs and clearance, based on session 2 First and last pixel inside fitting window: 1612 1760 Nominal wavelengths inside fitting window [nm]: 492.0504 492.1723 492.2941 492.4160 492.5378 492.6596 492.7814 492.9031 493.0249 493.1466 493.2684 493.3901 493.5118 493.6334 493.7551 493.8767 493.9983 494.1199 494.2415 494.3631 494.4846 494.6062 494.7277 494.8492 494.9707 495.0922 495.2136 495.3350 495.4565 495.5779 495.6993 495.8206 495.9420 496.0633 496.1846 496.3059 496.4272 496.5485 496.6697 496.7910 496.9122 497.0334 497.1546 497.2757 497.3969 497.5180 497.6391 497.7602 497.8813 498.0024 498.1234 498.2444 498.3655 498.4865 498.6074 498.7284 498.8493 498.9703 499.0912 499.2121 499.3330 499.4538 499.5747 499.6955 499.8163 499.9371 500.0579 500.1786 500.2994 500.4201 500.5408 500.6615 500.7822 500.9028 501.0235 501.1441 501.2647 501.3853 501.5059 501.6264 501.7470 501.8675 501.9880 502.1085 502.2289 502.3494 502.4698 502.5903 502.7107 502.8310 502.9514 503.0718 503.1921 503.3124 503.4327 503.5530 503.6733 503.7935 503.9137 504.0340 504.1542 504.2743 504.3945 504.5146 504.6348 504.7549 504.8750 504.9951 505.1151 505.2352 505.3552 505.4752 505.5952 505.7152 505.8351 505.9551 506.0750 506.1949 506.3148 506.4347 506.5545 506.6743 506.7942 506.9140 507.0338 507.1535 507.2733 507.3930 507.5127 507.6324 507.7521 507.8718 507.9914 508.1111 508.2307 508.3503 508.4698 508.5894 508.7089 508.8285 508.9480 509.0675 509.1870 509.3064 509.4259 509.5453 509.6647 509.7841 509.9034 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250622T211955.2Z 9304.888833 123 1 4.57 2 78.78 69.01 49.19 89.81 0.00 1 0.00 1 0 36 1.564e-02 1.546e-02 8.123e-04 8.102e-04 4.865721e+03 5.110365e+01 3.635934e+02 -6.000000e+00 8.475315e+02 289.20 -2.00 20.00 -2.00 505.38 0.00e+00 1.070441e-03 2.218418e-05 4.085333e-05 -6.000000e+00 4.386823e-04 289.20 -2.00 20.00 -2.00 500.62 0.00e+00 8.212324e-01 1.563127e-02 2.781484e-02 -6.000000e+00 3.045479e-01 232.73 -2.00 3.43 -2.00 502.19 0.00e+00 4.958 0.002 489.00 513.00 1 1.8769e+00 1.1972e-03 7.5443e-03 -6.0000e+00 2.3316e-02 -3.3330e-02 3.0883e-04 8.3086e-04 -6.0000e+00 6.1608e-03 1.3665e-01 3.0922e-03 6.5176e-05 3.7273e-05 -6.0000e+00 1.2970e-03 6.6075e-02 -2.7218e-04 12 8 8 10 0 0 8.90 25.11 0.88 0.06607 0.08752 1887 3594 3 2 0 2.400 20.01 25.11 29.63 27.78 28.21 0.0 1003.44 -4271 -3171 -1294 -357 616 1415 2092 2213 1574 862 366 -666 -1584 -2020 -2028 -1874 -1037 267 645 715 967 1051 1346 1652 1934 1647 1425 105 -1759 -2555 -2330 -1929 -188 1209 1372 832 173 -349 -854 -693 -218 571 1331 2106 2310 2364 1750 1108 -273 -1652 -2914 -3638 -3446 -2069 -698 153 723 517 668 836 1548 1764 2019 1649 1005 337 38 -434 -1219 -1269 -764 -276 443 754 248 -605 -1343 -1927 -2118 -1859 -1232 -1359 -1083 -538 -415 -499 -470 -37 432 1033 2269 3075 2876 2538 1769 769 -478 -2005 -2979 -2816 -2231 -849 651 705 145 -874 -1822 -2100 -1565 -895 -164 561 1067 1218 1820 2194 2981 2165 672 21 -390 46 456 946 975 929 525 736 656 -450 -1232 -1875 -2612 -2534 -1717 -746 -240 331 681 888 1059 1253 1538 1423 732 -665 -1835 -2240 -1825 -4121 -3100 -1298 -344 600 1397 2093 2227 1581 857 362 -656 -1543 -1953 -1964 -1830 -1023 269 663 738 996 1083 1383 1705 2003 1706 1474 108 -1771 -2513 -2286 -1907 -188 1255 1452 877 181 -363 -882 -711 -224 590 1385 2204 2430 2479 1825 1146 -280 -1661 -2876 -3554 -3363 -2046 -708 159 756 542 695 866 1606 1840 2104 1714 1036 343 39 -436 -1212 -1247 -751 -274 442 761 252 -604 -1324 -1889 -2068 -1818 -1214 -1350 -1011 -508 -397 -478 -448 -35 409 979 2156 2960 2783 2420 1664 714 -437 -1806 -2659 -2506 -2011 -785 623 697 144 -867 -1788 -2043 -1531 -888 -164 565 1079 1235 1844 2240 3037 2202 681 21 -386 45 451 937 966 924 523 729 654 -449 -1209 -1830 -2548 -2466 -1697 -753 -245 341 707 925 1107 1318 1622 1503 770 -691 -1875 -2265 -1848 SQ 20250622T211959.9Z 9304.888888 123 2 4.57 2 78.76 69.02 49.18 89.82 0.00 1 0.00 1 0 36 1.555e-02 1.537e-02 8.089e-04 8.067e-04 4.838293e+03 5.086191e+01 3.584178e+02 -6.000000e+00 8.427589e+02 289.20 -2.00 20.00 -2.00 505.39 0.00e+00 1.102693e-03 2.208374e-05 4.332125e-05 -6.000000e+00 4.362151e-04 289.20 -2.00 20.00 -2.00 500.62 0.00e+00 8.411188e-01 1.556887e-02 2.860970e-02 -6.000000e+00 3.028246e-01 232.73 -2.00 3.43 -2.00 502.19 0.00e+00 4.952 0.002 489.00 513.00 1 1.8712e+00 1.1922e-03 7.5616e-03 -6.0000e+00 2.3184e-02 -3.3780e-02 3.0758e-04 8.3789e-04 -6.0000e+00 6.1258e-03 1.3728e-01 2.9607e-03 6.4843e-05 3.6929e-05 -6.0000e+00 1.2896e-03 6.5959e-02 -2.6915e-04 12 8 8 10 0 0 9.33 25.11 0.86 0.06596 0.08650 1887 3594 3 2 0 2.400 20.01 25.11 29.63 27.78 28.21 0.0 1003.44 -4251 -3294 -1412 -307 703 1515 2169 2215 1691 980 286 -632 -1494 -1902 -2051 -1838 -1041 110 581 761 862 999 1359 1747 1889 1607 1346 139 -1776 -2509 -2462 -1886 -115 1236 1396 752 153 -265 -756 -775 -187 508 1298 2119 2271 2245 1711 1026 -245 -1629 -2932 -3581 -3362 -2172 -662 139 695 587 635 812 1404 1747 1924 1799 1027 384 61 -382 -1153 -1249 -785 -210 540 778 258 -585 -1431 -1914 -2170 -1750 -1310 -1415 -1150 -584 -396 -436 -596 -148 406 1000 2072 3020 2995 2347 1721 743 -414 -1923 -2933 -2917 -2257 -730 706 806 135 -874 -1810 -2122 -1480 -871 -139 556 1062 1311 1883 2228 2982 2142 615 -13 -414 46 675 630 858 931 572 709 581 -459 -1168 -1805 -2675 -2633 -1594 -782 -202 363 656 875 979 1182 1547 1302 769 -537 -1751 -2165 -1781 -4101 -3225 -1417 -295 684 1495 2169 2229 1697 974 283 -623 -1455 -1838 -1987 -1794 -1028 111 598 785 889 1031 1397 1802 1958 1667 1394 143 -1790 -2468 -2419 -1864 -115 1283 1477 794 161 -275 -781 -797 -193 526 1351 2218 2391 2358 1787 1063 -251 -1638 -2896 -3498 -3280 -2151 -672 144 727 615 661 842 1460 1825 2008 1869 1060 391 62 -384 -1147 -1228 -772 -208 538 786 262 -585 -1413 -1877 -2120 -1710 -1292 -1319 -1075 -552 -379 -418 -569 -141 385 948 1973 2910 2895 2243 1621 691 -378 -1732 -2617 -2599 -2036 -674 677 796 134 -867 -1776 -2066 -1447 -865 -139 560 1074 1328 1906 2274 3040 2180 625 -13 -410 45 666 627 852 926 569 704 580 -458 -1147 -1761 -2612 -2566 -1574 -790 -206 373 682 913 1025 1245 1632 1377 809 -559 -1789 -2190 -1803 SQ 20250622T212004.5Z 9304.888941 123 3 4.58 2 78.75 69.03 49.16 89.83 0.00 1 0.00 1 0 36 1.554e-02 1.536e-02 8.067e-04 8.045e-04 4.808007e+03 5.069680e+01 3.584367e+02 -6.000000e+00 8.418905e+02 289.20 -2.00 20.00 -2.00 505.38 0.00e+00 1.097522e-03 2.202602e-05 4.285464e-05 -6.000000e+00 4.357640e-04 289.20 -2.00 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