File name: Pandora240s1_Thessaloniki_20231220_L2Fit_fwvt1c13d20231018p1-8.txt File generation date: 20241007T173804.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v13d20231018.txt Level 1 file used: Pandora240s1_Thessaloniki_20231220_L1_smca1c13d20231018p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20231220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 for VP 20231018 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0819 492.2027 492.3235 492.4443 492.5651 492.6859 492.8066 492.9273 493.0480 493.1687 493.2894 493.4101 493.5307 493.6513 493.7719 493.8925 494.0131 494.1336 494.2541 494.3746 494.4951 494.6156 494.7361 494.8565 494.9769 495.0974 495.2177 495.3381 495.4585 495.5788 495.6991 495.8194 495.9397 496.0600 496.1802 496.3005 496.4207 496.5409 496.6611 496.7812 496.9014 497.0215 497.1416 497.2617 497.3818 497.5018 497.6219 497.7419 497.8619 497.9819 498.1018 498.2218 498.3417 498.4616 498.5815 498.7014 498.8213 498.9411 499.0609 499.1807 499.3005 499.4203 499.5401 499.6598 499.7795 499.8992 500.0189 500.1386 500.2582 500.3778 500.4975 500.6171 500.7366 500.8562 500.9757 501.0953 501.2148 501.3343 501.4537 501.5732 501.6926 501.8120 501.9314 502.0508 502.1702 502.2895 502.4088 502.5281 502.6474 502.7667 502.8860 503.0052 503.1244 503.2436 503.3628 503.4820 503.6011 503.7203 503.8394 503.9585 504.0775 504.1966 504.3156 504.4347 504.5537 504.6726 504.7916 504.9106 505.0295 505.1484 505.2673 505.3862 505.5050 505.6239 505.7427 505.8615 505.9803 506.0991 506.2178 506.3366 506.4553 506.5740 506.6927 506.8113 506.9300 507.0486 507.1672 507.2858 507.4044 507.5229 507.6414 507.7600 507.8785 507.9969 508.1154 508.2338 508.3523 508.4707 508.5891 508.7074 508.8258 508.9441 509.0624 509.1807 509.2990 509.4173 509.5355 509.6537 509.7720 509.8901 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231220T062647.1Z 8754.268601 78 1 5.99 2 84.69 127.29 134.51 33.55 0.00 1 0.00 1 0 15 5.669e-03 5.612e-03 1.859e-04 1.856e-04 6.173574e+03 1.090224e+01 4.680159e+02 -6.000000e+00 2.850393e+02 276.82 -2.00 20.00 -2.00 505.29 0.00e+00 3.165142e-03 4.896913e-06 1.770668e-04 -6.000000e+00 1.526434e-04 276.82 -2.00 20.00 -2.00 500.52 0.00e+00 5.301632e-01 3.543197e-03 4.549049e-02 -6.000000e+00 1.085809e-01 222.95 -2.00 3.50 -2.00 502.09 0.00e+00 9.400 0.015 489.00 513.00 1 6.1217e-01 2.6943e-04 1.4689e-02 -6.0000e+00 8.2687e-03 -7.3206e-03 7.1253e-05 1.2727e-03 -6.0000e+00 2.2127e-03 2.5578e-01 -4.9194e-04 1.2365e-05 6.2283e-05 -6.0000e+00 3.9264e-04 -1.0435e-03 -1.7654e-05 12 8 8 10 0 0 -30.68 22.85 1.66 -0.00104 -0.00446 545 59 1 2 0 10.534 20.00 22.85 12.22 27.25 27.25 29.5 944.69 -1036 -797 -17 138 531 868 1100 997 985 791 716 431 -196 -138 -378 -288 -253 119 256 192 301 176 128 402 431 558 648 555 -516 -655 -900 -1012 -1094 150 208 113 103 -125 -354 -473 -317 -208 60 262 460 362 685 451 410 -335 -727 -1147 -1341 -1199 -708 -288 -51 53 48 -14 -22 462 332 593 347 120 85 -72 -354 -791 -597 -397 -354 82 162 -29 -190 -456 -644 -900 -566 -364 -434 -379 -76 -9 -199 -299 -377 -231 -349 268 591 709 933 583 489 18 -736 -1250 -1365 -1256 -1005 45 -5 124 -14 -590 -693 -496 -203 -135 197 444 487 690 910 1084 651 662 351 92 56 463 262 274 622 412 499 874 234 -3 -85 -364 -1029 -500 -149 7 73 280 148 252 423 611 696 611 218 -497 -728 -910 -995 -778 -16 138 539 897 1128 1033 1017 800 735 441 -197 -136 -374 -287 -255 119 267 201 314 180 134 410 447 577 667 571 -533 -639 -878 -1000 -1091 152 215 116 107 -130 -362 -479 -322 -215 63 270 480 380 710 463 416 -342 -716 -1142 -1320 -1189 -708 -290 -53 55 50 -14 -22 481 340 605 353 123 86 -72 -353 -771 -590 -387 -348 82 163 -29 -186 -440 -617 -881 -539 -353 -423 -368 -75 -9 -195 -298 -375 -224 -341 265 599 703 922 568 478 18 -685 -1172 -1278 -1162 -959 44 -5 122 -13 -585 -674 -488 -199 -134 199 441 486 689 918 1108 663 662 347 91 54 460 258 268 611 407 487 859 232 -3 -82 -355 -990 -484 -146 7 74 279 149 254 429 623 710 622 218 -486 -712 -890 SQ 20231220T062653.2Z 8754.268671 78 2 5.93 2 84.67 127.31 134.50 33.58 0.00 1 0.00 1 0 22 7.079e-03 6.987e-03 4.642e-04 4.631e-04 5.856971e+03 2.723344e+01 4.364848e+02 -6.000000e+00 3.560963e+02 276.82 -2.00 20.00 -2.00 505.28 0.00e+00 3.207559e-03 1.214650e-05 1.782610e-04 -6.000000e+00 1.906051e-04 276.82 -2.00 20.00 -2.00 500.49 0.00e+00 4.286959e-01 8.857499e-03 4.573952e-02 -6.000000e+00 1.355327e-01 222.95 -2.00 3.50 -2.00 502.06 0.00e+00 9.379 0.015 489.00 513.00 1 2.1855e+00 6.7397e-04 1.4662e-02 -6.0000e+00 1.0323e-02 -5.7254e-03 1.7824e-04 1.2557e-03 -6.0000e+00 2.7600e-03 5.3604e-02 -1.2774e-03 3.0841e-05 5.8148e-05 -6.0000e+00 4.9048e-04 -8.3203e-03 6.9086e-05 12 8 8 10 0 0 99.99 22.85 1.70 -0.00832 -0.01718 545 59 1 2 0 10.534 20.00 22.85 12.22 27.25 27.25 29.5 944.69 -1561 -1214 -291 65 461 1006 1198 1243 1173 829 690 330 -202 -379 -728 -481 -387 87 366 334 396 230 292 571 542 750 833 663 -568 -973 -1143 -1268 -1306 176 394 248 174 -28 -391 -583 -359 -195 219 400 736 603 871 544 422 -329 -896 -1362 -1722 -1508 -851 -226 114 228 181 65 142 654 582 760 515 217 103 -125 -386 -887 -772 -553 -412 1 182 -148 -314 -644 -858 -1130 -745 -534 -621 -593 -89 -21 -339 -318 -427 -248 -406 349 792 884 962 652 484 -45 -884 -1389 -1551 -1459 -1141 87 236 202 -8 -631 -872 -619 -212 -117 430 706 776 956 1208 1359 857 793 395 134 -46 512 292 343 625 531 577 970 298 -90 -175 -555 -1286 -829 -274 -15 186 362 236 288 468 723 794 585 163 -779 -992 -1213 -1475 -1165 -289 64 460 1021 1243 1301 1223 848 697 332 -200 -368 -711 -473 -384 88 385 353 417 244 308 604 555 764 888 708 -594 -963 -1131 -1271 -1320 185 412 259 178 -29 -395 -583 -361 -199 226 417 776 641 915 566 434 -332 -873 -1306 -1636 -1442 -841 -232 120 240 191 68 149 690 620 768 545 226 105 -126 -390 -879 -756 -548 -412 1 187 -145 -313 -633 -837 -1098 -723 -528 -616 -587 -86 -21 -330 -307 -412 -239 -395 342 797 893 946 632 459 -41 -840 -1294 -1444 -1378 -1058 85 238 203 -8 -622 -845 -606 -213 -114 422 699 771 949 1213 1383 870 790 390 130 -44 495 286 335 613 522 560 949 295 -86 -165 -526 -1207 -785 -269 -15 186 369 243 296 463 719 790 582 168 -778 -969 -1184 SQ 20231220T062659.2Z 8754.268740 78 3 5.93 2 84.66 127.33 134.49 33.61 0.00 1 0.00 1 0 56 5.600e-01 3.503e-01 5.783e-01 4.072e-01 3.727235e+04 3.570257e+04 1.013768e+03 -6.000000e+00 3.119192e+04 276.82 -2.00 20.00 -2.00 505.08 0.00e+00 -1.276680e-02 1.103817e-02 6.153399e-04 -6.000000e+00 1.523356e-02 276.82 -2.00 20.00 -2.00 499.09 0.00e+00 -4.370083e+00 8.375030e+00 2.075345e-01 -6.000000e+00 1.078605e+01 222.95 -2.00 3.50 -2.00 500.75 0.00e+00 9.359 0.015 489.00 513.00 1 9.9931e+00 6.3558e-01 2.4771e-02 -6.0000e+00 8.2190e-01 1.7328e-01 1.7058e-01 3.9561e-03 -6.0000e+00 2.1639e-01 2.9914e-05 -2.1889e-02 2.0981e-02 1.5662e-04 -6.0000e+00 3.9545e-02 -8.3798e-02 9.6064e-04 12 8 8 10 0 0 19.28 22.85 46.88 -0.08380 -0.23563 545 59 1 2 0 10.534 20.00 22.85 12.22 27.25 27.25 29.5 944.69 12250 -26207 76609 -13148 32446 68406 7047 12264 -33667 -11991 -13833 17012 146138 16625 -16633 67838 33744 15524 22917 17736 40052 12700 56119 900000 -36710 3781 41538 -1069 -1372 -11217 83562 21308 -6642 -253 3493 -22385 62275 29763 54925 33096 5819 23802 16705 -45861 2843 20931 26837 -9389 60626 94488 40824 101492 -33039 -45319 107597 -4066 -18832 38693 23599 -7983 8034 11255 -22630 19203 46740 21583 26852 37450 41038 60410 3732 38273 2742 10402 75843 10896 63836 109797 11065 -594 1295 46053 -50931 19438 37717 55843 86203 108424 51504 36579 17605 41183 123 160481 -9224 -17096 -5960 900000 -26181 900000 161462 -1039 1616 10665 95305 54846 45003 33337 103530 -4045 -53561 -34439 72644 30939 41867 -12473 -12862 -13779 -8775 -23328 18253 41525 5668 111465 102830 2949 93733 17852 65509 900000 19740 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