File name: Pandora240s1_Thessaloniki_20231025_L2Fit_fout2c13d20231018p1-8.txt File generation date: 20241007T144923.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v13d20231018.txt Level 1 file used: Pandora240s1_Thessaloniki_20231025_L1_smca1c13d20231018p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20231025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 for VP 20231018 First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2379 305.3790 305.5201 305.6613 305.8024 305.9434 306.0845 306.2256 306.3666 306.5076 306.6487 306.7897 306.9307 307.0717 307.2126 307.3536 307.4945 307.6355 307.7764 307.9173 308.0582 308.1991 308.3400 308.4808 308.6217 308.7625 308.9034 309.0442 309.1850 309.3258 309.4665 309.6073 309.7480 309.8888 310.0295 310.1702 310.3109 310.4516 310.5923 310.7330 310.8736 311.0143 311.1549 311.2955 311.4361 311.5767 311.7173 311.8578 311.9984 312.1389 312.2795 312.4200 312.5605 312.7010 312.8415 312.9819 313.1224 313.2628 313.4033 313.5437 313.6841 313.8245 313.9649 314.1053 314.2456 314.3860 314.5263 314.6666 314.8069 314.9472 315.0875 315.2278 315.3680 315.5083 315.6485 315.7888 315.9290 316.0692 316.2094 316.3495 316.4897 316.6298 316.7700 316.9101 317.0502 317.1903 317.3304 317.4705 317.6106 317.7506 317.8907 318.0307 318.1707 318.3107 318.4507 318.5907 318.7307 318.8706 319.0106 319.1505 319.2904 319.4303 319.5702 319.7101 319.8500 319.9898 320.1297 320.2695 320.4093 320.5491 320.6889 320.8287 320.9685 321.1083 321.2480 321.3877 321.5275 321.6672 321.8069 321.9466 322.0863 322.2259 322.3656 322.5052 322.6448 322.7845 322.9241 323.0637 323.2032 323.3428 323.4824 323.6219 323.7614 323.9010 324.0405 324.1800 324.3194 324.4589 324.5984 324.7378 324.8773 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231025T061139.6Z 8698.258097 162 1 25.43 2 76.49 119.24 146.53 329.99 0.00 1 0.00 1 0 17 2.363e-01 1.062e-02 2.053e-01 7.016e-03 4.957989e-01 3.612898e-03 5.931362e-03 -6.000000e+00 1.349299e-01 225.12 -2.00 3.50 -2.00 319.85 0.00e+00 -2.425919e-05 1.143465e-03 1.584321e-03 -6.000000e+00 6.037295e-03 283.03 -2.00 20.00 -2.00 319.22 0.00e+00 4.178 0.001 302.00 328.00 3 3.3790e+00 1.0383e-02 4.9050e-02 -6.0000e+00 3.3338e-01 7.3789e-02 1.2694e-02 2.7578e-02 -6.0000e+00 3.6146e-01 -9.4471e-02 1.1052e-02 1.3383e-02 -6.0000e+00 2.1564e-01 3.2690e-02 5.7422e-03 3.8346e-03 -6.0000e+00 9.3659e-02 1.6652e-04 -5.4017e-04 1.9406e-04 4.1321e-05 -6.0000e+00 6.2427e-03 -4.0956e-03 0.0000e+00 12 9 9 12 1 1 82.90 23.83 0.78 -0.00410 -0.00815 13 3 1 8 0 1815.830 20.00 23.83 26.18 28.00 28.00 26.4 982.05 119410 -4652 55049 -20899 -85213 71575 -24591 -68364 -78536 -61108 -52465 115135 -54482 5140 -35313 -9848 73060 -3112 19181 -3899 4881 -30475 7584 4171 -16585 -3480 -14782 -34802 13467 1708 1066 12771 5797 13484 2117 -14343 9419 -5218 -2720 -2889 2756 -3856 3672 3607 -662 4531 -1693 2338 -260 8804 1407 -3648 372 1978 5267 1443 1221 -757 1996 -956 1382 2875 3357 2352 2771 -103 -231 -1072 1888 2159 -678 641 630 -489 -1417 1449 661 -1830 2016 -780 -3550 -776 -2109 -852 -630 -677 2029 -2257 -458 -720 1210 468 1453 2189 -489 -100 -120 -262 -815 -1164 932 -1901 -480 118 -1399 -1211 -397 -703 650 53 275 -371 1004 451 28 793 -48 594 568 301 233 764 494 -105 428 -339 492 603 -325 661 -431 -380 -949 -435 191 264 216 223 -163 -8 -145 -576 817 -55 377 -286 -2014 490 -352 -1743 -2491 -1748 -1403 788 -2033 128 -1581 -392 1363 -135 774 -189 244 -2147 389 243 -1271 -245 -1163 -3167 737 111 81 970 535 1190 194 -1599 934 -718 -447 -557 551 -868 799 790 -152 1004 -398 539 -63 2054 392 -1173 123 698 1866 552 479 -299 746 -367 543 1231 1587 1231 1447 -52 -116 -551 1062 1262 -437 421 402 -299 -795 778 339 -973 1167 -494 -2623 -629 -1846 -777 -620 -647 1981 -2338 -462 -690 1145 418 1224 1909 -492 -104 -141 -349 -1055 -1579 1150 -2177 -515 134 -1746 -1566 -543 -945 939 84 471 -604 1686 718 41 1137 -71 921 945 482 367 1248 790 -161 627 -482 668 881 -497 1090 -773 -705 -1725 -834 390 559 464 489 -354 -16 -286 -1083 SS 20231025T062510.7Z 8698.267485 166 1 53.29 2 74.29 121.78 147.59 335.48 0.00 1 0.00 1 0 17 1.141e-01 9.754e-03 1.048e-01 6.360e-03 4.356359e-01 3.250502e-03 5.110931e-03 -6.000000e+00 6.515895e-02 225.12 -2.00 3.50 -2.00 319.78 0.00e+00 2.645812e-04 1.003608e-03 2.565173e-04 -6.000000e+00 2.915855e-03 283.03 -2.00 20.00 -2.00 319.13 0.00e+00 3.627 0.001 302.00 328.00 3 4.0470e+00 9.3958e-03 4.2309e-02 -6.0000e+00 1.6099e-01 3.6837e-02 1.1294e-02 2.2621e-02 -6.0000e+00 1.7456e-01 -3.7112e-02 9.4671e-03 1.1292e-02 -6.0000e+00 1.0414e-01 5.4510e-03 4.9454e-03 3.3674e-03 -6.0000e+00 4.5225e-02 1.5492e-04 -2.7018e-05 1.8136e-04 3.6388e-05 -6.0000e+00 3.0155e-03 -3.3238e-03 0.0000e+00 12 8 8 10 0 0 99.56 23.83 0.84 -0.00332 -0.00353 31 3 1 8 0 1718.429 20.00 23.83 26.76 28.00 28.00 26.5 985.29 -9683 -49824 -19528 -29611 -44740 -32309 -23020 -37949 5185 -49617 -7154 -38165 -27431 -1373 -19411 -2016 28139 21409 -20082 -1358 -1281 -6865 8871 7596 17742 19361 1594 14861 9996 -7890 -3650 -2263 -13060 -9383 4713 3295 -1552 9964 -2897 -4429 -4423 -190 2468 2662 -4595 2791 -3163 4497 -564 4312 682 -150 2234 6 212 -95 3182 1261 -1510 831 3451 4025 3364 1665 -484 550 313 615 1078 441 766 -668 -1004 -107 1169 -1510 -46 -1502 -2796 -912 -1040 -2051 -2397 -1826 -502 -1734 651 715 982 485 1081 335 -24 758 1185 403 611 293 1091 390 -268 -1257 462 1021 -1088 -2184 -2050 -979 604 524 683 -739 1014 -332 416 520 -493 -1068 188 -341 -316 1064 94 -208 768 345 116 1329 287 -437 371 -573 -504 234 566 53 52 178 -619 -879 713 -236 -135 -1133 -343 -536 -855 -601 -428 -941 94 -1650 -157 -1269 -990 -46 -919 -91 999 881 -1313 -77 -74 -418 490 462 1040 1168 126 968 663 -656 -333 -226 -1636 -1158 468 343 -192 1310 -528 -956 -1040 -45 592 641 -1197 684 -816 1088 -145 1110 200 -49 754 2 81 -38 1249 497 -597 322 1365 1747 1619 885 -260 272 153 303 595 280 518 -473 -694 -70 683 -811 -23 -763 -1618 -601 -775 -1728 -2149 -1718 -458 -1699 654 729 989 464 1042 303 -21 669 1162 409 696 375 1441 498 -320 -1374 476 1118 -1316 -2770 -2766 -1379 906 859 1193 -1208 1715 -533 617 745 -734 -1680 313 -543 -498 1748 153 -321 1129 489 159 1924 426 -706 634 -1020 -931 454 1173 114 113 369 -1274 -1872 1434 -458 SS 20231025T063631.9Z 8698.275369 173 1 8.42 2 72.48 123.98 148.32 340.31 0.00 1 0.00 1 0 25 1.153e-01 1.617e-02 9.462e-02 1.146e-02 4.109558e-01 5.815724e-03 4.903593e-03 -6.000000e+00 6.585382e-02 225.12 -2.00 3.50 -2.00 318.45 0.00e+00 1.462055e-03 1.204730e-03 3.638707e-04 -6.000000e+00 2.945909e-03 283.03 -2.00 20.00 -2.00 317.77 0.00e+00 3.274 0.001 302.00 328.00 3 4.2818e+00 1.5625e-02 3.8607e-02 -6.0000e+00 1.6271e-01 8.2565e-02 1.7871e-02 2.1040e-02 -6.0000e+00 1.7640e-01 -6.5344e-02 1.2513e-02 1.0579e-02 -6.0000e+00 1.0524e-01 2.0173e-02 6.6834e-03 3.3031e-03 -6.0000e+00 4.5718e-02 1.7154e-04 -1.1423e-04 3.1324e-04 3.3013e-05 -6.0000e+00 3.0456e-03 -5.3175e-03 0.0000e+00 12 9 9 12 1 1 999.00 23.84 0.68 -0.00532 -0.00618 2 2 1 8 0 2803.601 20.00 23.84 27.03 28.00 28.00 26.4 986.13 -7920 21937 13051 -27720 7951 -46798 -53821 -28357 65966 -14633 -18344 23580 -10670 -3275 -30195 32634 20807 -17570 -8374 7277 6246 23258 16971 7405 -8330 -1817 -630 4421 -5540 -18747 -991 1542 4885 4709 -6697 3037 -2354 12418 -5209 5566 -2080 1076 -2956 -4845 914 6547 705 905 1211 -715 -790 2554 -1384 -490 4920 -2270 1827 6174 -1408 -2990 2503 4706 2141 607 1352 1179 -1631 -4059 3615 1361 409 416 -1613 -183 1795 -275 -294 -2501 1698 -231 1617 -1337 1237 -3317 -1143 -2477 -1566 -152 -1335 -386 331 3324 1318 3250 473 -2219 1405 1779 -1514 -1343 -185 -1839 12 -1652 -492 -498 -978 -1106 -110 -349 583 -828 701 837 1215 12 1136 -614 -407 1400 -1310 1498 692 743 608 193 827 2748 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