File name: Pandora240s1_Thessaloniki_20241115_L2Fit_fout2c13d20231018p1-8.txt File generation date: 20241116T003820.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v13d20231018.txt Level 1 file used: Pandora240s1_Thessaloniki_20241115_L1_smca1c13d20231018p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20241115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 for VP 20231018 First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2379 305.3790 305.5201 305.6613 305.8024 305.9434 306.0845 306.2256 306.3666 306.5076 306.6487 306.7897 306.9307 307.0717 307.2126 307.3536 307.4945 307.6355 307.7764 307.9173 308.0582 308.1991 308.3400 308.4808 308.6217 308.7625 308.9034 309.0442 309.1850 309.3258 309.4665 309.6073 309.7480 309.8888 310.0295 310.1702 310.3109 310.4516 310.5923 310.7330 310.8736 311.0143 311.1549 311.2955 311.4361 311.5767 311.7173 311.8578 311.9984 312.1389 312.2795 312.4200 312.5605 312.7010 312.8415 312.9819 313.1224 313.2628 313.4033 313.5437 313.6841 313.8245 313.9649 314.1053 314.2456 314.3860 314.5263 314.6666 314.8069 314.9472 315.0875 315.2278 315.3680 315.5083 315.6485 315.7888 315.9290 316.0692 316.2094 316.3495 316.4897 316.6298 316.7700 316.9101 317.0502 317.1903 317.3304 317.4705 317.6106 317.7506 317.8907 318.0307 318.1707 318.3107 318.4507 318.5907 318.7307 318.8706 319.0106 319.1505 319.2904 319.4303 319.5702 319.7101 319.8500 319.9898 320.1297 320.2695 320.4093 320.5491 320.6889 320.8287 320.9685 321.1083 321.2480 321.3877 321.5275 321.6672 321.8069 321.9466 322.0863 322.2259 322.3656 322.5052 322.6448 322.7845 322.9241 323.0637 323.2032 323.3428 323.4824 323.6219 323.7614 323.9010 324.0405 324.1800 324.3194 324.4589 324.5984 324.7378 324.8773 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241115T101857.5Z 9085.429832 430 1 54.12 2 59.31 181.68 119.48 9.71 0.00 1 0.00 1 0 17 1.059e-02 6.398e-03 1.848e-03 5.963e-04 2.529866e-01 2.987063e-04 3.081307e-03 -6.000000e+00 5.996000e-03 223.26 -2.00 3.50 -2.00 317.15 0.00e+00 3.057541e-04 4.241402e-05 6.281493e-05 -6.000000e+00 2.675177e-04 280.32 -2.00 20.00 -2.00 316.50 0.00e+00 1.951 0.000 302.00 328.00 3 1.9203e+00 7.7860e-04 2.3151e-02 -6.0000e+00 1.4766e-02 8.3569e-03 8.7642e-04 1.2801e-02 -6.0000e+00 1.6045e-02 -4.2774e-03 5.3201e-04 6.3897e-03 -6.0000e+00 9.5698e-03 -5.5176e-03 2.6784e-04 1.8664e-03 -6.0000e+00 4.1568e-03 8.3774e-03 3.6546e-05 1.6716e-05 2.0368e-05 -6.0000e+00 2.7995e-04 4.2664e-03 0.0000e+00 10 0 0 10 0 0 99.95 23.62 0.88 0.00427 0.00454 824 90 1 8 0 65.321 20.00 23.62 19.23 27.75 28.00 31.5 964.87 -2622 -2579 -2772 -4329 -2603 -2432 -2238 -956 -543 -1560 -3152 -727 -1884 -939 71 -135 252 936 87 1617 792 539 1116 487 773 621 -529 -340 488 1283 1564 467 1347 -1740 -2034 -458 -1258 -451 -316 -1124 -1599 -693 -461 -1248 138 -586 -597 111 -596 758 1314 354 1019 1021 355 1457 776 535 761 589 802 1192 893 913 -490 285 380 -454 1619 235 -364 196 -435 599 85 193 42 -789 304 -1023 -1308 -1270 -2487 -1219 -766 -1184 -134 -314 243 -47 662 684 542 965 744 593 385 565 -403 -264 99 -683 97 834 -1011 -948 -478 -900 233 48 288 -339 412 156 266 771 615 135 148 -229 -213 57 495 -304 1092 238 521 1031 159 -142 -154 -449 -403 356 -133 -183 277 -96 -184 -100 151 -695 -287 -297 -324 -466 -246 -251 -249 -119 -74 -221 -442 -105 -317 -178 15 -31 59 230 22 422 211 141 303 141 234 194 -163 -97 130 342 450 144 451 -596 -639 -146 -454 -190 -145 -595 -906 -404 -276 -749 82 -349 -344 62 -331 423 784 227 682 720 256 1065 579 394 548 428 609 980 792 782 -445 233 297 -353 1374 210 -347 191 -417 543 77 157 32 -581 243 -939 -1223 -1307 -2709 -1381 -865 -1422 -167 -399 303 -56 770 728 533 956 804 711 472 762 -562 -351 122 -779 116 990 -1320 -1282 -681 -1243 337 74 462 -538 615 215 363 1008 828 192 211 -345 -321 83 707 -413 1509 315 658 1364 212 -202 -229 -676 -624 537 -215 -306 471 -167 -318 -167 243 -1085 SS 20241115T111622.7Z 9085.469708 463 1 9.07 2 61.12 197.22 116.28 23.79 0.00 1 0.00 1 0 17 1.044e-02 6.703e-03 2.903e-03 1.294e-03 2.646647e-01 6.531592e-04 3.226971e-03 -6.000000e+00 5.913581e-03 223.26 -2.00 3.50 -2.00 316.35 0.00e+00 3.711013e-04 7.643202e-05 5.148748e-05 -6.000000e+00 2.638292e-04 280.32 -2.00 20.00 -2.00 315.74 0.00e+00 2.061 0.000 302.00 328.00 3 1.9777e+00 1.6811e-03 2.4341e-02 -6.0000e+00 1.4563e-02 7.9519e-03 1.8816e-03 1.3328e-02 -6.0000e+00 1.5824e-02 -9.3345e-03 1.1043e-03 6.6372e-03 -6.0000e+00 9.4381e-03 -2.3591e-03 5.3536e-04 1.9311e-03 -6.0000e+00 4.0997e-03 6.9960e-03 -6.1537e-05 3.5493e-05 2.1681e-05 -6.0000e+00 2.7609e-04 4.0961e-03 0.0000e+00 12 9 1 12 1 1 99.79 23.68 0.90 0.00410 0.00363 76 50 1 8 0 117.406 20.00 23.68 18.88 27.75 28.00 31.7 964.71 -2364 -3219 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-1163 -1487 -1400 -2505 -1464 -1052 -1408 82 -329 -33 -57 516 575 483 734 992 298 634 603 -525 -436 450 -1036 285 860 -1506 -1038 -648 -1065 354 383 278 -376 578 105 501 1070 839 607 125 -423 -158 92 796 -190 1372 359 580 1319 338 -129 -434 -414 -357 335 -215 -444 341 -518 -472 -119 191 -910 SS 20241115T134738.5Z 9085.574751 552 1 53.74 2 77.47 231.44 98.48 54.03 0.00 1 0.00 1 0 17 2.949e-01 1.621e-02 2.358e-01 1.070e-02 5.583234e-01 5.672668e-03 6.541077e-03 -6.000000e+00 1.678550e-01 223.26 -2.00 3.50 -2.00 320.50 0.00e+00 4.867553e-03 2.165055e-03 1.108269e-03 -6.000000e+00 8.111060e-03 280.30 -2.00 20.00 -2.00 319.95 0.00e+00 4.482 0.002 302.00 328.00 3 3.7631e+00 1.7331e-02 5.2819e-02 -6.0000e+00 4.1361e-01 2.0343e-01 2.1862e-02 2.9150e-02 -6.0000e+00 4.4998e-01 -2.0025e-01 2.0219e-02 1.6895e-02 -6.0000e+00 2.6839e-01 7.1067e-02 1.0199e-02 7.7519e-03 -6.0000e+00 1.1673e-01 7.4883e-05 -4.4269e-04 2.9923e-04 8.0701e-05 -6.0000e+00 7.8752e-03 4.8164e-03 0.0000e+00 12 8 8 10 0 0 97.22 23.68 0.97 0.00482 0.00149 22 2 1 8 0 2442.331 20.00 23.68 17.51 27.75 28.00 31.5 957.63 -120697 -66084 -32154 47804 -118995 -134683 -14270 -105430 -111233 -82830 900000 900000 -89725 -782 -57213 900000 7747 57664 -6730 -44696 27141 -16523 50676 -18623 -36673 10922 -2054 -35930 9085 -1357 50548 -28057 6019 -3526 9998 -9397 -9295 14218 20083 -13929 -2679 10104 2508 2178 15036 -11112 6272 -1794 4389 -6155 8869 9289 10783 -1610 8024 9096 10953 1420 -3951 8272 -2670 10243 1396 -2560 -2144 3374 11797 1988 2147 6935 -2460 906 -4036 615 1516 -3293 2790 -2220 -6004 -948 -2167 -1337 244 -2741 -1176 1761 -45 -73 1276 2225 -640 -2579 1157 1942 -338 -1260 268 2030 -2068 -177 -225 -1561 138 -131 -1372 -3269 -1243 143 -100 -530 154 -386 56 71 -104 -986 706 291 -626 566 3010 1180 263 -1464 2400 345 808 -851 1615 -341 978 -14 -11 74 -260 -229 1126 -1085 -459 -133 311 -1038 -2621 -919 -335 498 -2481 -3276 -149 -2290 -2802 -1655 900000 900000 -3146 -14 -2223 900000 198 984 -230 -2330 694 -642 1057 -829 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