File name: Pandora240s1_Thessaloniki_20241012_L2Fit_fout2c13d20231018p1-8.txt File generation date: 20241012T221905.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v13d20231018.txt Level 1 file used: Pandora240s1_Thessaloniki_20241012_L1_smca1c13d20231018p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20241012 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 for VP 20231018 First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2379 305.3790 305.5201 305.6613 305.8024 305.9434 306.0845 306.2256 306.3666 306.5076 306.6487 306.7897 306.9307 307.0717 307.2126 307.3536 307.4945 307.6355 307.7764 307.9173 308.0582 308.1991 308.3400 308.4808 308.6217 308.7625 308.9034 309.0442 309.1850 309.3258 309.4665 309.6073 309.7480 309.8888 310.0295 310.1702 310.3109 310.4516 310.5923 310.7330 310.8736 311.0143 311.1549 311.2955 311.4361 311.5767 311.7173 311.8578 311.9984 312.1389 312.2795 312.4200 312.5605 312.7010 312.8415 312.9819 313.1224 313.2628 313.4033 313.5437 313.6841 313.8245 313.9649 314.1053 314.2456 314.3860 314.5263 314.6666 314.8069 314.9472 315.0875 315.2278 315.3680 315.5083 315.6485 315.7888 315.9290 316.0692 316.2094 316.3495 316.4897 316.6298 316.7700 316.9101 317.0502 317.1903 317.3304 317.4705 317.6106 317.7506 317.8907 318.0307 318.1707 318.3107 318.4507 318.5907 318.7307 318.8706 319.0106 319.1505 319.2904 319.4303 319.5702 319.7101 319.8500 319.9898 320.1297 320.2695 320.4093 320.5491 320.6889 320.8287 320.9685 321.1083 321.2480 321.3877 321.5275 321.6672 321.8069 321.9466 322.0863 322.2259 322.3656 322.5052 322.6448 322.7845 322.9241 323.0637 323.2032 323.3428 323.4824 323.6219 323.7614 323.9010 324.0405 324.1800 324.3194 324.4589 324.5984 324.7378 324.8773 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241012T052929.7Z 9051.228816 75 1 53.28 2 81.06 108.13 162.09 346.86 0.00 1 0.00 1 0 33 6.060e-01 3.998e-02 4.097e-01 2.874e-02 6.924985e-01 1.664941e-02 9.786836e-03 -6.000000e+00 3.585639e-01 226.23 -2.00 3.50 -2.00 321.49 0.00e+00 5.284511e-03 8.697998e-03 1.113111e-02 -6.000000e+00 2.132040e-02 284.50 -2.00 20.00 -2.00 320.98 0.00e+00 6.092 0.004 302.00 328.00 3 3.2107e+00 5.9382e-02 8.9154e-02 -6.0000e+00 8.9435e-01 5.9914e-01 7.6830e-02 7.7583e-02 -6.0000e+00 9.7631e-01 -7.8648e-01 6.7076e-02 2.9008e-02 -6.0000e+00 5.7213e-01 3.0023e-01 3.2194e-02 5.6632e-03 -6.0000e+00 2.5036e-01 2.4001e-05 1.1253e-03 8.4885e-04 1.8479e-04 -6.0000e+00 1.7635e-02 5.3794e-03 0.0000e+00 12 8 8 10 0 0 98.41 23.98 1.75 0.00538 0.01384 30 3 1 8 0 1775.343 20.00 23.98 26.66 28.00 28.00 32.0 972.41 68741 900000 -138067 900000 900000 -77833 900000 900000 -156050 900000 900000 900000 900000 -33592 7887 -54524 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3464 3989 2796 4428 -1077 212 -1220 4000 3724 5571 3910 4016 3699 5810 2452 5476 7720 339 4545 3768 1508 -7086 -2128 605 2380 2040 1385 2916 2163 378 -1826 -4183 -2914 2040 2196 6723 524 2311 -2382 -1956 1472 3772 633 2970 43 -2853 -1542 -5687 1406 -76 1247 -1706 -169 -4156 -5025 361 -2907 -2911 -2487 -9037 -5662 -2589 -794 2842 -855 -911 3074 -1902 231 -1683 1851 -3045 2782 1959 2569 -729 12730 2206 4877 -4989 -441 2519 4181 7769 -260 -3462 -277 -2647 2505 1199 -2547 498 -2695 4036 2329 -9312 SS 20241012T054137.7Z 9051.237242 80 1 7.45 2 78.89 110.24 162.39 355.50 0.00 1 0.00 1 0 25 3.962e-01 4.439e-02 2.950e-01 2.720e-02 5.476339e-01 1.408901e-02 8.193131e-03 -6.000000e+00 2.270580e-01 226.23 -2.00 3.50 -2.00 320.06 0.00e+00 6.943436e-03 4.515802e-03 6.017147e-03 -6.000000e+00 1.018952e-02 284.50 -2.00 20.00 -2.00 319.41 0.00e+00 5.005 0.002 302.00 328.00 3 3.6694e+00 4.1050e-02 6.2054e-02 -6.0000e+00 5.6208e-01 2.9794e-01 4.8590e-02 4.1240e-02 -6.0000e+00 6.0890e-01 -6.1546e-01 3.4331e-02 1.7339e-02 -6.0000e+00 3.6329e-01 3.0360e-01 1.7586e-02 4.0280e-03 -6.0000e+00 1.5761e-01 5.4255e-05 -1.8102e-04 7.3791e-04 1.0155e-04 -6.0000e+00 1.0491e-02 3.1189e-03 0.0000e+00 12 9 9 12 1 1 999.00 23.96 0.83 0.00312 0.00176 1 2 1 8 0 3724.067 20.00 23.96 26.91 28.00 28.00 32.0 973.36 -98102 -62572 4469 -105306 -114333 -108084 -36785 -24546 -129995 119330 16454 -98687 -20313 147436 106261 -5459 38884 155301 30153 24150 1950 33187 900000 67957 19495 89678 32975 61830 39216 -4324 -13372 83978 -17960 90323 40147 52186 48167 11802 23265 21049 17491 35171 10840 24034 24834 30482 33413 26980 31827 16699 36145 20749 -3720 21203 38385 9727 6692 -283 -8049 18762 -4248 -2127 11144 3605 9750 5030 11744 12736 1980 8917 2165 1069 -447 15500 -7198 16623 -6260 1247 -4457 -4111 -3217 -1770 -10069 -5233 -6462 -6726 -3773 -541 -3683 -6016 -1658 -2670 -5101 -9110 2620 -5836 -1071 -62 115 -6086 5385 -3781 73 -773 -3142 -2265 -1549 498 280 1606 1235 1147 2182 2915 2274 2388 -110 -548 2514 3564 -803 649 1830 358 2030 3306 3659 4811 1581 2677 912 1050 -2249 -2363 930 -2336 710 -927 -3195 -1010 1389 -1975 -8453 -4009 162 -9306 -9599 -8857 -1507 -947 -15039 3164 436 -9276 -1077 3909 2817 -408 1968 4117 1817 1572 155 2024 900000 3063 1447 3329 2098 2787 2183 -401 -1595 4230 -2809 4789 3193 3736 3959 1627 3392 3572 3292 5781 2357 4588 4740 5576 5935 5222 5991 3852 7570 5501 -1219 6352 9871 3095 2210 -98 -2910 5720 -1566 -856 4378 1677 4253 2170 4727 5187 1016 4857 1341 685 -280 7770 -4094 6691 -3048 580 -2535 -2745 -2224 -1360 -8942 -4683 -5838 -6447 -3686 -519 -3620 -5729 -1517 -2324 -4395 -8008 2335 -6522 -1211 -79 152 -8264 6047 -4188 80 -849 -3820 -2844 -2074 652 406 2549 1995 1888 3470 4362 3437 3520 -173 -852 4066 5859 -1351 1039 2829 535 3079 4762 5109 7270 2601 4492 1679 1891 -4386 -4898 1887 -5055 1509 -2038 -7039 -2054 2766 -3842 SS 20241012T055153.0Z 9051.244364 85 1 25.46 2 77.08 112.06 162.38 2.91 0.00 1 0.00 1 0 17 3.219e-01 1.780e-02 2.601e-01 1.116e-02 5.028159e-01 5.792545e-03 5.942081e-03 -6.000000e+00 1.844298e-01 226.22 -2.00 3.50 -2.00 320.05 0.00e+00 7.485855e-03 1.974504e-03 8.998051e-04 -6.000000e+00 8.278391e-03 284.50 -2.00 20.00 -2.00 319.41 0.00e+00 4.353 0.001 302.00 328.00 3 3.9104e+00 1.7079e-02 5.0349e-02 -6.0000e+00 4.5658e-01 1.2071e-01 2.0785e-02 2.6499e-02 -6.0000e+00 4.9471e-01 -1.4476e-01 1.7812e-02 1.5799e-02 -6.0000e+00 2.9513e-01 5.3320e-02 9.2009e-03 9.3345e-03 -6.0000e+00 1.2790e-01 7.9725e-05 -2.9216e-04 3.0913e-04 8.4632e-05 -6.0000e+00 8.5178e-03 3.1628e-03 0.0000e+00 12 9 9 12 1 1 99.11 23.97 0.57 0.00316 0.00097 7 2 1 8 0 3181.337 20.00 23.97 27.18 28.00 28.25 32.0 974.67 -148375 173210 -35348 -114895 35972 -117114 -111553 -104773 -3598 26836 79225 1718 -17113 88588 2536 20782 91318 94 -25962 37869 -32150 -11198 22720 -13676 -13490 -15276 6294 -22139 5565 -15821 -29986 -10446 11333 32027 -3419 -16811 -20540 10348 24843 13551 1958 21342 -4949 12416 6439 8478 16827 541 628 6734 -723 5249 8217 3347 20691 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