File name: Pandora240s1_Thessaloniki_20231024_L2Fit_fout2c13d20231018p1-8.txt File generation date: 20241007T145001.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v13d20231018.txt Level 1 file used: Pandora240s1_Thessaloniki_20231024_L1_smca1c13d20231018p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20231024 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 for VP 20231018 First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2379 305.3790 305.5201 305.6613 305.8024 305.9434 306.0845 306.2256 306.3666 306.5076 306.6487 306.7897 306.9307 307.0717 307.2126 307.3536 307.4945 307.6355 307.7764 307.9173 308.0582 308.1991 308.3400 308.4808 308.6217 308.7625 308.9034 309.0442 309.1850 309.3258 309.4665 309.6073 309.7480 309.8888 310.0295 310.1702 310.3109 310.4516 310.5923 310.7330 310.8736 311.0143 311.1549 311.2955 311.4361 311.5767 311.7173 311.8578 311.9984 312.1389 312.2795 312.4200 312.5605 312.7010 312.8415 312.9819 313.1224 313.2628 313.4033 313.5437 313.6841 313.8245 313.9649 314.1053 314.2456 314.3860 314.5263 314.6666 314.8069 314.9472 315.0875 315.2278 315.3680 315.5083 315.6485 315.7888 315.9290 316.0692 316.2094 316.3495 316.4897 316.6298 316.7700 316.9101 317.0502 317.1903 317.3304 317.4705 317.6106 317.7506 317.8907 318.0307 318.1707 318.3107 318.4507 318.5907 318.7307 318.8706 319.0106 319.1505 319.2904 319.4303 319.5702 319.7101 319.8500 319.9898 320.1297 320.2695 320.4093 320.5491 320.6889 320.8287 320.9685 321.1083 321.2480 321.3877 321.5275 321.6672 321.8069 321.9466 322.0863 322.2259 322.3656 322.5052 322.6448 322.7845 322.9241 323.0637 323.2032 323.3428 323.4824 323.6219 323.7614 323.9010 324.0405 324.1800 324.3194 324.4589 324.5984 324.7378 324.8773 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231024T055622.9Z 8697.247488 111 1 54.29 2 78.83 116.18 155.03 342.50 0.00 1 0.00 1 0 17 2.858e-01 7.262e-03 1.747e-01 4.028e-03 5.710175e-01 2.136023e-03 6.606964e-03 -6.000000e+00 1.632203e-01 225.21 -2.00 3.50 -2.00 320.73 0.00e+00 3.519545e-03 8.988767e-04 1.496752e-03 -6.000000e+00 7.306029e-03 283.15 -2.00 20.00 -2.00 320.15 0.00e+00 4.980 0.002 302.00 328.00 3 1.7673e+00 6.7567e-03 5.7633e-02 -6.0000e+00 4.0333e-01 6.0314e-02 8.9309e-03 3.0695e-02 -6.0000e+00 4.3730e-01 -8.9102e-02 8.8391e-03 1.7535e-02 -6.0000e+00 2.6088e-01 2.5468e-02 4.3728e-03 6.8272e-03 -6.0000e+00 1.1328e-01 3.6433e-04 -1.3299e-04 1.1258e-04 7.3338e-05 -6.0000e+00 7.5523e-03 -2.8593e-03 0.0000e+00 11 8 0 10 0 0 99.03 23.81 0.90 -0.00286 -0.00386 135 15 1 8 0 401.784 20.00 23.81 24.98 28.00 28.00 26.3 976.67 -62349 -108315 -76864 -110323 -109415 -57003 -29875 -150258 -75012 -131991 -67526 -30887 26471 55274 -11273 17951 2886 -13216 13271 27339 -20233 -22302 -11845 -18775 -14810 -24029 -2231 -27984 -6509 -9940 -3626 -7157 -9256 9075 -958 -16051 -7985 -4951 233 5631 -870 -3628 -930 1265 8235 5953 -1227 -259 -1446 2557 923 -1792 3790 3749 923 736 -2224 2147 774 818 2852 2412 1302 2810 1476 1502 1364 1366 2647 -59 -484 1998 1493 374 364 237 -1283 -1608 -477 -83 376 -1513 -2347 -1032 -39 -665 -129 23 -116 630 1228 190 501 -82 -763 -743 -20 428 -610 -240 -476 -307 -415 1159 -1326 -1707 -529 -726 -6 555 511 -185 273 382 -257 667 350 273 408 -291 83 136 562 -515 979 -158 679 383 420 -386 -34 -663 -169 268 -80 255 57 -122 -348 155 385 -538 -367 -1134 -629 -1192 -1074 -336 -147 -2803 -803 -2686 -747 -276 170 335 -165 231 47 -283 232 439 -535 -597 -304 -563 -455 -849 -64 -999 -207 -359 -148 -349 -531 449 -49 -990 -514 -371 20 546 -99 -452 -119 160 993 755 -170 -37 -216 394 162 -357 774 832 219 182 -579 527 188 199 720 686 421 993 534 517 474 489 1063 -28 -246 1022 744 177 157 92 -486 -629 -213 -44 225 -1046 -1748 -803 -32 -536 -109 20 -98 502 989 146 370 -65 -627 -703 -21 518 -781 -296 -545 -315 -403 1179 -1494 -2007 -658 -968 -9 894 819 -305 438 582 -404 1009 549 413 659 -485 134 213 856 -756 1370 -235 974 552 684 -697 -66 -1353 -360 559 -179 593 134 -294 -827 348 820 -1097 SS 20231024T060215.3Z 8697.251566 114 1 54.12 2 77.83 117.25 155.30 345.63 0.00 1 0.00 1 0 17 1.867e-01 6.277e-03 1.173e-01 2.783e-03 5.302972e-01 1.472527e-03 6.125127e-03 -6.000000e+00 1.066419e-01 225.21 -2.00 3.50 -2.00 320.49 0.00e+00 2.176896e-03 5.707972e-04 4.377885e-04 -6.000000e+00 4.773366e-03 283.15 -2.00 20.00 -2.00 319.89 0.00e+00 4.603 0.002 302.00 328.00 3 1.5447e+00 4.4890e-03 5.3182e-02 -6.0000e+00 2.6352e-01 8.9952e-03 5.7779e-03 2.7989e-02 -6.0000e+00 2.8571e-01 -3.1425e-02 5.5716e-03 1.4831e-02 -6.0000e+00 1.7045e-01 2.6057e-03 2.8024e-03 5.4589e-03 -6.0000e+00 7.4014e-02 6.8639e-04 -2.6945e-04 7.8284e-05 5.3317e-05 -6.0000e+00 4.9342e-03 -2.9981e-03 0.0000e+00 10 0 0 10 0 0 97.27 23.81 0.90 -0.00300 -0.00502 224 24 1 8 0 241.227 20.00 23.81 25.53 28.00 28.00 26.4 979.98 -87177 -68783 -101102 6601 -71223 -226 -39608 -4164 -31658 -50177 -70952 -55450 -58700 -14003 236 -32631 -7631 -847 -12195 -5625 -9197 3006 -11880 -1345 10288 -610 -11448 -14147 -12104 -5501 -1019 -6401 -4200 -6343 5935 591 -10914 492 -3758 2612 343 -1062 48 -705 27 589 -1256 -779 1252 1167 3310 3055 2045 3244 703 1600 641 57 -48 191 351 1912 1302 1747 533 1407 1378 44 1682 1517 571 591 -190 644 -950 -1970 -1286 -1216 -220 -1535 -1780 -1504 -2075 -478 -700 -1416 -160 -424 877 1471 702 1105 667 705 36 652 124 989 182 -209 -143 -1370 -3 905 -1337 -1234 -226 -907 277 29 279 -1 -51 -35 421 617 296 -99 -111 -79 -98 121 567 -291 641 439 -9 1025 31 -47 -426 -524 -352 495 -293 20 39 147 -49 -81 413 -481 -848 -622 -1349 28 -612 -1 -303 -26 -289 -594 -1067 -821 -1129 -214 4 -861 -171 -20 -337 -154 -268 77 -378 -42 307 -21 -494 -603 -502 -231 -49 -368 -271 -434 335 37 -859 42 -406 311 46 -153 7 -108 4 93 -203 -130 211 210 650 664 485 825 190 447 186 16 -13 54 104 622 476 703 219 541 530 18 750 778 317 339 -106 338 -460 -867 -538 -519 -106 -885 -1173 -1117 -1655 -361 -573 -1236 -144 -391 792 1251 556 902 525 584 31 637 139 1236 240 -267 -169 -1476 -3 965 -1578 -1511 -293 -1261 417 45 459 -1 -84 -54 610 865 429 -152 -182 -134 -163 194 881 -434 916 604 -12 1476 51 -84 -826 -975 -686 1014 -649 45 90 350 -115 -180 874 -976 SS 20231024T060703.0Z 8697.254896 116 1 54.17 2 77.03 118.12 155.48 348.22 0.00 1 0.00 1 0 17 1.715e-01 6.393e-03 8.676e-02 3.031e-03 5.053852e-01 1.591700e-03 5.890283e-03 -6.000000e+00 9.794026e-02 225.21 -2.00 3.50 -2.00 320.29 0.00e+00 2.637789e-03 5.806739e-04 6.057451e-04 -6.000000e+00 4.383914e-03 283.15 -2.00 20.00 -2.00 319.68 0.00e+00 4.338 0.001 302.00 328.00 3 1.9970e+00 4.7492e-03 5.0247e-02 -6.0000e+00 2.4202e-01 1.6042e-02 5.9803e-03 2.6534e-02 -6.0000e+00 2.6240e-01 -2.9558e-02 5.5830e-03 1.4194e-02 -6.0000e+00 1.5654e-01 2.7861e-03 2.8465e-03 5.3313e-03 -6.0000e+00 6.7974e-02 5.7058e-04 -3.8580e-04 8.5252e-05 5.2604e-05 -6.0000e+00 4.5316e-03 -2.9405e-03 0.0000e+00 10 0 0 10 0 0 99.85 23.82 0.91 -0.00294 -0.00584 173 19 1 8 0 312.738 20.00 23.82 25.96 28.00 28.00 26.5 982.70 -33415 -31830 -53611 -83073 -51420 -75709 -74611 -37923 -31329 -55350 -32538 -44557 -13874 -48108 -30063 -15066 17308 -10690 -11314 -6628 13868 -11776 -9978 -12288 6162 -1745 -3905 5780 -3818 936 -899 -8063 -6051 -1910 -7130 -8929 -5578 -1234 664 2224 -3463 -2528 -1096 -737 2497 1643 1726 1655 -1723 -186 1900 3899 2350 3364 923 1112 1462 289 233 268 -217 1595 1300 3401 1134 1153 68 -677 2045 691 187 584 -719 1376 90 -351 -593 -629 41 -1389 -1586 -891 -2890 -1633 -547 -881 -108 -146 254 499 795 878 39 93 502 343 131 699 -175 116 -60 -1033 -396 1201 -1407 -1047 -554 -688 42 589 361 -73 166 32 131 671 612 -159 68 -30 -308 474 314 -283 593 164 148 910 -214 106 -245 -446 -491 339 -53 -131 71 -47 -21 -98 643 -583 -255 -267 -594 -1166 -481 -997 -1062 -428 -370 -892 -428 -754 -216 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