File name: Pandora240s1_Thessaloniki_20250220_L2Fit_fout2c13d20231018p1-8.txt File generation date: 20250220T225105.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v13d20231018.txt Level 1 file used: Pandora240s1_Thessaloniki_20250220_L1_smca1c13d20231018p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20250220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 for VP 20231018 First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2379 305.3790 305.5201 305.6613 305.8024 305.9434 306.0845 306.2256 306.3666 306.5076 306.6487 306.7897 306.9307 307.0717 307.2126 307.3536 307.4945 307.6355 307.7764 307.9173 308.0582 308.1991 308.3400 308.4808 308.6217 308.7625 308.9034 309.0442 309.1850 309.3258 309.4665 309.6073 309.7480 309.8888 310.0295 310.1702 310.3109 310.4516 310.5923 310.7330 310.8736 311.0143 311.1549 311.2955 311.4361 311.5767 311.7173 311.8578 311.9984 312.1389 312.2795 312.4200 312.5605 312.7010 312.8415 312.9819 313.1224 313.2628 313.4033 313.5437 313.6841 313.8245 313.9649 314.1053 314.2456 314.3860 314.5263 314.6666 314.8069 314.9472 315.0875 315.2278 315.3680 315.5083 315.6485 315.7888 315.9290 316.0692 316.2094 316.3495 316.4897 316.6298 316.7700 316.9101 317.0502 317.1903 317.3304 317.4705 317.6106 317.7506 317.8907 318.0307 318.1707 318.3107 318.4507 318.5907 318.7307 318.8706 319.0106 319.1505 319.2904 319.4303 319.5702 319.7101 319.8500 319.9898 320.1297 320.2695 320.4093 320.5491 320.6889 320.8287 320.9685 321.1083 321.2480 321.3877 321.5275 321.6672 321.8069 321.9466 322.0863 322.2259 322.3656 322.5052 322.6448 322.7845 322.9241 323.0637 323.2032 323.3428 323.4824 323.6219 323.7614 323.9010 324.0405 324.1800 324.3194 324.4589 324.5984 324.7378 324.8773 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250220T070918.9Z 9182.298136 279 1 6.03 2 71.03 123.78 78.83 223.20 0.00 1 0.00 1 0 17 1.735e-01 8.153e-03 1.229e-01 4.691e-03 5.974852e-01 2.408823e-03 6.958631e-03 -6.000000e+00 9.892318e-02 225.11 -2.00 3.50 -2.00 319.48 0.00e+00 2.998088e-03 6.834811e-04 3.072342e-04 -6.000000e+00 4.296464e-03 275.49 -2.00 20.00 -2.00 318.98 0.00e+00 3.039 0.000 302.00 328.00 3 2.6003e+00 6.7255e-03 4.3183e-02 -6.0000e+00 2.4503e-01 1.3352e-02 8.0145e-03 3.0852e-02 -6.0000e+00 2.6611e-01 -4.7147e-02 7.1226e-03 1.5962e-02 -6.0000e+00 1.5804e-01 1.2695e-02 3.7872e-03 6.0664e-03 -6.0000e+00 6.8104e-02 9.1543e-04 -4.8389e-04 1.2092e-04 5.3458e-05 -6.0000e+00 4.5865e-03 2.4804e-03 0.0000e+00 12 9 1 12 1 1 93.66 22.96 1.12 0.00248 -0.00116 15 16 1 8 0 376.176 20.00 22.96 11.41 27.25 27.50 35.5 987.01 -7245 -97101 17615 -82161 -74581 -50458 -48010 -49932 -29498 -44183 -26649 -50307 -41283 -11008 -25486 -11414 27100 6687 -15257 -13124 4503 -2719 4988 -14487 4815 -16117 -16325 -907 -10158 -7401 -6628 -7289 -1835 6204 -3608 -4599 -5525 202 1165 -1521 -981 1005 132 -2963 4578 -659 -2173 1181 -304 1888 2863 15 1656 2949 161 1654 1207 1190 189 992 1856 2794 2163 2616 901 2112 470 -1309 2193 827 -1082 -655 -924 622 89 260 -1261 -2068 665 -2192 -817 -986 -2814 -1306 -1017 -1230 349 150 1145 -186 1209 1042 802 351 198 156 522 600 -562 -53 -441 -244 -380 675 -1375 -812 -849 -1340 152 221 887 -547 251 439 133 719 683 119 -326 -224 -273 55 445 -40 628 691 311 596 401 152 -336 -355 -68 277 -510 -196 503 -17 -122 63 -33 -636 -51 -1898 117 -1401 -1085 -587 -599 -727 -392 -735 -427 -1196 -1152 -287 -956 -438 781 263 -795 -708 208 -134 244 -941 275 -1194 -1217 -56 -692 -542 -582 -743 -205 661 -396 -530 -728 30 211 -303 -214 228 32 -745 1087 -169 -575 315 -86 559 943 6 606 1156 67 709 531 514 80 417 817 1365 1104 1476 522 1153 263 -769 1414 574 -818 -506 -690 429 60 157 -745 -1272 427 -1710 -671 -860 -2666 -1286 -1012 -1293 378 164 1227 -191 1199 977 729 340 206 176 634 783 -775 -69 -567 -295 -434 808 -1713 -1041 -1106 -1873 219 338 1464 -893 415 686 205 1069 1047 183 -536 -359 -445 85 673 -61 910 963 422 883 642 257 -589 -624 -124 516 -987 -391 1005 -34 -245 118 -61 -1166 SS 20250220T072948.3Z 9182.312364 291 1 54.11 2 67.87 127.97 81.54 226.90 0.00 1 0.00 1 0 17 1.321e-01 6.146e-03 5.178e-02 1.851e-03 5.185938e-01 9.538334e-04 5.990137e-03 -6.000000e+00 7.533565e-02 225.11 -2.00 3.50 -2.00 319.98 0.00e+00 2.263340e-03 3.087259e-04 3.138336e-04 -6.000000e+00 3.271931e-03 275.49 -2.00 20.00 -2.00 319.48 0.00e+00 2.632 0.000 302.00 328.00 3 2.4942e+00 2.7228e-03 3.7524e-02 -6.0000e+00 1.8661e-01 -5.8049e-03 3.3486e-03 2.6960e-02 -6.0000e+00 2.0266e-01 -1.8473e-02 3.1638e-03 1.4070e-02 -6.0000e+00 1.2036e-01 -2.6920e-03 1.6510e-03 5.2329e-03 -6.0000e+00 5.1866e-02 1.6529e-03 -2.2632e-04 5.1108e-05 4.8138e-05 -6.0000e+00 3.4927e-03 2.3276e-03 0.0000e+00 10 0 0 10 0 0 99.99 22.97 0.86 0.00233 0.00063 656 71 1 8 0 82.129 20.00 22.97 12.10 27.25 27.50 35.8 991.39 -10760 -28559 -32895 -60578 -43780 -65463 -58537 25356 -47536 -25957 -37966 -43732 -16341 -12291 -10024 -8300 -4221 -3363 -6226 -12157 -3133 -5789 -5663 -12315 -3117 -2056 -5368 -1925 1060 -1449 -4867 -4518 -826 -4748 -5335 -5742 -3526 -1701 1110 -1435 -2210 -1222 -1169 -690 702 -6 -297 -233 -177 1867 2337 2164 3246 1215 589 2370 154 -416 226 1545 1424 2144 1706 1685 833 1135 1008 -653 1613 500 11 518 -712 91 -172 91 -639 -719 271 -923 -1524 -959 -2272 -1489 -945 -1398 56 74 575 519 822 1051 686 856 861 373 465 589 -295 -247 134 -693 -32 351 -1210 -1021 -629 -938 236 14 244 -413 361 209 270 774 510 46 -73 -598 -24 -17 405 -341 824 279 465 1152 88 -44 -264 -244 -198 250 -198 -198 220 -90 -342 27 491 -441 -79 -279 -356 -811 -454 -935 -855 183 -796 -375 -635 -890 -316 -282 -275 -259 -137 -119 -240 -525 -126 -237 -247 -624 -153 -105 -311 -103 55 -83 -340 -356 -72 -440 -462 -519 -353 -200 155 -240 -407 -236 -236 -140 142 -1 -62 -50 -39 430 596 606 968 399 201 824 56 -149 78 529 515 857 762 826 411 526 466 -314 858 306 7 348 -468 56 -96 45 -306 -351 150 -604 -1138 -801 -2040 -1271 -865 -1357 56 75 573 488 710 933 585 765 789 391 551 785 -412 -330 165 -772 -34 393 -1480 -1291 -846 -1341 365 21 408 -702 591 323 423 1172 797 69 -118 -995 -38 -26 613 -493 1238 404 650 1593 137 -76 -482 -462 -392 480 -408 -422 473 -198 -740 55 949 -817 SS 20250220T074022.5Z 9182.319705 296 1 54.62 2 66.31 130.23 83.00 228.75 0.00 1 0.00 1 0 17 2.646e-01 2.544e-02 2.840e-01 2.104e-02 4.836210e-01 1.109473e-02 5.720989e-03 -6.000000e+00 1.543202e-01 225.11 -2.00 3.50 -2.00 319.73 0.00e+00 6.777785e-03 3.269968e-03 1.117686e-03 -6.000000e+00 6.889453e-03 275.49 -2.00 20.00 -2.00 319.23 0.00e+00 2.471 0.000 302.00 328.00 3 6.5162e+00 3.1064e-02 3.6169e-02 -6.0000e+00 3.8285e-01 1.7927e-01 3.7106e-02 2.8530e-02 -6.0000e+00 4.1678e-01 -1.1810e-01 3.2542e-02 1.3478e-02 -6.0000e+00 2.4443e-01 2.5362e-02 1.7229e-02 8.7658e-03 -6.0000e+00 1.0525e-01 3.2851e-05 -9.1118e-04 5.9481e-04 6.0687e-05 -6.0000e+00 7.3512e-03 1.5636e-03 0.0000e+00 12 8 8 10 0 0 99.95 23.00 1.24 0.00156 -0.00528 24 3 1 8 0 2275.464 20.00 23.00 12.55 27.25 27.50 35.7 992.91 -54519 900000 30216 900000 -87449 900000 900000 900000 -66564 12310 -66951 -49268 -53868 49805 900000 -50035 100968 -6696 35622 39883 13210 63976 10386 77978 32874 -7218 2800 10629 27136 5695 -13075 15894 -13066 84689 -46123 143831 10212 -19538 -280 13821 -10805 -640 16211 8864 -8064 -9663 -272 10966 -5052 -4787 11253 3545 2302 4163 9668 26447 1718 -4109 1233 4476 8603 5828 3566 9377 -686 -372 -6772 12574 -6168 5323 -925 -4102 -5878 -3787 -2555 -4546 -1807 -2606 -1208 -397 -4062 -820 -1902 -1345 -273 -409 -130 -234 3086 1558 1374 3261 3983 3817 -2373 1038 -362 2228 -1307 1143 272 -1174 913 1087 -5460 2149 -2376 -3308 -1200 873 3639 -2482 455 52 -357 -1780 2320 -1134 -1697 2812 2202 -2776 -1424 678 1919 2885 1212 1857 439 1355 -365 692 -879 -2088 -81 518 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