File name: Pandora240s1_Thessaloniki_20241009_L2Fit_fout2c13d20231018p1-8.txt File generation date: 20241010T083615.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v13d20231018.txt Level 1 file used: Pandora240s1_Thessaloniki_20241009_L1_smca1c13d20231018p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20241009 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 for VP 20231018 First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2379 305.3790 305.5201 305.6613 305.8024 305.9434 306.0845 306.2256 306.3666 306.5076 306.6487 306.7897 306.9307 307.0717 307.2126 307.3536 307.4945 307.6355 307.7764 307.9173 308.0582 308.1991 308.3400 308.4808 308.6217 308.7625 308.9034 309.0442 309.1850 309.3258 309.4665 309.6073 309.7480 309.8888 310.0295 310.1702 310.3109 310.4516 310.5923 310.7330 310.8736 311.0143 311.1549 311.2955 311.4361 311.5767 311.7173 311.8578 311.9984 312.1389 312.2795 312.4200 312.5605 312.7010 312.8415 312.9819 313.1224 313.2628 313.4033 313.5437 313.6841 313.8245 313.9649 314.1053 314.2456 314.3860 314.5263 314.6666 314.8069 314.9472 315.0875 315.2278 315.3680 315.5083 315.6485 315.7888 315.9290 316.0692 316.2094 316.3495 316.4897 316.6298 316.7700 316.9101 317.0502 317.1903 317.3304 317.4705 317.6106 317.7506 317.8907 318.0307 318.1707 318.3107 318.4507 318.5907 318.7307 318.8706 319.0106 319.1505 319.2904 319.4303 319.5702 319.7101 319.8500 319.9898 320.1297 320.2695 320.4093 320.5491 320.6889 320.8287 320.9685 321.1083 321.2480 321.3877 321.5275 321.6672 321.8069 321.9466 322.0863 322.2259 322.3656 322.5052 322.6448 322.7845 322.9241 323.0637 323.2032 323.3428 323.4824 323.6219 323.7614 323.9010 324.0405 324.1800 324.3194 324.4589 324.5984 324.7378 324.8773 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241009T065731.5Z 9048.289948 128 1 54.00 2 65.38 123.84 132.89 94.32 0.00 1 0.00 1 0 17 1.441e-02 6.090e-03 9.903e-03 1.700e-03 3.077680e-01 8.599616e-04 3.681655e-03 -6.000000e+00 8.265541e-03 226.55 -2.00 3.50 -2.00 318.22 0.00e+00 3.729632e-04 1.639927e-04 9.588026e-05 -6.000000e+00 3.711811e-04 284.86 -2.00 20.00 -2.00 317.47 0.00e+00 2.384 0.000 302.00 328.00 3 3.2780e+00 2.3068e-03 2.8464e-02 -6.0000e+00 2.0475e-02 -1.1280e-02 2.6254e-03 1.5854e-02 -6.0000e+00 2.2179e-02 2.5881e-03 1.7459e-03 7.8450e-03 -6.0000e+00 1.3231e-02 -9.0131e-03 9.2168e-04 2.2699e-03 -6.0000e+00 5.7311e-03 1.3056e-03 -6.4091e-05 4.8298e-05 2.2961e-05 -6.0000e+00 3.8143e-04 4.1467e-03 0.0000e+00 10 0 0 10 0 0 99.06 23.97 0.92 0.00415 0.00367 174 19 1 8 0 309.968 20.00 23.97 28.39 28.00 28.25 32.0 980.03 4264 2218 -69 -1729 -1963 -3034 -6037 -3077 -2320 -3283 -6423 -5073 519 -4235 -569 -2474 -82 -1133 -107 -950 749 1149 1631 384 -964 -94 -274 -2127 -240 1947 471 913 714 -1173 -2102 -2241 -2216 -876 -706 -1373 -572 -913 -869 -819 891 -538 -453 478 -603 792 546 705 1484 1511 462 1680 448 629 469 686 993 959 1099 1208 -188 74 356 -481 1378 488 -493 601 -396 714 417 75 -230 -811 212 -1204 -1114 -1343 -2424 -1064 -688 -1176 4 -128 278 249 416 550 607 978 601 418 268 774 -481 -121 226 -1022 24 861 -957 -981 -391 -773 253 264 316 -368 238 163 310 720 551 83 96 -291 -405 -22 293 -337 1009 154 690 1051 127 -143 24 -353 -442 199 -168 -173 231 37 -124 -49 283 -706 215 122 -4 -93 -95 -149 -331 -186 -154 -230 -458 -385 43 -429 -64 -312 -12 -171 -17 -155 122 184 272 69 -186 -19 -53 -394 -42 337 91 190 164 -275 -458 -506 -563 -261 -253 -569 -252 -421 -414 -390 418 -257 -211 219 -277 369 276 382 843 827 287 1061 265 366 295 432 595 628 779 909 -139 50 231 -313 986 399 -433 539 -350 595 319 51 -162 -564 147 -966 -995 -1330 -2547 -1164 -744 -1356 5 -156 334 281 471 572 587 960 650 463 331 1051 -679 -163 282 -1182 27 1026 -1255 -1334 -560 -1161 371 415 520 -605 369 235 445 994 785 115 144 -458 -638 -34 436 -477 1353 215 917 1475 180 -217 39 -574 -743 326 -294 -314 426 70 -233 -87 491 -1186 SS 20241009T074116.7Z 9048.320332 153 1 18.57 2 58.92 133.73 125.05 100.39 0.00 1 0.00 1 0 17 1.069e-02 6.899e-03 5.944e-03 2.321e-03 2.553734e-01 1.186125e-03 3.108004e-03 -6.000000e+00 6.131821e-03 226.54 -2.00 3.50 -2.00 316.66 0.00e+00 2.006092e-04 1.502948e-04 4.882740e-05 -6.000000e+00 2.753367e-04 284.86 -2.00 20.00 -2.00 315.95 0.00e+00 1.929 0.000 302.00 328.00 3 3.8257e+00 3.0889e-03 2.3216e-02 -6.0000e+00 1.5189e-02 -3.9894e-03 3.4542e-03 1.3116e-02 -6.0000e+00 1.6453e-02 -6.0891e-03 2.0431e-03 6.4664e-03 -6.0000e+00 9.8153e-03 -3.5578e-03 1.0005e-03 1.8363e-03 -6.0000e+00 4.2520e-03 1.2688e-03 -1.3314e-04 6.4334e-05 2.0154e-05 -6.0000e+00 2.8292e-04 3.6004e-03 0.0000e+00 12 9 1 12 1 1 99.67 23.97 0.83 0.00360 0.00260 27 9 1 8 0 662.884 20.00 23.97 28.47 28.00 28.25 31.9 980.01 -1348 -5269 -1505 -1314 -1252 120 43 -1357 -2120 -3308 -969 1638 438 -440 -185 -701 -1117 1176 830 925 -376 1153 215 1304 679 282 206 -65 1513 -71 1934 996 2005 -1741 -2867 -396 -2486 -368 -73 -1321 -989 -618 -555 -1155 -7 -652 -839 -116 -1006 825 1934 580 1015 1946 235 1081 641 661 829 698 1262 1808 364 600 -82 111 639 -571 1769 18 -563 452 -890 568 -480 189 -244 -1447 375 -1154 -1493 -1326 -2097 -1461 -1019 -945 -45 -455 437 270 455 645 510 985 876 658 293 382 -61 -188 84 -717 -12 927 -971 -1119 -381 -691 154 -124 251 -358 586 252 36 492 443 402 49 -451 -129 27 535 -276 831 741 805 863 -125 378 -149 -182 -485 335 96 -228 155 -239 -280 -91 28 -623 -194 -829 -232 -183 -156 15 6 -205 -356 -582 -162 282 87 -101 -48 -180 -295 352 256 270 -112 367 65 417 229 98 70 -23 490 -24 680 376 743 -667 -1117 -155 -1013 -173 -38 -790 -630 -407 -376 -784 -4 -439 -549 -74 -636 521 1299 421 711 1426 178 832 503 511 628 533 1002 1552 316 549 -73 96 524 -468 1576 17 -573 471 -918 552 -432 162 -194 -1134 316 -1041 -1498 -1365 -2277 -1660 -1172 -1153 -57 -589 556 325 533 691 540 1049 949 792 366 497 -81 -240 106 -839 -14 1126 -1222 -1460 -523 -989 218 -188 375 -531 860 342 47 624 578 552 69 -672 -192 39 754 -369 1117 949 982 1108 -174 525 -218 -270 -702 505 147 -363 252 -398 -463 -145 43 -977 SS 20241009T090034.3Z 9048.375397 197 1 54.13 2 50.19 155.50 111.24 110.87 0.00 1 0.00 1 0 17 9.078e-03 6.562e-03 1.116e-03 4.808e-04 2.063467e-01 2.447622e-04 2.525030e-03 -6.000000e+00 5.207049e-03 226.54 -2.00 3.50 -2.00 316.49 0.00e+00 1.820109e-04 2.948495e-05 3.802132e-05 -6.000000e+00 2.337903e-04 284.85 -2.00 20.00 -2.00 315.77 0.00e+00 1.559 0.000 302.00 328.00 3 1.8874e+00 6.3575e-04 1.8764e-02 -6.0000e+00 1.2898e-02 -7.2933e-03 7.1083e-04 1.0609e-02 -6.0000e+00 1.3971e-02 3.4563e-03 4.1685e-04 5.2320e-03 -6.0000e+00 8.3347e-03 -7.7640e-03 2.0108e-04 1.4875e-03 -6.0000e+00 3.6110e-03 1.3740e-02 4.3776e-05 1.3343e-05 1.6793e-05 -6.0000e+00 2.4021e-04 3.0600e-03 0.0000e+00 11 8 0 10 0 0 99.96 23.98 0.92 0.00306 0.00339 1407 153 1 8 0 38.121 19.99 23.98 29.14 28.00 28.25 32.2 984.65 -835 -2719 -1144 -3652 -1810 -537 -991 -76 -203 -1415 -1968 -761 -507 -669 378 -557 4 998 283 921 1047 887 951 747 756 573 -354 181 1055 1382 1545 458 1465 -1485 -2206 -442 -1362 -504 -230 -1235 -1455 -763 -622 -1425 -51 -661 -769 -8 -636 684 1294 506 876 992 334 1458 789 620 730 628 925 1186 731 798 -550 277 291 -311 1510 276 -402 217 -378 640 102 78 199 -756 383 -1095 -1341 -1296 -2476 -1225 -723 -1160 -91 -294 155 -5 578 674 570 1096 891 486 330 607 -355 -272 81 -770 156 827 -945 -966 -465 -892 209 65 271 -278 437 157 255 758 537 220 181 -180 -305 -43 475 -333 1091 281 657 1124 235 -114 -151 -397 -331 323 -171 -181 195 -134 -254 -76 195 -699 -134 -462 -193 -569 -247 -79 -157 -13 -39 -285 -384 -153 -115 -170 107 -155 1 318 93 311 357 297 330 274 289 226 -137 64 348 451 538 169 581 -600 -817 -166 -576 -248 -123 -758 -952 -512 -428 -983 -35 -449 -504 -5 -394 423 849 355 640 760 261 1150 635 492 568 493 758 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